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Showing 1-20 of 679 results

  1. Rhodium/Ruthenium Applications

    Asymmetric catalytic hydrogenation and hydrogen transfer reactions of various substrates such as prochiral ketones and olefins using Rh(I) and Ru(II)...
    Kenzo Sumi, Hidenori Kumobayashi in Organometallics in Process Chemistry
    Chapter

  2. An air- and moisture-stable ruthenium precatalyst for diverse reactivity

    Versatile, efficient and robust (pre)catalysts are pivotal in accelerating the discovery and optimization of chemical reactions, sha** diverse...

    Gillian McArthur, Jamie H. Docherty, ... Igor Larrosa in Nature Chemistry
    Article Open access 03 April 2024

  3. Activation of Inert C–H Bonds

    The development of catalytic reactions involving carbon–hydrogen bond cleavage is one of the most attractive research subjects in organic and...
    Fumitoshi Kakiuchi, Naoto Chatani in Ruthenium Catalysts and Fine Chemistry
    Chapter

  4. Determination and Imaging of Small Biomolecules and Ions Using Ruthenium(II) Complex-Based Chemosensors

    Luminescence chemosensors are one of the most useful tools for the determination and imaging of small biomolecules and ions in situ in real time....
    Miaomiao Wu, Zexi Zhang, ... Run Zhang in Metal Ligand Chromophores for Bioassays
    Chapter Open access 2022

  5. Metal Complexes with Redox-Active Ligands in the Indirect Electrosynthesis of Organic Sulfur Compounds

    Abstract

    A possibility of using metal complexes with redox-active ligands in organic electrosynthesis is demonstrated on the basis of literature data...

    E. V. Shinkar’, I. V. Smolyaninov, N. T. Berberova in Russian Journal of Coordination Chemistry
    Article 01 December 2023

  6. Photoinduced Electron-Transfer in First-Row Transition Metal Complexes

    In this chapter, after a brief summary of the basic photophysical and photochemical concepts, the state of the art of the photoinduced electron...
    Noufal Kandoth, Miguel Claros, ... Julio Lloret-Fillol in Springer Handbook of Inorganic Photochemistry
    Chapter 2022

  7. 3d-Metal Catalyzed C–C Bond Formation Through α-Alkylation of Ester, Amide, and Nitriles with Alcohol via Dehydrogenative Coupling

    The borrowing hydrogenation (BH) and acceptorless dehydrogenative coupling (ADC) methods emerged as sustainable tools for forging carbon–carbon bonds...
    Koushik Sarkar, Animesh Das, Biplab Maji in Dehydrogenation Reactions with 3d Metals
    Chapter 2023

  8. Metallocene-Catalyzed Selective Reactions

    Transition metal cyclopentadienyl complexes constitute a large family of compounds that can be used as catalyst for a number of organic...
    Martin Kotora in Metallocenes in Regio- and Stereoselective Synthesis
    Chapter

  9. Novel Catalyst Systems Based on Cationic Palladium Cyclopentadienyl Complexes for the Polymerization of Norbornene and Norbornene Derivatives

    Abstract

    Results of studying the catalytic properties of systems based on complexes with [Pd(Cp)(L) n ] m [BF 4 ] m (where Cp = η 5 -C 5 H 5 ; n = 2, m = 1: L = tris...

    D. S. Suslov, M. V. Pakhomova, ... P. A. Abramov in Kinetics and Catalysis
    Article 01 February 2024

  10. Electronic Structure and Reactivity of Metal Carbenes

    Metal carbenes have for a long time been classified as Fischer or Schrock carbenes depending on the oxidation state of the metal. Since the...
    Thomas Strassner in Metal Carbenes in Organic Synthesis
    Chapter

  11. Synthesis and Contemporary Applications of Platinum Group Metals Complexes with Acyclic Diaminocarbene Ligands (Review)

    Abstract

    Complexes of platinum group metals with acyclic diaminocarbene ligands have found application as transition metal catalysts, photoluminescent...

    M. A. Kinzhalov, K. V. Luzyanin in Russian Journal of Inorganic Chemistry
    Article 01 January 2022

  12. Water-Soluble Carbon Monoxide-Releasing Molecules (CORMs)

    Carbon monoxide-releasing molecules (CORMs) are promising candidates for producing carbon monoxide in the mammalian body for therapeutic purposes. At...

    Huma Khan, Muhammad Faizan, ... Weiqiang Zhang in Topics in Current Chemistry
    Article 14 December 2022

  13. Functional Group Directed B–H Activation of Polyhedral Boron Hydrides by Transition Metal Complexes (Review)

    Abstract

    Activation of B–H groups of polyhedral boron hydrides (boranes and carboranes) is one of the most actively develo** areas of boron...

    I. B. Sivaev in Russian Journal of Inorganic Chemistry
    Article 21 September 2021

  14. Alternative Transformations of N-Heterocyclic Carbene Complexes of the Group 11 Metals in Transmetalation Reactions (A Review)

    Abstract

    The carbene transfer from N-heterocyclic carbene complexes of Group 11 metals (NHC–M C ) (especially silver and copper) to other metals is...

    V. N. Mikhaylov, I. A. Balova in Russian Journal of General Chemistry
    Article 01 November 2021

  15. Catalytic Hydrodehalogenation of Haloarenes with Hydrogen and Hydrogen-Containing Compounds: A Review

    New catalytic methods for the hydrodehalogenation of haloarenes with hydrogen and hydrogen-containing reagents (metal and non-metal hydrids, organic...

    V. Sh. Saberov, G. F. Rayenko, ... N. I. Korotkikh in Theoretical and Experimental Chemistry
    Article 01 July 2023

  16. Dithiocarboxylic Acid Salts of Group 1–17 Elements (Except for Carbon)

    In this chapter, we review dithiocarboxylic acid salts. Methods of synthesizing these salts are reviewed, such as insertion of carbon disulfide into...
    Naokazu Kano, Takayuki Kawashima in Chalcogenocarboxylic Acid Derivatives
    Chapter

  17. The Applications of Metal-Based Photocatalysis in Organic Synthesis

    Photoredox catalysis is considered as a “hot topic” in organic synthesis, and it is now impossible to count the number of papers that have been...
    Morgan Cormier, Jean-Philippe Goddard in Springer Handbook of Inorganic Photochemistry
    Chapter 2022

  18. Different Types of Reducing Agents

    Following are given different types of reducing agents. As already stated, the method of choice depends on the selectivity required and also on the...
    V. K. Ahluwalia in Reduction in Organic Synthesis
    Chapter 2023

  19. Enantioselective Radical Reactions

    Over the past two decades, many researchers have been interested in “taming” the reactive free radical intermediate and utilizing it in...
    Jake Zimmerman, Mukund P. Sibi in Radicals in Synthesis I
    Chapter

  20. Group 1–17 Element (Except Carbon) Derivatives of Thio-, Seleno- and Telluro-Carboxylic Acids

    Over the last two decades, our understanding of the chemistry of Group 1–17 element derivatives of chalcogenocarboxylic acids has improved...
    Shinzi Kato, Osamu Niyomura in Chalcogenocarboxylic Acid Derivatives
    Chapter
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