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Controlled radical copolymerization of fluoroalkenes by using light-driven redox-relay catalysis
Fluoroalkenes are feedstocks in the manufacture of high-performance fluoropolymers with various applications. However, the synthesis of well-defined...
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New strategies for asymmetric photocatalysis: asymmetric organocatalytic/photoredox relay catalysis for efficient synthesis of polycyclic compounds containing vicinal amino alcohols
An asymmetric catalytic strategy in photocatalysis utilizing a chirality-induced approach through an organocatalytic/photoredox relay catalysis...
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Selective electrochemical synthesis of urea from nitrate and CO2 via relay catalysis on hybrid catalysts
The nitrogen cycle needed for scaled agriculture relies on energy- and carbon-intensive processes and generates nitrate-containing wastewater. Here...
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Asymmetric annulations based on cycloisomerization of cyclopropyl tethered allenyl ketones by bimetallic relay catalysis
The diastereo- and enantioselective tandem cycloisomerization/[4 + 2]-cycloaddition reaction of cyclopropyl tethered allenyl ketones with...
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Alkene 1,1-difunctionalizations via organometallic-radical relay
Radical reactions play an important role in modern organic synthetic chemistry. The generation of carbon radicals from the homolytic cleavage of...
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Chiral Diaminocarbene Complexes, Synthesis and Application in Asymmetric Catalysis
The synthetic routes to optically pure N-heterocyclic carbene (NHC) complexes and their application in asymmetric catalysis is reviewed. Chiral...
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Silver/chiral pyrrolidinopyridine relay catalytic cycloisomerization/(2 + 3) cycloadditions of enynamides to asymmetrically synthesize bispirocyclopentenes as PDE1B inhibitors
Significant progress has been made in asymmetric synthesis through the use of transition metal catalysts combined with Lewis bases. However, the use...
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Biomimetic asymmetric catalysis
Enzymes are the core for biological transformations in nature. Their structures and functions have drawn enormous attention from biologists as well...
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Synergistic catalysis for stereocontrol of prochiral nucleophiles in palladium-catalyzed asymmetric allylic substitution
In contrast to the stereocontrol of the stereocenter at the allyl unit, the asymmetric induction of prochiral nucleophiles remains a challenge in...
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Bridging the incompatibility gap in dual asymmetric catalysis over a thermoresponsive hydrogel-supported catalyst
The integration of dual asymmetric catalysis is highly beneficial for the synthesis of organic molecules with multiple stereocenters. However, two...
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Proton Relay Mediated Electrocatalytic Hydrogen Evolution by an Economic Co(III) Complex
Bis(iminidiacetato)cobaltate(III) complex has been evaluated for electrocatalytic proton reduction. The process follows a rare pathway of protonation...
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Global profiling of functional histidines in live cells using small-molecule photosensitizer and chemical probe relay labelling
Recent advances in chemical proteomics have focused on develo** chemical probes that react with nucleophilic amino acid residues. Although...
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Proton-controlled Action of an Imidazole as Electron Relay in a Photoredox Triad
AbstractElectron relays play a crucial role for efficient light-induced activation by a photo-redox moiety of catalysts for multi-electronic...
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Photoelectrochemical asymmetric catalysis enables site- and enantioselective cyanation of benzylic C–H bonds
The enantioselective functionalization of ubiquitous C( sp 3 )–H bonds is ideally suited for the construction of three-dimensional chiral structures....
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Exploiting photoredox catalysis for carbohydrate modification through C–H and C–C bond activation
Photoredox catalysis has recently emerged as a powerful synthetic platform for accessing complex chemical structures through non-traditional bond...
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Recent Progress in Asymmetric Relay Catalysis of Metal Complex with Chiral Phosphoric Acid
Asymmetric metal/organo relay catalysis, utilizing a metal complex and a chiral organocatalyst in a one-pot cascade reaction, is aimed to...
