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Polyoxometalate-based flexible conductive materials with superionic conductivity
Flexible ion-conductive materials exhibit intriguing advantages for applications in flexible electronic devices. Currently, the further enhancement...
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Polyoxometalate Unit Assembling for Crystal Catalysts
Early transition metals such as W, Mo, V, and Nb form anionic metal oxide molecules, so-called “Polyoxmetalates”. We present a variety of structures...
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An efficient strategy for alkoxy halogenation addition of olefins catalyzed by polyoxometalate-based iron catalyst
The halogenation of alkenes is a crucial pathway in forming C-X bonds, with a significant impact on organic synthesis and pharmaceuticals. However,...
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Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning and antifouling functionalities
Membrane technology is ideal for removing aqueous humic acid, but humic acid deposits cause membrane fouling, a significant challenge that limits its...
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Exploring Proton Conductivity Studies of a Copper-based Hydroxylated Polyoxometalate
A sole inorganic framework-material formulated as [Li(H 2 O) 4 ][{Cu I (H 2 O) 1.5 } {Cu II (H 2 O) 3 } 2 {W VI 12 O 36 (OH) 6 }]·N 2 ·H 2 S·3H 2 O ( 1 ), consisting of a...
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Fe-substituted Polyoxometalate-based Spherical Assemblies as Catalysts for Olefin Epoxidation
Fe-substituted polyoxometalate(Na 15 [(P 2 W 15 O 56 ) 2 Fe 3 ])(Fe-POM)-based composite (C 19 H 42 N) 15 [(P 2 W 15 O 56 ) 2 Fe 3 ](CTAB-Fe-POM) was successfully synthesized...
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Phase engineering of polyoxometalate assembled superstructures
Superstructures of cluster assemblies have extraordinary properties compared with individual clusters, however, their precise synthesis and phase...
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A Ni–Mo Polyoxometalate Based on Octamolybdate: Self-assemble and Application in Hydrotreating Catalyst
With the help of hydrogen bonding and π⋯π stacking, the small molecular clusters in the impregnating solution was induced to self-assemble and form a...
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A sensing platform based on Cu-MOF encapsulated Dawson-type polyoxometalate crystal material for electrochemical detection of xanthine
A promising sensing platform based on polyoxometalate-based metal–organic framework (POMOF) was established for sensitive electrochemical detection...
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High-entropy Metal Oxide-polyoxometalate-palladium Sub-1 nm Nanowires for Semi-hydrogenation Reaction of Alkynes
Palladium and palladium-based nanomaterials have shown great catalytic potential in the semi-hydrogenation reaction of alkynes. However, the scarcity...
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Atomically-precise Janus polyoxometalate catalyst with tunable water splitting activity
The development of bifunctional catalysts for solar-driven hydrogen and oxygen evolution has been regarded as a challenging but interesting research...
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Polyoxometalate functionalized magnetic metal–organic framework with multi-affinity sites for efficient enrichment of phosphopeptides
The reasonable design of metal–organic framework (MOF)–derived nanomaterial has important meaning in increasing the enrichment efficiency in the...
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The practically renewable and highly efficient electrocatalysts derived from a newly-designed Mo8Pt polyoxometalate compound
Platinum (Pt) catalysts are the most practical electrocatalysts; however, their low abundance and high cost severely limit their large-scale...
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Straightforward construction of hollow polyoxometalate-based metal-organic framework via pseudo-homoepitaxial growth
Hollow structures are significant for shortening diffusion path and promoting active center exposure. Single-crystalline hollow polyoxometalate-based...
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Synthesis, Characterization and Remarkable Nonlinear Absorption of a Pyridyl Containing Symmetrical Porphyrin-Polyoxometalate Hybrid
In this manuscript, a pyridyl containing porphyrin, C 46 H 36 N 8 O 4 (denoted as Tris@NTPP) and its derived polyoxometalate-porphyrin hybrid, [C 4 H 9 ) 4 N] 3 [C 41 H...
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Polyoxometalate based hybrids: synthesis of metal complexes and investigation of their electrochemical, thermal and biological properties
The hybrid compounds (KL 1 –KL 3 ) based on Keggin polyoxometalate (POM) were synthesized from the reaction between azo-imine ligands (HL 1 –HL 3 ) and...
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A highly reduced Mo74 polyoxometalate featuring high proton conductivity accessed by building block strategy
Highly reduced polyoxometalates (POMs) are predicted to be used as rather high energy density materials; however, it still suffers from the limited...
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A ring-shaped 12-Ti-substituted poly(polyoxometalate): synthesis, structure, and catalytic properties
A new ring-shaped 12-Ti-substituted poly(polyoxometalate) (poly(POM)), K 10 H 15 [{K 2 Na(H 2 O) 3 }@{(Ti 2 O) 2 (Ti 4 O 4 ) 2 ( A - α -1,3,5-GeW 9 O 36 ) 2 ( A - α -2,3,4-GeW 9 O 36 ) 2 }]·45H...
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Integrating advanced Keggin-structure polyoxometalate into polymeric membrane to enhance photocatalytic self-cleaning and antifouling functionalities
The high photocatalytic activity of environmentally benign Keggin-type polyoxometalate (POM) was introduced into polyethersulfone (PES) membrane to...