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Direct enantioselective reduction of C=C bond of β-polyfluoro-alkylated enones via asymmetric photoredox catalysis
Direct enantioselective reduction of the C=C bond of β-polyfluoro-alkylated enones is an important but long-pending subject in asymmetric catalysis....
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Exploiting photoredox catalysis for carbohydrate modification through C–H and C–C bond activation
Photoredox catalysis has recently emerged as a powerful synthetic platform for accessing complex chemical structures through non-traditional bond...
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New strategies for asymmetric photocatalysis: asymmetric organocatalytic/photoredox relay catalysis for efficient synthesis of polycyclic compounds containing vicinal amino alcohols
An asymmetric catalytic strategy in photocatalysis utilizing a chirality-induced approach through an organocatalytic/photoredox relay catalysis...
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Targeted activation in localized protein environments via deep red photoredox catalysis
State-of-the-art photoactivation strategies in chemical biology provide spatiotemporal control and visualization of biological processes. However,...
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The Key Concepts and Strategy in Photoredox/Nickel Dual Catalysis and Application to C–C Bond Formation Reactions
Trisubstituted enones are versatile synthetic building blocks used for the synthesis of natural products and pharmaceutical agents. Various methods...
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Enantioselective alkylation of α-amino C(sp3)−H bonds via photoredox and nickel catalysis
The catalytic enantioselective construction of C( sp 3 )−C( sp 3 ) bonds remains a substantial challenge in organic synthesis. One particularly promising...
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Cage escape governs photoredox reaction rates and quantum yields
Photoredox catalysis relies on light-induced electron transfer leading to a radical pair comprising an oxidized donor and a reduced acceptor in a...
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General radical difluoromethylation using difluoroacetic anhydride via photoredox catalysis
CF 2 H-containing molecules play pivotal roles in diverse fields from medicinal chemistry to materials science. However, the application of existing CF 2 ...
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Visible-light promoted photoredox catalysis in flow: addition of biologically important α‑amino radicals to michael acceptors
Visible light promoted photoredox catalyzed formation of α-amino radicals from cyclic tertiary amine compounds and their subsequent addition to...
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Asymmetric photoredox catalytic formal de Mayo reaction enabled by sensitization-initiated electron transfer
Visible-light-driven photoredox catalysis is known to be a powerful tool for organic synthesis. Its occurrence critically depends on the twice...
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Photoredox catalysis powered by triplet fusion upconversion: arylation of heteroarenes
In this work, the feasibility of triplet fusion upconversion ( TFU , also named triplet–triplet annihilation upconversion) technology for the...
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Trifluoroethoxylation of Styrenes via Photoredox-Catalyzed Meerwein Reaction
AbstractIn recent years, visible-light photoredox catalysis has become a widely used synthetic method. Photoredox-catalyzed Meerwein reaction of...
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N-heterocyclic carbene- and organic photoredox-catalysed meta-selective acylation of electron-rich arenes
meta -Selective functionalization of electron-rich arenes provides a complementary route to that of traditional organic synthesis. In classical...
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Photoredox-active Cr(0) luminophores featuring photophysical properties competitive with Ru(II) and Os(II) complexes
Coordination complexes of precious metals with the d 6 valence electron configuration such as Ru(II), Os(II) and Ir(III) are used for lighting...
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C–heteroatom coupling with electron-rich aryls enabled by nickel catalysis and light
Nickel photoredox catalysis has resulted in a rich development of transition-metal-catalysed transformations for carbon–heteroatom bond formation. By...
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Site-selective tyrosine bioconjugation via photoredox catalysis for native-to-bioorthogonal protein transformation
The growing prevalence of synthetically modified proteins in pharmaceuticals and materials has exposed the need for efficient strategies to enable...
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Accelerating charge transfer via nonconjugated polyelectrolyte interlayers toward efficient versatile photoredox catalysis
One of the challenges for high-efficiency single-component-based photoredox catalysts is the low charge transfer and extraction due to the high...
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Photoredox catalytic alkylarylation of alkynes with arylsulfonylacetate as bifunctional reagent
Difunctionalization of alkynes represents a powerful and straightforward approach to the synthesis of complex molecules. However, the radical...
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Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion
Skeletal editing has received unprecedented attention as an emerging technology for the late-stage manipulation of molecular scaffolds. The direct...
