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PALLADIUM(II) COMPLEX WITH TETRAHYDROBENZOXAZINOBENZOXOSINE: SYNTHESIS, ELECTRONIC AND MOLECULAR STRUCTURES
AbstractInteraction of the palladium(II) benzonitrile complex [Pd(PhCN) 2 Cl 2 ] with glyoxal-bis(2-hydroxy-3,5-di- tert -butylphenyl)imine (H 2 L) induces...
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Palladium Catalyzed Cascade Reactions Involving π-Allyl Palladium Chemistry
Palladium-catalyzed cascade reactions have gained steadily increasing importance over the last decade. The important factor in these reactions is...
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Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones
AbstractThe reaction of PdCl 2 with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl 2 ] 2 [Pd(Dpp-mian)...
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Basicity and Hydride-Donating Ability of Palladium(II) Hydride Complex with Diarylamido-bis-phosphine Pincer Ligand
AbstractThe hydride ion transfer and proton transfer are the key steps in the reactions of (de)hydrogenation, dehydrocoupling, production of H 2 , and...
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Biologically Active Palladium(II), Zinc(II), and Copper(II) Complexes with Terpene Ligands as Potential Pharmaceutical Drugs
AbstractA final review of the results of studies of versatile biological activities (in vitro) of chiral metal complexes with benzylamine and...
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Palladium(II) complex bearing benzothiazole based O,N,S donor pincer ligand: Study of in-vitro cytotoxicity, interaction with CT-DNA and BSA protein
A new palladium(II) complex, [Pd(LS Et )Cl] ( C1 ) with benzothiazole based ONS donor pincer ligand (HLS Et ) was synthesized (where, HLS Et =...
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Synthesis and Structures of Mono- and Trinuclear Complexes of Palladium(II) with 2-Chloropyridine
AbstractNew complex compounds[(2-clpy) 2 Pd(OOCMe) 2 ] ( I ), [{(Ph)Pd(2-clpy)} 2 (OOCMe) 4 Pd]·3C 6 H 6 ( II ), and [{(Ph)Pd(2-clpy)} 2 (OOCMe) 4 Pd] ( III ) are...
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Spectrophotometric Study of Palladium(II) Complexation with Elementary Amino Acids in Aqueous Solution
AbstractComplex formation of aqua palladium(II) ions with glycine (Gly), β‑alanine (β-Ala), and taurine (Tau) in aqueous solution was studied by...
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Sequentially Palladium-Catalyzed Processes
Sequentially palladium-catalyzed reactions consist of combinations of identical, related, or significantly different palladium-catalyzed processes...
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Extraction Properties of 4-[(Hexylsulfanyl)methyl]-3,5-dimethyl-1-phenyl-1H-pyrazole in the Palladium(II) Recovery from Nitric Acid Solutions
AbstractPalladium(II) extraction from nitric acid solutions with the complex-forming reagent 4-[(hexylsulfanyl)methyl]-3,5-dimethyl-1-phenyl-1 H -pyraz...
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Isocyanide-Phosphine Complexes of Palladium(II) Dihalides: Synthesis, Structure, and Resistance to Ligand Disproportionation Reactions
AbstractThe structure of isocyanide-phosphine complexes of palladium(II) dihalides [PdX 2 (CNR)(PPh 3 )] (X = Cl, Br, I; R = t- Bu, Xyl, and Mes) in CDCl 3 ...
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Palladium-Catalyzed Annulation of Alkynes
Palladium readily catalyzes the cross-coupling of functionally substituted aryl or vinylic halides and alkynes to afford a wide variety of...
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Complexation during Sorption of Palladium(II) Ions by Chemically Modified Silica
AbstractComplexation during the sorption of palladium(II) ions from chloride media by chemically modified silicas has been studied. Due to the use of...
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Three-dimensional self-assembled reduced graphene oxide composite as a promising adsorbent for the collection of palladium (II) and platinum (IV) in a low concentration
A three-dimensional reduced graphene oxide aerogel modified by sulfamic acid and ethylenediamine was prepared via one-step reduction self-assembly...
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Hyperbranched Polyester Polycarbamoyl Phosphonate Doped with Palladium(II) Ions for Catalytic Hydrogenation of α-Methylstyrene
AbstractA second-generation hyperbranched polyester with the terminal carbamoyl phosphonate groups has been synthesized. The structure of the...
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Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties
AbstractComplexes [PdL 2 Cl 2 ] ( I ) and [PdL 2 Вr 2 ] ( II ) (L is 5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione) are synthesized...
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Synthesis of 2-Heteroylidene Triterpenoids: Complex Formation with Palladium and in vitro Cytotoxic Activity
AbstractThe interaction of palladium(II) chloride with 2-heteroylidene of betulonic acid (prepared via the condensation with pyridine-2-carbaldehyde,...
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Palladium (II) Complex Supported on Magnetic Nanoparticles Modified with Phenanthroline: A Highly Active Reusable Nanocatalyst for the Synthesis of Benzoxazoles, Benzothiazoles and Cyanation of Aryl Halides
A well dispersed magnetically separable palladium complex (MNPs-phenanthroline-Pd) has been synthesized via the immobilization of palladium (II)...
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Nucleophilic Attack by Palladium Species
Recent researches have revealed that certain allyl-, vinyl-, and arylpalladium intermediates show a nucleophilic nature and react with various...
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Palladium-Catalyzed Cycloaddition Reactions of Arynes
The transition-metal-catalyzed cyclotrimerization of alkynes has been used extensively in synthesis during the past 25 years. However, until recently...