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Synthesis and characterization of a smart polymer-coated core–shell MnFe2O4@ organometallic framework for targeted drug delivery
Scientists are currently working to develop more effective and less harmful methods of delivering drugs to tissue. One method is to use a special...
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Photoreductive Electron Transfers in Nanoarchitectonics Organization Between a Diketopyrrolopyroleplatinum(II)-Containing Organometallic Polymer and Various Electron Acceptors
A platinum(II) polyyne/diketopyrrolopyrole-containing polymer of two different chain lengths, P (short) and P’ (long chain), were prepared in order...
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Synthesis of thermoresponsive polymer gels with crosslinked domains containing iridium complexes for ammonia sensing and N-alkylation catalysis
Incorporating organometallic complexes into nanodomains in polymer networks would broaden the scopes of gel material design and applicability. In...
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Highly reactive polyisobutylene through cationic polymerization of isobutylene
Highly reactive polyisobutylene (HRPIB) is the most important industrial polymeric material used as additives for lubricants, fuels and polymers....
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Research progress in highly efficient reversible deactivation radical polymerization of vinylidene fluoride
Polyvinylidene fluoride (PVDF)-based polymers are extensively utilized in various fields such as building and large bridge coatings, lithium battery...
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Immobilization and Study of Homogeneous Catalysts in a Continuous Flow Reactor Using Inorganic Particles Coated with Polymer
We demonstrated that organometallic catalysts can be immobilized in a gas-phase packed bed reactor (PBR) by coating inorganic particles with a...
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Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate)
AbstractThe new complex [Co III (3-CH 3 Salen)(CH 2 CN)]·CH 3 CN was synthesized and its crystal structure was determined by the X-ray diffraction analysis....
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Advanced Strategies for Stabilizing Single-Atom Catalysts for Energy Storage and Conversion
Well-defined atomically dispersed metal catalysts (or single-atom catalysts) have been widely studied to fundamentally understand their catalytic...
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Fluoride-initiated Anionic Ring-opening Polymerization: Mono- or Difunctional Polydimethylsiloxanes with Different Termini
The current paradigm in polymer chemistry increasingly involves controlled syntheses with better structural control and, consequently, products with...
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Organometallic PAEs
This review describes recent results in the field of poly(aryleneethynylene)s (PAEs) that contain metal ions in the polymer backbone, or in the... -
Spectroscopic Characterization of Organometallic Centers on Insulator Single Crystal Surfaces:From Metal Carbonyls to Ziegler--Natta Catalysts
A detailed knowledge of the microscopic properties is one of the prerequisites for an understanding of heterogeneous catalysts. A strategy which... -
Polyphosphazenes: A Review
In this paper the synthesis, properties and applications of poly(organophosphazenes) have been highlighted. Five different classes of macromolecules... -
Kinetic control over the chiral-selectivity in the formation of organometallic polymers on a Ag(110) surface
Methods to control chiral-selectivity in molecular reactions through external inputs are of importance, both from a fundamental and technological...
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Organometallic and Metallo-Organic Precursors for Nanoparticles
Several synthetic methods for the preparation of semiconductor nanoparticles have been reported. Colloidal and organometallic routes have probably... -
Stabilized Noble Metal Nanoparticles: An Unavoidable Family of Catalysts for Arene Derivative Hydrogenation
Transition-metal nanoparticle science is a strategic research area in material development due to their particular physical and chemical... -
Anion Sensing by Metal-Based Receptors
Metal-based receptors are an important and expanding class of molecules in anion sensing. This review describes the subject with specific focus on... -
Comparative study of the optoelectronic properties of diketopyrrolopyrrole based polymers obtained by direct C-H arylation
Donor–acceptor (D-A) type of new constituted diketopyrrolopyrrole-based polymers, PDPP-EDOT (poly A), PDPP-TP (poly B), and PDPP-EBTE (poly C), were...
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Synthesis and Structure of PAEs
This review discusses the progress in the synthesis of poly(aryleneethynylene)s (PAEs). It covers the literature from 1999 through 2003. The last... -
Stereospecific Olefin Polymerization Catalyzed by Metallocene Complexes
Metallocene complexes that serve as stereoselective olefin polymerization catalysts are described. The polymerization of propylene, styrene, methyl... -
Analogy between Surface and Molecular Organometallic Chemistry
Homogeneous and heterogeneous catalysis traditionally pertains to different communities, and it is thought that they are directed by different...