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Basicity and Hydride-Donating Ability of Palladium(II) Hydride Complex with Diarylamido-bis-phosphine Pincer Ligand
AbstractThe hydride ion transfer and proton transfer are the key steps in the reactions of (de)hydrogenation, dehydrocoupling, production of H 2 , and...
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Metal surfaces catalyse polarization-dependent hydride transfer from H2
Hydride transfer is a critical elementary reaction step that spans biological catalysis, organic synthesis and energy conversion. Conventionally,...
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Reduction in Organic Synthesis
This book discusses some of the reduction agents and processes involved in organic synthesis such as catalytic hydrogenation, homogeneous catalytic...
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Hydrogen and Metal Hydride Energy Technologies: Current State and Problems of Commercialization
AbstractThe need for the transition to carbon-free energy and the introduction of hydrogen energy technologies as its key element is substantiated....
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Inverse hydride shuttle catalysis enables the stereoselective one-step synthesis of complex frameworks
The rapid assembly of complex scaffolds in a single step from simple precursors identifies as an ideal reaction in terms of efficiency and...
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Reduction Performance and Mechanism of Liquid Terminated-Carboxyl Fluoroelastomers Using Unitary or Binary Metal Hydride Reduction Systems
AbstractUnitary metal hydride reduction systems (diisobutyl aluminum hydride and lithium aluminum hydride) and binary metal hydride reduction systems...
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Manipulating electrolyte concentration for metal hydride electrode at ultra-low temperature
Metal hydride electrode has been widely used in alkaline aqueous battery due to their merits of good comprehensive performance and high safety....
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Activation of metallocene hydride intermediates by methylaluminoxane in alkene dimerization and oligomerization
In order to elucidate the dependence of the structure and reactivity of the bimetallic hydride intermediates formed in the systems...
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Reactions of Carbon Dioxide Bound to Aluminum Diimine Hydride with Borane Dimethyl Sulfide and Ammonia
AbstractThe reaction of aluminum bis-formate acenaphthene-1,2-diimine complex [(Ar BIG -bian)Al(μ-OC(H)O) 2 Li(Thf) 2 ] ( I ) (Ar BIG -bian =...
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Branching and Cross-Linking of Siloxane Copolymers Containing Hydromethyl-Siloxane Units by the Hydride Transfer Restructuring Reaction. Possible Route to Silicone Coatings
The restructuring reactions of three siloxane copolymers: poly(Me 2 SiO-co-HMeSiO), poly(PhMeSiO-co-HMeSiO) and poly(3,3,3-F 3 PrMeSiO-co-HMeSiO) in the...
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Ruthenium-Catalyzed Organic Synthesis in Aqueous Media
Ruthenium-catalyzed organic synthesis in aqueous media has attracted much attention recently. The applications of ruthenium in aqueous media are...
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Speciation analysis of inorganic Sb leached from InSb thin films by hydride generation–microwave plasma-atomic emission spectroscopy
Sb speciation analysis is important in relation to industrial exposure or environmental release because of the large difference in toxicity between Sb
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Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine
Recently main group compounds have stepped into the territory of precious transition metal compounds with respect to utility in the homogeneous...
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Olefin Metathesis Directed to Organic Synthesis: Principles and Applications
For many years after its discovery, olefin metathesis was hardly used as a synthetic tool. This situation changed when well-defined and stable...
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Cobalt(III) hydride HAT mediated enantioselective intramolecular hydroamination access to chiral pyrrolidines
Enantioenriched pyrrolidines and derivatives are ubiquitous substructures in compounds of importance to medicinal and biological chemistry. Herein,...
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Diffusion-Thermal Phase Transformations in Titanium Hydride Containing a Multi-Barrier Systems of Hydrogen Traps
AbstractDiffusion-thermal phase transformations in modified titanium hydride containing a multi-barrier system of hydrogen traps are considered....
