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Asymmetric oligomerization state and sequence patterning can tune multiphase condensate miscibility
Endogenous biomolecular condensates, composed of a multitude of proteins and RNAs, can organize into multiphasic structures with compositionally...
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Co-Oligomerization of 1,3-Butadiene and Ethylene Promoted by Zerovalent ‘Bare’ Nickel Complexes
The transition-metal-catalyzed cyclooligomerization of 1,3-dienes and the co-oligomerization of 1,3-dienes and alkenes, that involve the...
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Protein-Protein Docking Approach to GPCR Oligomerization
G-protein-coupled receptors (GPCRs), the largest family of human membrane proteins, play a crucial role in cellular control and are the target of...
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Catalytic length-controlled oligomerization with synthetic programmable templates
Nature uses templated length-controlled oligomerization to process genetic information. Templates that are DNA and RNA based and fully synthetic have...
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Oligomerization of Pent-1-ene over Ni-Modified Granular Y Zeolite with Hierarchical Porosity
AbstractThe study investigates the catalytic performance of Ni-modified granular samples of hierarchical porous Y h (FAU) zeolite, some of which were...
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Oligomerization of C5 Olefins on Amorphous Mesoporous Aluminosilicates
AbstractCatalytic properties of ASM amorphous mesoporous aluminosilicates with different SiO 2 /Al 2 O 3 molar ratios (20, 40, 80) in oligomerization of...
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The Initiation Mechanism of the Isoolefin Oligomerization Reaction in the Presence of Ethylaluminum Dichloride–Protonodonor Complex Catalysts
AbstractThe mechanism of the initiation of isoolefins in the presence of ethylaluminum dichloride–proton donor (water, phenol, hydrochloric acid)...
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Granulated Hierarchical Zeolite Y and Dealuminated Samples Based on It in Pentene Oligomerization
AbstractThe catalytic properties of a number of FAU (Y) zeolite samples (microporous zeolite H-Y, granular hierarchical zeolite H-Yh, zeolite H-USYh...
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Preparation of nickel catalysts bearing Schiff base macrocycles and their performance in ethylene oligomerization
Two Schiff base macrocyclic ligands ( L1 and L2 ) were synthesized using ethylenediamine and terephthalaldehyde (or isophthalaldehyde) as raw materials...
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Activation of metallocene hydride intermediates by methylaluminoxane in alkene dimerization and oligomerization
In order to elucidate the dependence of the structure and reactivity of the bimetallic hydride intermediates formed in the systems...
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Catalytic Synthesis of Butene-1 and Hexene-1 in the Homogeneous Oligomerization of Ethylene in the Presence of Nickel Complexes Based on N-Heteroaryl-Substituted α-Diphenylphosphinoglycines
AbstractIt has been shown in tests that N -heteroaryl-substituted α-diphenylphosphinoglycines, namely, N -(pyrazin-2-yl) α-diphenylphosphinoglycine, N -...
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Oligomerization of Hydroperoxide Lyase, a Novel P450 Enzyme in Plants
The oligomeric state of fatty acid hydroperoxide lyase (HPL), of molar mass ∼55 kDa is uncertain and it has been reported as a trimer or tetramer...
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Synthesis and ethylene oligomerization behavior of trinuclear nickel complex with phosphorus dendrimer
A phosphorus dendrimer with multiple amino groups was synthesized via a two-step reaction with phosphonitrilic chloride trimer and 4-acetamidophenol....
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Measuring NLR Oligomerization III: Detection of NLRP3 and NLRC4 Complex by Bioluminescence Resonance Energy Transfer
Bioluminescent resonance energy transfer (BRET) is a natural phenomenon resulting from a non-radiative energy transfer between a bioluminescent donor...
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Selectivity of Ethylaluminium Dichloride–Proton Donor Complex Catalysts from the C4 Fraction in Initiating the Oligomerization of Isobutylene
AbstractThe mechanism of isobutylene initiation in the presence of ethylaluminum dichloride–proton donor (water, phenol, hydrochloric acid) complex...
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Introduction of adsorption, deactivation and dehydrogenation descriptors to promote the single-event kinetics model composed of elementary steps catalogued by the carbenium ions type for ethylene oligomerization and aromatization
AbstractAfter improving the cycle algorithm, the parameters of a single-event kinetic model, which is composed of elementary steps catalogued by...
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Oligomerization of Ethylene to Linear α-Olefins Using Complex Catalytic Systems of Zirconium Carboxylate
AbstractThe oligomerization of ethylene in aliphatic and aromatic solvents on complex zirconium carboxylate catalytic systems obtained from...
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Structure-Performance Evolution of Cobalt-Ammonia Activated Carbon Catalyst for Ethylene Oligomerization
The structure-performance evolution of Co/N-AC catalyst during ethylene oligomerization was investigated in detail. It was found that the catalytic...
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Methods to Measure NLR Oligomerization I: Size Exclusion Chromatography, Co-immunoprecipitation, and Cross-Linking
Protein oligomerization is a common principle of regulating cellular responses. Oligomerization of NLRs is essential for the formation of NLR...
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Influence of Bridged Group on Coordination Mode and Ethylene Oligomerization Behavior of Diamine Bridged Salicylaldimine Ni(II) Complexes
AbstractSeries of diamine and p-phenylenediamine bridged salicylaldimine ligands ( L1 – L4 ) were synthesized, and the corresponding nickel complexes ( C1 –...
