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ipso-Substitution Reaction of Nitro Group with Hydrogen in 5-Nitropyridines
AbstractAs a result of the oxidative aromatization of 5-nitro-1,4-dihydropyridines with hydrogen peroxide in a dioxane solution, previously...
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Carbonized Polyaniline as a Catalyst for Hydrogenation with Molecular Hydrogen of Organic Substrates with C=C Double Bond and Nitro Group
Nitrogen-doped carbon, which is characterized by a large surface area and the presence of micro- and mesopores, has been obtained by pyrolysis of...
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On the stability and existence of nitro-graphene, nitro-graphane, and nitro-graphene oxide
Here, the possibility of the existence of nitro-graphene derivatives with undisturbed graphene backbone is considered. Based on the first-principles...
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Palladium-Containing Aminated Activated Carbons: Hydrogenation of Aromatic Nitro Compounds
AbstractThe hydrogenation of 2-amino-4-methyl-6-nitrophenol, 2-chloro-4-nitrophenylformamide, 4Ñ€nitro- m -xylene, 2-nitro- m -xylene, o -bromonitrobenzene...
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Nitro-functionalized Fe-MOFs for lithium-sulfur batteries
Energy storage by means of lithium-sulfur batteries holds great promise. They are inexpensive and have a high potential energy density....
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Reactions of 2-Nitro-1H-benzo[f]chromenes and 3-Nitro-1-benzofurans with Nucleophiles
Abstract2-Nitro-1 H -benzo[ f ]chromenes reacted with alcohols to give a series of 3-alkoxy-2-nitro-2,3-dihyÂdro-1 H -benzo[ f ]chromenes as mixtures of cis ...
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Highly selective electrochemical oxidation of 2-nitro-4-methylsulfonyltoluene to 2-nitro-4-methylsulfonylbenzoic acid enabled by molybdate
It is urgent to develop a green synthesis approach for 2-nitro-4-methylsulfonylbenzoic acid (NMSBA) production as nitric acid oxidation procedure...
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Express Search and Characterization of Nitro Compounds via Visualization Mass Spectrometry
AbstractThe authors describe a way of detecting nitro and amino compounds using a mass spectrometer with laser desorption/ionization. This allows...
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Synthesis of 16-Nitro- and 16-Amino-14,17-ethanoestrane Derivatives
AbstractThe hydrogenation of 16-nitro-14,17-etheno steroids has been studied using different catalysts. The chemoselectivity criteria have been...
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Photochemical Oxidation of Dimethyl Sulfide with Triplet Nitro Compounds
AbstractThe mechanism of oxygen atom transfer between triplet molecules of a nitro compound and dimethyl sulfide is considered. This reaction pathway...
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Amination of 3-Nitro-5,15-dimesitylnorcorrolatonickel(II) and 3,12-Dinitro-5,15-dimesitylnorcorrolatonickel(II)
AbstractThe reaction of 3-nitro-5,15-dimesitylnorcorrolatonickel(II) and amines afforded 3-nitro-12-amino-5,15-dimesityl-norcorrolatonickel(II) in...
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Copper(II) Furancarboxylate Complexes with 5-Nitro-1,10-Phenanthroline as Promising Biological Agents
AbstractThe reaction of copper(II) acetate with 2-furancarboxylic (HFur)/5-nitro-2-furancarboxylic (HNfur) acids and 5-nitro-1,10-phenanthroline...
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Nitro-substituted 2-aryl-[1,2,4]triazolo[1,5-a]azines in the reactions with C-nucleophiles
Synthesis of nitro-substituted [1,2,4]triazolo[1,5- a ]pyrimidines based on oxidative cyclization of the corresponding nitropyrimidinyl hydrazones of...
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Experimental design optimization for the synthesis of lenalidomide nitro precursor
In this study, the synthesis of lenalidomide nitro precursor was investigated, which is helpful in the production of active pharmaceutical...
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Hydrazine-assisted one-pot depropargylation and reduction of functionalized nitro calix[4]arenes
Calix[4]arene derivatives containing two or four O -propargyl moieties are capable of undergoing reductive depropargylation in the presence of...
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Theoretical exploration of the stabilities and detonation parameters of nitro-substituted 1H-benzotriazole
ContextThe nitro group was introduced into the nitrogen heterocycle of 1H-benzotriazole to design a total of 31 derivatives. To estimate the thermal...
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Theoretical study of the stability and reactivity of nitro-coumarins and amino-coumarins by DFT method
The nitration reaction was applied to synthesize new substituted coumarin derivatives which undergo a reduction reaction to give the corresponding...
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Voltammetric Determination of a Potential Antiviral Drug Sodium Salt of 3-Nitro-4-Hydroxy-7-Methylthio-4H-[1,2,4]Triazolo[5,1-c][1,2,4]Triazinide Monohydrate
AbstractSodium salt of 3-nitro-4-hydroxy-7-methylthio-4H-[1,2,4]triazolo[5,1- c ][1,2,4]triazinide mono-hydrate (compound ( 1 )) is one of promising...
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Kinetics of Thermal Decomposition of 1,1-Bis(Methoxy-NNO-Azoxy)-3-Nitro-3-Azabutane
AbstractThe thermal decomposition of 1,1-bis(methoxy-NNO-azoxy)-3-nitro-3-azabutane is studied under isothermal and nonisothermal conditions. The...
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Nitro- and tetrazolopyrazines: modeling of the crystal structure and assessment of properties
The crystal structures of a series of nitro- and tetrazolopyrazines were modeled quantum chemically and by the atom-atom potential method and their...