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Surface Organometallic Chemistry for Single-site Catalysis and Single-atom Catalysis
Although driven by different research interests, single-site catalysts and single-atom catalysts are both believed to be model systems bridging...
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Hierarchically Macroporous Zeolite ZSM-5 Microspheres for Efficient Catalysis
Hollow zeolite microspheres have recently attracted much attention for their applications in catalysis, microreactors and biomedicine. Herein, we...
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Synthesis of new amino phosphonates based on secondary amines using microwave activation and phthalocyanine catalysis
The condensation of diethyl phosphite with aldehydes and cyclic ketones under conditions of thermal catalysis and microwave radiation (MW) afforded...
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Current state and future prospects of liquid metal catalysis
The need for advances in the sustainable production of fuels and chemicals has accelerated the push for innovation in catalytic systems that enable...
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Structure Engineering of Layered Double Hydroxides (LDHs) for Heterogeneous Catalysis
Layered double hydroxide (LDH) is regarded as an advanced platform material in catalysis and attracts vast attrition recently. As a kind of...
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Confined Mn2+ enables effective aerobic oxidation catalysis
Effective and mild activation of O 2 is essential but challenging for aerobic oxidation. In heterogeneous catalysis, high-valence manganese oxide ( e.g. ...
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Enzyme-driven Nanorobots Walking Along Predesigned Tracks on the DNA Origami for Cargo Transport and Catalysis
In molecular engineering, designing and synthesizing molecular machines with capable of performing complex tasks, remains a formidable challenge. DNA...
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Direct enantioselective reduction of C=C bond of β-polyfluoro-alkylated enones via asymmetric photoredox catalysis
Direct enantioselective reduction of the C=C bond of β-polyfluoro-alkylated enones is an important but long-pending subject in asymmetric catalysis....
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Metal–Organic Frameworks (MOFs): The Next Generation of Materials for Catalysis, Gas Storage, and Separation
Metal–organic frameworks (MOFs) have emerged as a promising class of porous materials for various applications such as catalysis, gas storage, and...
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Iron(III)-based metalloradical catalysis for asymmetric cyclopropanation via a stepwise radical mechanism
Metalloradical catalysis (MRC) exploits the metal-centred radicals present in open-shell metal complexes as one-electron catalysts for the generation...
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Lipopeptides as tools in catalysis, supramolecular, materials and medicinal chemistry
Lipopeptides are amphiphilic peptides in which an aliphatic chain is attached to either the C or N terminus of peptides. Their self-assembly — into...
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Discrimination between the Homogeneous and Heterogeneous Mechanisms of Catalysis in the Copper- and Ligand-Free Sonogashira Reaction Using Phase Trajectory Analysis
AbstractThe paper presents the results of a comparative study of the differential selectivity of the copper- and ligand-free Sonogashira reaction...
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C(5)—H arylation of 1-substituted 1,2,4-triazoles with aryl halides under Pd/NHC catalysis
An efficient method for the synthesis of 1-substituted 5-aryl-1,2,4-triazoles by selective C—H arylation of 1-substituted 1,2,4-triazoles with...
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Homogeneous Catalysis of The Suzuki–Miyaura Reaction with Aryl Chlorides
AbstractThis paper presents the results of a kinetic study aimed at obtaining data on the contributions of homogeneous and heterogeneous mechanisms...
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Carbonyl cross-metathesis via deoxygenative gem-di-metal catalysis
Carbonyls and alkenes are versatile functional groups, whose reactivities are cornerstones of organic synthesis. The selective combination of two...
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C(2)H-Alkylation of (Benz)oxazoles with Tertiary Alkyl Chlorides and Bromides under Photoinduced Palladium Catalysis
AbstractA method has been developed for the selective C(2)H alkylation of (benz)oxazoles with tertiary alkyl chlorides and alkyl bromides under...
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Controlled radical copolymerization of fluoroalkenes by using light-driven redox-relay catalysis
Fluoroalkenes are feedstocks in the manufacture of high-performance fluoropolymers with various applications. However, the synthesis of well-defined...
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Photoelectrochemical asymmetric catalysis enables site- and enantioselective cyanation of benzylic C–H bonds
The enantioselective functionalization of ubiquitous C( sp 3 )–H bonds is ideally suited for the construction of three-dimensional chiral structures....
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Copper Phthalocyanine Improving Nonaqueous Catalysis of Pseudomonas cepacia Lipase for Ester Synthesis
The nonaqueous catalysis of lipases is significant for synthesis of high pure esters, but they usually behave low catalytic activity due to...
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Nuclear spin catalysis in biochemical physics
Magnetic isotope effects have been recently discovered in living nature. They were observed for the first time in experiments on cells enriched with...