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Second Law of Thermodynamics, Gibbs’ Thermodynamics, and Relaxation Times of Thermodynamic Parameters

Abstract

The relationship between the second law of thermodynamics and Gibbs’ thermodynamics is discussed. The second law of thermodynamics is...

Yu. K. Tovbin in Russian Journal of Physical Chemistry A

Article 14 April 2021

Confined Three-Aggregate Systems and Their Thermodynamics

Abstract

A class of small systems is considered that includes spatial regions occupied by atoms and molecules in three-aggregate states, with a total...

Yu. K. Tovbin in Russian Journal of Physical Chemistry A

Article 20 May 2024

Chemical Thermodynamics

This chapter on Chemical Thermodynamics starts with an introduction in Sect. 2.1, followed by the section on equations of state (Sect. 2.2) covering...

Nuggenhalli S. Nandagopal in Chemical Engineering Principles and Applications

Chapter 2023

Thermodynamics analysis of acetaminophen and its metabolites using density functional theory

The thermodynamics factors of acetaminophen and its metabolites were considered using density functional theory (DFT) at 298.15 K temperature and 1...

Abdel-baset H. Mekky in Journal of Umm Al-Qura University for Applied Sciences

Article Open access 20 March 2024

Statistical Thermodynamics

Why it is important to know this material? Statistics provides the key elements for understanding the molecular nature of the macroscopic properties...

Luisa Di Paola in Fundamentals of Molecular Bioengineering

Chapter 2024

Classical and Chemical Thermodynamics

Why it is important to know this material? Chemical thermodynamics are the very foundation of thermodynamic phase equilibria, which play a central...

Luisa Di Paola in Fundamentals of Molecular Bioengineering

Chapter 2024

Thermodynamics: Basic Concepts

Thermodynamics studies the changes associated with the exchange of energy between a system and its surroundings. It establishes the conditions that...

Syed S. H. Rizvi in Food Engineering Principles and Practices

Chapter 2024

The Laws of Thermodynamics

Using a minimum of mathematics, the science of thermodynamicsThermodynamics is developed in its historical context, focusing on the concepts of...

Robert Fleck in Entropy and the Second Law of Thermodynamics

Chapter 2023

Thermodynamics of the Sodium-Iron-Phosphate-Water System Under Hydrothermal Conditions II: The Solubility and Gibbs Energy of Formation of Maricite (NaFe^IIPO₄) from 220 to 300 °C

Maricite, NaFe ^IIPO ₄, is an important iron(II) corrosion product in high-pressure steam generators operating under phosphate pH control. Experimental...

Dmitrii Chvedov, Liliana Trevani, Peter R. Tremaine in Journal of Solution Chemistry

Article 02 May 2023

Thermodynamics of Interaction between Poly(perfluorosulfonic acid) Nafion and Water

Abstract

The thermodynamics of interaction between poly(perfluorosulfonic acid) Nafion and water is studied by isothermal sorption and...

S. D. Chernyuk, A. P. Safronov, ... O. V. Bushkova in Polymer Science, Series A

Article 01 April 2023

Landauer’s Principle and Thermodynamics

Landauer’s principleLandauer’s principle is reconsidered and re-evaluated. It is demonstrated that it is not consistent with Carnot’s theorem, when...

Erkki J. Brändas in Advances in Methods and Applications of Quantum Systems in Chemistry, Physics, and Biology

Conference paper 2024

Thermodynamics of CO2 Conversion

The work has looked at possible processes to utilise atmospheric carbon dioxide (CO2) as well as the thermodynamic complexities involved in trying to...

Joshua Gorimbo, Ralph Muvhiiwa in Carbon Dioxide Utilization to Sustainable Energy and Fuels

Chapter 2022

Electrical Conductivity and Thermodynamics of Ion Association of Ammonium Ionic Liquids in Acetone

Abstract

The electrical conductivity of a number of tetraalkylammonium ionic liquids with tetrafluoroborate anion has been studied in acetone in the...

O. E. Zhuravlev, A. D. Kaftanov, G. S. Yulmasov in Russian Journal of Physical Chemistry A

Article 10 December 2023

Solvation Thermodynamics of DL-α-Amino Butyric Acid in Aqueous Sodium Sulfate Solvent System

Abstract

The present study tells us about the solubility of DL-α-amino butyric acid (DL-α-Aba) in aqueous binary solvent mixture of sodium sulfate...

Sanjay Roy, Kalachand Mahali, ... Puspal Mukherjee in Russian Journal of Physical Chemistry A

Article 03 August 2023

Investigation of the solubility and thermodynamics of salicylic acid in 2-propanol and ethylene glycol/propylene glycol binary solvent mixtures at (293.15 to 313.15) K

This study aimed to measure both the solubility and thermodynamics of salicylic acid in binary solvent mixtures of (2-propanol + ethylene glycol) and...

Fatemeh Dabagh, Fatemeh Khalili, ... Abolghasem Jouyban in BMC Chemistry

Article Open access 09 May 2024

Kinetics, thermodynamics and stability constants of aniline oxidative coupling reaction with promethazine: experimental and computational study

A spectrophotometric method was employed to investigate the kinetics and thermodynamics of the oxidative coupling reaction between aniline and...

Hayman Saeed Salih, Mohammad Tahir Kareem, Kareem Jumaa Jibrael in Reaction Kinetics, Mechanisms and Catalysis

Article 02 October 2023

Antibiotic Drug Solubility and Thermodynamics Profile in Binary (1,4-Dioxane, Acetonitrile, and Water) Solvents at Different Temperatures (T = 298.15–318.15 K)

Abstract

Cefpodoxime proxetil (CP) solubility in binary solvent mixtures (1,4-dioxane + water and acetonitrile + water) was tested using the...

Ravibhai Bhola, Rizwan Ghumara, ... Hasit Vaghani in Russian Journal of Physical Chemistry A

Article 17 December 2023

The Laws of Thermodynamics

In this chapter, we will first consider very simple systems, i.e., single-component and single-phase systems capable of absorbing and releasing work...

Marcus Elstner, Qiang Cui, Maja Gruden in Introduction to Statistical Thermodynamics

Chapter 2024