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Carbon
We take a wide-ranging look at “organic chemistry,” the study of carbon-containing compounds. Since carbon is central to the structure and function...
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Carbon-Carbon Bond Cleavage Reaction Using Metallocenes
Among a lot of transition metal mediated or catalyzed C–C bond cleavage reactions, metallocene mediated C–C bond cleavage reactions, in particular,...
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Stereochemistry of Organic Compounds Containing Carbon–Carbon Single Bonds (Hydrocarbons)
Organic compounds containing carbon–carbon single bonds are called alkanes.
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Enumeration of constitutional isomers of methyl alkanes by means of alkyl biradicals: equivalence of odd and even isomer series of symmetrical methyl alkanes
A mathematical–chemical approach using alkyl biradicals has been used to enumerate isomers of alkenes, alkylcyclopropanes, and alkyl triradicals for...
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Phospholipid and n-alkane composition, anti-α-glucosidase and anti-cyclooxygenase activities of milk thistle oil
Although milk thistle oil has been authorized as a new edible oil in many countries, there is a lack of information about its chemical and biological...
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Stereochemistry of Trivalent Carbon
Carbon is tetravalent and normally forms four covalent bonds involving four bond orbitals each having two electrons.
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The Singular Properties of Carbon as the Basis for the Emergence of Life
The singular role of carbon as the “basic element” of organic chemistry and biochemistry results from its properties to form long and branched chains...
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Recent advances in the improvement of cyanobacterial enzymes for bioalkane production
The use of biologically produced alkanes has attracted considerable attention as an alternative energy source to petroleum. In 2010, the alkane...
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Using NMR solvent relaxation to determine the Hansen solubility parameters of a carbon black and as a quick method to compare the surface quality of carbon blacks
The selection of appropriate solvents into which carbon blacks can be dispersed optimally is important for product manufacture and performance....
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Carbon Dioxide-Based Green Solvents
Currently, the ‘sustainability’ and ‘renewability’ is most important aspects for the environment and for the living beings. In the chemical industry,...
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Application of Hydrophilic Lipophilic Difference Theory for Fenofibrate Formulation as a Self-Emulsifying Drug Delivery System
AbstractImproved oral bioavailability of lipophilic substances can be achieved using self-emulsifying drug delivery systems. However, because the...
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Understanding the Conformational Interconversions of a Polymer Chain in a Liquid Environment at the Single-molecule Level
T he conformational interconversions of polymer chains have been of great interest as a basic scientific issue. Single-molecule force...
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Carbon-wise utilization of lignin-related compounds by synergistically employing anaerobic and aerobic bacteria
BackgroundLignin is a highly abundant but strongly underutilized natural resource that could serve as a sustainable feedstock for producing chemicals...
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Computational Studies of the Solid-State Molecular Organometallic (SMOM) Chemistry of Rh s-Alkane Complexes
A review of computational studies on the structures, bonding and reactivity of rhodium σ-alkane complexes in the solid state is presented. These...
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Hydrocarbons
Hydrocarbons (HCs), i.e. compounds composed only of carbon and hydrogen, are the simplest organic compounds. They can occur as linear or branched...
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Phase Equilibria of Binary Mixtures of 3-Chloro-2-Hydroxypropyl Methacrylate and 2-N-Morpholinoethyl Methacrylate in Supercritical Carbon Dioxide
This study presents exceptional perception into the phase transition behavior of binary mixtures containing 3-chloro-2-hydroxypropyl methacrylate...
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Recent advances in metal-mediated oxidations with mCPBA
Among the various peroxides that are available, meta -chloroperbenzoic acid ( m CPBA) is an effective oxidizing reagent that is used in a variety of...
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Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine
Recently main group compounds have stepped into the territory of precious transition metal compounds with respect to utility in the homogeneous...
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Nuclear Magnetic Resonance (NMR) Spectroscopy
The nuclear magnetic resonance (NMR) spectroscopy is of three types: Proton nuclear magnetic resonance (1HNMR) spectroscopy, carbon-13 nuclear...
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Analogy between Surface and Molecular Organometallic Chemistry
Homogeneous and heterogeneous catalysis traditionally pertains to different communities, and it is thought that they are directed by different...