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Elemental Phosphorus in the Synthesis of Organophosphorus Compounds: The Recent Advances (A Review)
AbstractRecent publications on direct reactions of elemental phosphorus with organic halides (alkyl bromides, aryl (and hetaryl) halides, and aryl...
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Formation process of halogen-rich argyrodite: elemental disordering of atomic arrangement at the 4a and 4d sites in a heat treatment
Sulfide-based solid electrolytes are increasingly recognized as crucial materials for the practical application of all-solid-state batteries. In...
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Influence of the Substitution of Iron by Aluminum and Titanium on the Structure and Properties of Barium Hexaferrite
AbstractIonic substitution is considered to be an effective approach to modify functional characteristics of hexagonal ferrites. To this aim, solid...
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Use of elemental profiles determined by energy-dispersive X-ray fluorescence and multivariate analyses to detect adulteration in Ceylon cinnamon
The price of Cinnamomum verum (Ceylon cinnamon) is around twice as high as that of the other cinnamon varieties commonly grouped under the name...
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Effect of aliovalent bismuth substitution on structure and optical properties of CsSnBr3
Aliovalent substitution of the B component in ABX 3 metal halides has often been proposed to modify the band gap and thus the photovoltaic properties,...
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The influence of electronic effects on the substitution reactions of N,N′-donor cis-palladium(II) complexes with bidentate (pyridin-2-yl)methyl-aniline ligands
The substitution behaviour of bidentate N,N ′-donor (pyridin-2-yl)methyl-aniline chelates with different substituents on the mononuclear Pd(II)...
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Directed regulation mechanism on chlorine substitution of PCDD/Fs isomers based on quantum chemical computation
BackgroundChlorine substitution has been considered as one of the key steps of polychlorinated dibenzodioxin/furan (PCDD/Fs) generation. The...
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Effects of Br substitution to improve the ionic conductivity of chloride electrolytes without changing crystal structure
Chloride solid-state electrolytes (SSEs) are of great interest because of their wide electrochemical window. However, most chloride SSEs have lower...
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Reactions of bis(trifluoromethyl)-substituted 2-azanorbornenes and 2-azanorbornanes: electrophilic addition, N-substitution, and hydrogenation
The chemical behavior of bis(trifluoromethyl)-2-azabicyclo[2.2.1]hept-5-enes and -heptanes in electrophilic addition reactions to the C-C bond, N -subs...
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Verification of preparations of (1H-indol-3-yl)methyl electrophiles and development of their microflow rapid generation and substitution
Although highly reactive (1 H -indol-3-yl)methyl electrophiles such as (1 H -indol-3-yl)methyl halides are potential precursors for the synthesis of...
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Mechanical and thermal properties of non-structural adhesive mortar using linear low-density polyethylene (LLDPE) aggregate substitution with vinyl acetate/ethylene (VAE) interface
Linear low-density polyethylene (LLDPE) is a type of plastic with a high percentage of solid waste and is hardly degradable. The characteristics of...
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Separation Factors and Peclet Numbers in Evaporation Refining of Elemental Substances near Their Melting Point
Abstract—Using the Burton–Prim–Slichter equation, we demonstrate that distillation or sublimation refining of some elemental substances (as...
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Efficient Spinel Nanoparticle Catalysts ACo2O4(A = Cu, Ni, Mn) for Catalytic Oxidation of Toluene: Cation Substitution Effects
Co 3 O 4 has been applied in several catalytic fields as a favorite catalyst. However, its performance is still not enough to replace noble metal...
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Structural and Optical Properties of Bi4Six/2Gex/2V2-xO11-x/2 Compounds: Effect of Double Substitution and Phase Transitions
The solid-state reaction method was employed to successfully synthesize a range of compounds, Bi 4 Si x/2 Ge x/2 V 2-x O 11-x/2 , where 0.1 ≤ x ≤ 0.6. The main...
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Nucleophilic Substitution Reactions of 3-(Bromomethyl)-5,7-dimethyl-2-oxaadamantan-1-ol
AbstractReactions of 3-(bromomethyl)-5,7-dimethyl-2-oxaadamantan-1-ol with various nucleophiles afforded a number of new 2-oxaadamantane derivatives....
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Epitaxial Silicon Carbide on Silicon. Method of Coordinated Substitution of Atoms (A Review)
AbstractA review of advances in the growth of SiC epitaxial films on silicon is presented. All the main classical methods used at present to...
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Sulfonation of poly(ether ether ketone): An evidence for di-substitution of the repeat unit
Sulfonation of poly(ether ether ketone) (PEEK) is an electrophilic substitution reaction that takes place on the aromatic ring flanked by the two...
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Isomorphous Zn-Substitution on Y Zeolite Structure by the Hydrothermal Method as a Novel Strategy: Evaluation by Methyl Orange Photodegradation
Isomorphous substitution of Zn-Y zeolite (Zn-DYZ) was successfully conducted with different Zn/Al ratios of 0.5:9.5, 1:9, 1.5:8.5, and 2:8 mol ratios...
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Rational molecular design of efficient yellow-red dendrimer TADF for solution-processed OLEDs: a combined effect of substitution position and strength of the donors
The development of high-performance solution-processed red organic light-emitting diodes (OLEDs) remains a challenge, particularly in terms of...
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Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?
AbstractReactions of 1-(chloromethyl)silatrane with organic group 14 element anions [(Me 3 Si) 3 E] ‒ (E = Si, Ge) generated in situ afforded the...