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Facile synthesis of acrylamide derivative copolymers with side urethane groups for systematic variation of the thermoresponsive behavior
A simple method to finely control the thermoresponsive properties of polymers over a wide range of temperatures is to enhance the versatility of the...
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Vasorin-containing small extracellular vesicles retard intervertebral disc degeneration utilizing an injectable thermoresponsive delivery system
Intervertebral disc degeneration (IDD) is the pathological reason of back pain and the therapeutic approaches are still unsatisfactory. Recently,...
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Rheological and thermoresponsive shape memory properties of polylactic acid (PLA) and styrene-butadiene-styrene (SBS) copolymer blends
In this study, a thermoresponsive shape memory polymer based on various compositions of melt blended of polylactic acid (PLA) and...
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Fabrication of low cost thermoresponsive microgel@CuO catalyst for rapid reduction of methylene blue dye
Azo dyes which are carcinogenic and mutagenic in nature are hazardous water pollutants. The present study details the catalytic reduction of...
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Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl-2-furfural
A base-free catalytic system for the aerobic oxidation of 5-hydroxymethyl-2-furfural was exploited by using Pt nanoparticles immobilized onto a...
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Dispersion of submicron-sized SiO2/Al2O3-coated TiO2 particles and efficient encapsulation via the emulsion copolymerization of methacrylates using a thermoresponsive polymerizable nonionic surfactant
Submicron-sized SiO 2 /Al 2 O 3 (Si/Al)-coated titanium dioxide (Si/Al-TiO 2 ) particles were encapsulated through the emulsion copolymerization of...
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Thermoresponsive PEDOT:PSS/PNIPAM conductive hydrogels as wearable resistive sensors for breathing pattern detection
This study investigated a sustainable method for preparing PEDOT:PSS/PNIPAM conductive hydrogels. The free radical polymerization of NIPAM to PNIPAM...
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Synthesis, Thermoresponsive Behavior, and Catalytic Properties of Amphiphilic Diblock Copolymers of N-Vinylcaprolactam and N-Vinylimidazole
AbstractThermoresponsive diblock copolymers (DCs) were prepared by two-stage reversible addition-fragmentation chain transfer/macromolecular design...
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Thermoresponsive phase behavior and nanoscale self-assembly generation in normal and reverse Pluronics®
Self-assembly generation in block copolymers (BCPs): normal Pluronics® (L31, L64, L35, P65) and reverse Pluronics® (31R1, 17R4, 25R4, 10R5) are...
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A DFT Study on Molecular Structure, MEP, HOMO–LUMO and Spectroscopic Analysis of Thermoresponsive Monomers Used in Micro/Nanogel Preparations
AbstractIn this work, N-isopropylacrylamide (NIPAAm) and N-isopropylmethacrylamide (NIPMAAm), known as thermoresponsive monomers and used in...
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Thermoresponsive Nanogels from Dendronized Copolymers for Complexation, Protection and Release of Nucleic Acids
A series of thermoresponsive cationic dendronized copolymers and their corresponding nanogels containing dendritic oligoethylene glycol (OEG) units...
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Poly(N,N-bis(2-methoxyethyl)acrylamide), a thermoresponsive non-ionic polymer combining the amide and the ethyleneglycolether motifs
Poly( N , N -bis(2-methoxyethyl)acrylamide) (PbMOEAm) featuring two classical chemical motifs from non-ionic water-soluble polymers, namely, the amide...
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Self-assembly in newly synthesized dual-responsive double hydrophilic block copolymers (DHBCs) in aqueous solution
Double hydrophilic diblock copolymers (DHBCs) with a zwitterionic block of poly[2-(methacryloyloxyethyl phosphorylcholine)] (PMPC) having degree of...
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Novel pH- and thermoresponsive supramolecular dendronized copolymer
Functional materials with stimulus response and simple control response have gained increasing attention from scientists due to the high demand for...
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Thermoresponsive poly(N-isopropylacrylamide) copolymer networks for galantamine hydrobromide delivery
Natural alkaloid galantamine is widely used for the treatment of Alzheimer’s disease and various other memory impairments. Galantamine hydrobromide...
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Nanosilver anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficient catalytic degradation of organic dyes
A novel alginate/poly(acrylic acid/acrylamide) double-network hydrogel composite with silver nanoparticles was successfully fabricated using the...
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Thermoresponsive Starch Hydrogel Stabilized Pd Nanoparticles: Soft Catalyst for the Preparation of (±)-α-Methylbiphenylalanine in Water Aiming at Bioorthogonal Chemistries
AbstractThe corn-starch was able to reduce Pd(II) species under relatively low concentration (5.0 wt/vol) leading to the formation of a...
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From controlled radical polymerization of vinyl ether to polymerization-induced self-assembly
Vinyl ether (VE) was long believed to be among the monomers that could not be radically homopolymerized. Therefore, to synthesize block copolymers...
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Poly(2-oxazoline)s: synthesis and biomedical applications
With the advancement of medical technology, the previous biomedical material platforms have been unable to meet the increasingly diverse application...
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Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation
Herein, we present a new route to synthesize poly(2-oxazoline)s (POx) with coumarin moieties as pendant groups that can be crosslinked by irradiation...