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Stereoselective conjugate cyanation of enals by combining photoredox and organocatalysis
Precise control over the selectivity of a reaction is a fundamental target. While great advances have been obtained in achieving stereocontrol, the...
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Copper-catalysed asymmetric radical cyanation
Catalytic asymmetric cyanation is a straightforward route to α-chiral nitriles that has previously relied on the enantioselective attack of cyanide...
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Copper-promoted domino cyanation/Ullmann coupling toward difunctionalized acenaphthylenes with various optoelectronic properties
Tremendous progress has been made on aromatic fusion of acenaphthylene towards organic semiconductors. However, scarce studies focus on the...
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Non-enzymatic catalytic asymmetric cyanation of acylsilanes
The asymmetric cyanation of acylsilanes affords densely functionalized tetrasubstituted chiral carbon centers bearing silyl, cyano, and hydroxy...
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Photoelectrochemical asymmetric catalysis enables site- and enantioselective cyanation of benzylic C–H bonds
The enantioselective functionalization of ubiquitous C( sp 3 )–H bonds is ideally suited for the construction of three-dimensional chiral structures....
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Design of a palladium nanocatalyst produced from Schiff base modified dialdehyde cellulose and its application in aryl halide cyanation and reduction of nitroarenes
In this paper, a versatile heterogeneous catalyst system (Pd-DAC-Sch) based on stabilization of palladium nanoparticles on dialdehyde cellulose...
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Palladium (II) Complex Supported on Magnetic Nanoparticles Modified with Phenanthroline: A Highly Active Reusable Nanocatalyst for the Synthesis of Benzoxazoles, Benzothiazoles and Cyanation of Aryl Halides
A well dispersed magnetically separable palladium complex (MNPs-phenanthroline-Pd) has been synthesized via the immobilization of palladium (II)...
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Recyclable and Reusable Pd(OAc)2/XPhos–SO3Na/PEG-400/H2O System for Cyanation of Aryl Chlorides with Potassium Ferrocyanide
Pd(OAc) 2 /XPhos–SO 3 Na in a mixture of poly(ethylene glycol) (PEG-400) and water is shown to be a highly efficient catalyst for the cyanation of aryl...
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Water-Dispersible Pd–N-Heterocyclic Carbene Complex Immobilized on Magnetic Nanoparticles as a New Heterogeneous Catalyst for Fluoride-Free Hiyama, Suzuki–Miyaura and Cyanation Reactions in Aqueous Media
AbstractPd– N -heterocyclic carbine complex immobilized on magnetic nanoparticles is synthesized and characterized by different techniques such as...
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Diastereoselective Pd-Catalyzed Aryl Cyanation and Aryl Borylation
In Chap. 2, a Pd-catalyzed diastereoselective anion capture cascade reaction is discussed. Building on the Pd-catalyzed carboiodination reaction en...
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Synthesis of deuterium labeled dabigatran etexilate
Dabigatran is a direct thrombin inhibitor widely applied in atrial fibrillation anticoagulation therapy. The stable isotope-labeled dabigatran...
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A general arene C–H functionalization strategy via electron donor–acceptor complex photoactivation
The photoactivation of electron donor–acceptor complexes has emerged as a sustainable, selective and versatile strategy for the generation of radical...
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Synthesis, Molecular and Crystal Structures of Some Monocyanocymantrenes
Electrophilic cyanation of the lithiated cymantrenes [(C 5 X 4 Li)Mn(CO) 3 ] (X = H, Cl) yields the corresponding monocyanocymantrenes [(C 5 X 4 CN)Mn(CO) 3 ] ( 1 ,...
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Cu-Catalyzed C-C Coupling Reactions
This book chapter intends to give the reader a timely overview of significant copper-catalyzed cross-coupling reaction advancements. Carbon–carbon...
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Poly(arylene ether nitrile) Dielectric Film Modified by Bi2S3/rGO-CN Fillers for High Temperature Resistant Electronics Fields
High-quality film capacitors are widely used in many fields such as new energy vehicles, electronic communications, etc., due to their advantages in...
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Programmable late-stage C−H bond functionalization enabled by integration of enzymes with chemocatalysis
New chemo- and biocatalytic methodology is important for the future sustainable synthesis of essential molecules. Transition metal catalysis enables...
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Transition-Metal-Based Carbon–Carbon and Carbon–Heteroatom Bond Formation for the Synthesis and Decoration of Heterocycles
A literature overview, up to the end of 2004, of the most important microwave-assisted transition-metal-mediated processes used for the decoration...
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A Chemo-enzymatic Approach for the Rapid Assembly of Tetrahydroisoquinoline Alkaloids and Their Analogs
The utilization of enzymes that catalyze sequential reactions to construct highly functionalized skeletons in a single step could expedite the total...
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Recent advances in theoretical studies on transition-metal–catalyzed regioselective C-H functionalization of indoles
Indole compounds are widely found in natural products and drug candidates. The transition-metal–catalyzed regioselective C-H bond functionalization...
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