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Hybrid Mn(II)–Cu(I) Complex Based on 1,3,5-Tris(diphenylphosphinyl)benzene
AbstractThe reaction of 1,3,5-tris(diphenylphosphinylbenzene (L) with MnI 2 in the presence of CuI (wet MeCN, 25°C, 30 min) leads to the formation of...
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Nuclear Genome-Encoded Mitochondrial OXPHOS Complex I Genes in Female Buffalo Show Tissue-Specific Differences
Buffalo physiology intricately balances energy, profoundly influencing health, productivity, and reproduction. This study explores...
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An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C-C coupling reactions
Development of transition metal-based photocatalysts with low cost, strong visible light absorption, and high efficiency is a long-stand pursuit for...
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High-Efficiency Thermally Activated Delayed Fluorescence of a Copper(I) Complex Based on Octachloro-1,10-Phenanthroline
AbstractA [Cu(phen-Cl 8 )(Xantphos)]PF 6 ·2CH 2 Cl 2 ( 1 ·2CH 2 Cl 2 ) complex based on octachloro-1,10-phenanthroline (phen-Cl 8 ) and...
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Complex Formation of Silver(I) with 1,2,3-Benzotriazole: Protonization Constants of 1,2,3-Benzotriazole
AbstractThe acid–base properties of 1,2,3-benzotriazole (Bta) at 25°C and I = 0.1 mol/L KCl are studied in an aqueous solution by the pH-metric...
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Thermodynamics of complex formation of silver(I) with substituted pyridines and cyclic amines in non-aqueous solvents
The understanding of the thermodynamic stability and speciation of metal complexes in solution requires access to their enthalpy and entropy of...
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Trans-to-cis isomerization of a platinum(II) complex with two triphosphine ligands via coordination with gold(I) ions
The reaction of a square-planar platinum(II) complex containing two bis(2-diphenylphosphinoethyl)phenylphosphine (triphos), [Pt(triphos) 2 ](NO 3 ) 2 ,...
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Synthesis of the Silver(I) Complex [Ag2[B12H12]]
AbstractA method has been developed for synthesis of high-purity silver(I) complex [Ag 2 [B 12 H 12 ]] through pyrolysis of NaВН 4 –KВF 4 mixtures at...
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Base-Free Aerobic Oxidation of Primary Alcohols to Aldehydes Catalyzed by 1,1-Di(pyridin-2-yl)urea-Functionalized SBA-15- Immobilized Copper(I) Iodide Complex
A highly efficient, heterogeneous copper(I)-catalyzed aerobic oxidation of primary aliphatic, allylic, propargylic and benzylic alcohols to aldehydes...
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Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion
AbstractNew crystalline pseudo-polymer complex [Au{S 2 CN(CH 2 ) 6 } 2 ] 4 [Ag 5 Cl 9 ] ( I ) was obtained by binding gold(III) with silver(I)...
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Method for improving adsorption capacity of gold(I) thiosulfate complex on mercapto-functionalized silica gel by masking copper with ethylenediamine
The thiosulfate method is a cyanide-free hydrometallurgical method for gold extraction, but the existence of copper ion in Cu 2+ –NH 3 –S 2 O 3 2− system is...
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STRUCTURE OF A BINUCLEAR RHODIUM(I) COMPLEX WITH THE ACENAPHTHENE- 1,2-DIIMINE LIGAND
AbstractBy the interaction of [Rh 2 (COE) 4 (μ-Cl) 2 ] (COE = cyclooctene) with 1,2-bis[(2,6-diisopropyl phenyl)imino]acenaphthene (dpp-bian) new...
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Thermodynamic Characteristics of Silver(I) Complex Formation with Selected N- and N,N'-Substituted Thioureas in Aqueous Solution
AbstractSilver(I) complex formation with thiourea (Tu), N -phenylthiourea (Phtu), N , N '-diphenylthiourea (Bphtu), N -acetylthiourea (Aсtu), and...
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Analysis of the intermediates of the catalytic system for the Chan—Evans—Lam reaction based on Cu(i) complex with N-heterocyclic carbene
The complex dynamic nature of the Chan—Evans—Lam catalytic system in the presence of CuCl complex with N-heterocyclic carbene...
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Synthesis of Benzoselenazoles Catalyzed by Copper(I) Complex Supported on Magnetic Nanoparticles
In this paper, Fe 3 O 4 @bis(phenyl-imine)-CuI nanocomposite was successfully fabricated from available martials by a simple methos and well...
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Supramolecular Dimeric Silver(I) Complex Based on the 1,1′-Bis(diphenylphosphino)ferrocene: Thermal Behaviors, Luminescence Studies and Cytotoxic Properties
A supramolecular dimeric complex [Ag(dppf)(NO 3 )] 2 was prepared via the reaction of a solution of AgNO 3 in methanol/dichloromethane with...
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Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure
AbstractThe reaction of TpReOCl(S t Bu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium...
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Optimization of hydrogen production in Enterobacter aerogenes by Complex I peripheral fragments destruction and maeA overexpression
As a concentrated energy source with high added value, hydrogen has great development prospects, with special emphasis on sustainable microbial...
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SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF HETEROLEPTIC Cu(I) DITHIOCARBAMATE COMPLEX CONTAINING DIPHENYL PHOSPHINOFERROCENE (dppf)
AbstractA new copper(I) heteroleptic pyridyl functionalized dithiocarbamate(dtc) complex, [Cu(L) 2 dppf]·2H 2 O·MeOH, ( 1 ) (where...
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New coordination mode of Lasalocid in its dinuclear lithium(I) complex
A new lithium(I) complex of the polyether ionophorous antibiotic Lasalocid (LasH) was synthesized and structurally characterized by single-crystal...