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Molecular insights of nanozymes from design to catalytic mechanism
Emerging as cost-effective potential alternatives to natural enzymes, nanozymes have attracted increasing interest in broad fields. To exploit the...
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Catalytic mechanism for Renilla-type luciferases
The widely used coelenterazine-powered Renilla luciferase was discovered over 40 years ago, but the oxidative mechanism by which it generates blue...
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Elucidating the reaction mechanism of a palladium-palladium dual catalytic process through kinetic studies of proposed elementary steps
In the synergistic dual catalytic process, the kinetics of the catalytic cycles must be balanced for the successful outcome of the reaction....
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Catalytic effect and mechanism of graphene-salen Fe nanocomplex on the pyrolysis of energetic TKX-50
Various graphene-salen iron nanocomplex S-551-Fe, S-602-Fe, S-902-Fe, S-590-Fe, S-792-Fe and S-550-Fe were successfully synthesized using different...
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Analysis of liquid products and mechanism of thermal/catalytic pyrolysis of HDPE
The experiments of rapid thermal pyrolysis and catalytic pyrolysis of high density polyethylene (HDPE) were carried out using Py-GC/MS. The...
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Cascade and Sequential Catalytic Transformations Initiated by Ruthenium Catalysts
Ruthenium holds a prominent position among the efficient transition metals involved in catalytic processes. Molecular ruthenium catalysts are able...
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Studies on Effective Photo-catalytic Degradation of Rhodamine-B Using Metal-Doped Oxidized-Activated Carbon: Kinetics, Isotherm Models and Degradation Mechanism
Utilization of the biomass with simple preparation method is one of the keys to prepare cost-effective photocatalysts. Photo-catalysts such as...
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Study on CO catalytic oxidation mechanism on Pd/CeO2 surface models: the effect of oxygen vacancies on CO catalytic oxidation reaction
Palladium supported on ceria, Pd/CeO 2 , is one of the main components in modern three-way catalysts, which has been widely applied in the treatment of...
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The catalytic mechanism and limiting factor of polyamide hydrolysis for chemical recycling: the classic hydrolysis of polyamide 4
A series of chemical recycling methods have been developed for polyamides (PAs) for green and sustainable technologies of plastic waste. However, the...
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Molecular insights into the catalytic mechanism of plasticizer degradation by a monoalkyl phthalate hydrolase
Phthalate acid esters (PAEs), a group of xenobiotic compounds used extensively as plasticizers, have attracted increasing concern for adverse effects...
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Hydrogen cyanide catalytic hydrolysis mechanism by Al-doped graphene: A density functional theory study
ContextThe hydrogen cyanide (HCN) hydrolysis reaction mechanism over Al-doped graphene was investigated through the density functional theory method....
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Construction of starch-based bionic glutathione peroxidase and its catalytic mechanism
Glutathione peroxidase (GPx) is an important selenium-containing antioxidant enzyme in human body. The preparation of bionic GPx and the mimicry of...
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Green Catalytic Hydrogenation of Phthalate Plasticizers
This book provides an overview of plasticizers, from the latest global research developments to the laws and regulations applied to their use. In...
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Development of a microbial protease for composting swine carcasses, optimization of its production and elucidation of its catalytic hydrolysis mechanism
BackgroundDead swine carcass composting is an excellent method for harmless treatment and resource utilization of swine carcass. However, poor...
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Mechanism of catalytic migration of the double bond in 2-vinylnorbornanes
Liquid-phase hydrogenation of 5-vinylbicyclo[2.2.1]hept-2-ene (5-vinyl-2-norbornene, VNE) existing as a mixture of endo - and exo -isomers in the...
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Anatomy of Catalytic Centers in Phillips Ethylene Polymerization Catalyst
A relevant fraction of the polyethylene produced in the world (about 30%) is obtained with the Phillips process. Many efforts in the last 30 years...
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Catalytic cycle of formate dehydrogenase captured by single-molecule conductance
Understanding the mechanisms and kinetics of enzymatic reactions is essential for studies of life science and for bioengineering. Here the different...
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Carbon-based nanozymes: design, catalytic mechanisms, and environmental applications
Carbon-based nanozymes are synthetic nanomaterials that are predominantly constituted of carbon-based materials, which mimic the catalytic properties...
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Non-catalytic and Catalytic Co-pyrolysis of Lignocellulosic-Lignocellulosic Waste
The present investigation involves non-catalytic and catalytic co-pyrolysis. The mixture of sesame oil cake and jute waste sacks in the ratio 1:1 was...