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Palladium Catalyzed Cascade Reactions Involving π-Allyl Palladium Chemistry
Palladium-catalyzed cascade reactions have gained steadily increasing importance over the last decade. The important factor in these reactions is...
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Cascade Reactions Involving Pauson–Khand and Related Processes
The Pauson–Khand [2 + 2 + 1] cycloaddition is one of the best ways to construct a cyclopentenone. It implies the formation of three new bonds and...
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Catalytically generated noncovalent ammonium dienolate: a versatile platform for the development of organocatalytic asymmetric cascade reactions
Organocatalytic cascade reactions represent a powerful strategy for the rapid construction of complex chiral molecules with multiple stereocenters...
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Pickering emulsion droplets and solid microspheres acting synergistically for continuous-flow cascade reactions
Integration of multiple incompatible catalysts in one continuous-flow reaction system is of paramount significance for green synthetic chemistry....
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Heterocycles from Cascade Reactions via Carbene gem-Difunctionalization
Cascade reactions via metal carbene gem-difunctionalization, which are initiated by metal-catalyzed carbene formation, followed by nucleophilic...
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Complex Polycyclic Molecules from Acyclic Precursors via Transition Metal-Catalyzed Cascade Reactions
This review gives an insight into the growing field of transition metal-catalyzed cascades. More particularly, we have focused on the construction...
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Cascade asymmetric dearomative cyclization reactions via transition-metal-catalysis
Catalytic asymmetric dearomatization (CADA) reactions offer an efficient strategy for directly converting aromatic compounds into chiral cyclic...
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The Virtue of Michael-Type Addition Processes in the Design of Transition Metal-Promoted Cyclizative Cascade Reactions
Cascade reactions involving a transition metal-promoted step and a Michael-type addition process have emerged as a powerful tool to construct...
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Regiospecific C–H amination of (−)-limonene into (−)-perillamine by multi-enzymatic cascade reactions
Background(−)-Limonene, one of cyclic monoterpenes, is an important renewable compound used widely as a key building block for the synthesis of new...
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Design and Synthesis of Silica Supported Pd Nanoparticles: Application to Cascade Reactions
Transition metal-catalyzed tandem reactions are highly prominent in organic synthesis. Especially, palladium-catalyzed biscarbofuctionalization of...
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Synthesis of Spiro[imidazo[2,1-b]thiazole-2,3'-thiophenes] via Sulfa-Michael/Aldol Cascade Reactions
AbstractThe sulfa-Michael/aldol cascade reaction of ( Z )-2-(arylmethylene)-5,6-dihydroimidazo[2,1- b ]thiazol-3(2 H )-ones and 1,4-dithiane-2,5-diol...
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Theranostic nanosystem mediating cascade catalytic reactions for effective immunotherapy of highly immunosuppressive and poorly penetrable pancreatic tumor
The dense desmoplastic stroma and immunosuppressive microenvironment of pancreatic cancer hinder the penetration of drugs and induce a considerable...
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Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes
Hybrid fused two-dimensional/three-dimensional (2D/3D) rings are important pharmacophores in drugs owing to their unique structural and...
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Rapid and Cost-Effective On-site Detection of Plant Viruses Using Personal Glucose Meters Integrated with LAMP and Cascade Enzymatic Reactions
This study presents a novel method for detecting plant viruses by combining a personal glucose meter (PGM)-based cascade enzymatic reaction (CER)...
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Cascade and Sequential Catalytic Transformations Initiated by Ruthenium Catalysts
Ruthenium holds a prominent position among the efficient transition metals involved in catalytic processes. Molecular ruthenium catalysts are able...
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Biocatalytic cascade to polysaccharide amination
BackgroundChitin, the main form of aminated polysaccharide in nature, is a biocompatible, polycationic, and antimicrobial biopolymer used extensively...
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Immobilized enzyme cascade for targeted glycosylation
Glycosylation is a critical post-translational protein modification that affects folding, half-life and functionality. Glycosylation is a...
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Integration of enzyme immobilization and biomimetic catalysis in hierarchically porous metal-organic frameworks for multi-enzymatic cascade reactions
Multiple enzymes-induced biological cascade catalysis is indispensable in biotechnology and industrial processes. Nevertheless, the drawbacks of most...
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Tandem Radical Reactions
Radical tandem reactions—and in a wider context radical dominos or cascades—have attracted a lot of attention because of their intrinsic elegance...
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Domino Heck-Pericyclic Reactions
Palladium-catalyzed cross-coupling reactions and cycloadditions as well as electrocyclic transformations can efficiently be combined in one-pot...