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Carbonylation and Other Transformations of Polyfluorobenzocyclobutenols in Superacids
AbstractAcid-catalyzed carbonylation of a series of polyfluorinated benzocyclobuten-1-ols, as well as cyclic sulfuric acid esters derived from...
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Enantioselective synthesis of β- and α-amino ketones through reversible alkane carbonylation
The direct incorporation of alkanes and CO into value-added chiral products through alkane carbonylation is a desirable transformation; however, it...
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Specific detection of protein carbonylation sites by 473 nm photodissociation mass spectrometry
The study of protein oxidation remains a challenge despite the biomedical interest in reliable biomarkers of oxidative stress. This is particularly...
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Dimethyl Ether Carbonylation in the Presence of an H-MOR Zeolite Modified with Copper, Cobalt, and Magnesium
AbstractThe adsorption, temperature-programmed desorption, and carbonylation of dimethyl ether (DME) in the presence of mordenite and ferrierite (SiO
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Catalysts for Carbonylation of Alcohols to Obtain Carboxylic Acids and Esters
AbstractCarbonylation of alcohols with CO is one of synthetic routes to carboxylic acids and esters, which are demanded by chemical and...
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Synthesis of non-equivalent diamides and amido-esters via Pd-catalysed carbonylation
Given the widespread use of amides in chemistry and biology, the development of methods for their synthesis remains important. Although the...
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Palladium-catalyzed enantioselective carbonylation reactions
Carbonylation, one of the most powerful approaches to the preparation of carbonylated compounds, has received significant attention from researchers...
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Extension of Highly Efficient Alcohol-promoted Rearrangement into One-pot Domino Palladium-catalyzed Carbonylation for Sterically Crowded Aromatic Six-membered Imides
A romatic six-membered imides suffer the introduction of bulky substituents at the imide positions due to the formation of isoimides and low...
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Process modeling of syngas conversion to ethanol and acetic acid via the production of dimethyl ether and its carbonylation
A process model was developed to simulate the generation of ethanol or acetic acid by selectively using syngas from coke oven gas as the carbon...
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One-pot carbonylation-dehydration tandem reaction of aryl iodides with acylhydrazines for synthesis of 2,5-diaryl-1,3,4-oxadiazoles
The structures of 2,5-diaryl-1,3,4-oxadiazoles with good stability have attract great attention for development of new and safe therapeutic agents...
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Nickel–copper catalysts supported by boron and nitrogen co-doped activated carbon for gas phase carbonylation of ethanol
In this paper, nitrogen-doped, boron-doped and boron and nitrogen co-doped activated carbon supported nickel–copper was used as catalyst for ethanol...
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Methyl Acetate Synthesis by Dimethyl Ether Carbonylation in the Presence of Zeolites: A Review
AbstractThe review analyzes the specific features of methyl acetate synthesis by dimethyl ether carbonylation in the presence of zeolite catalysts....
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Oxidative Carbonylation of Methane to Acetic Acid over Commercial Rodium-Modified ZSM-5 Zeolites
AbstractThe paper shows that introducing rhodium into zeolite significantly enhances the catalytic performance of the system. Rh/IK(UST), a catalyst...
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Palladium-catalyzed asymmetric carbamoyl-carbonylation of alkenes
An unprecedented palladium-catalyzed asymmetric carbamoyl-carbonylation of tethered alkenes with CO and alcohols has been developed. This reaction...
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Mechanistic insight into the synergistic Cu/Pd-catalyzed carbonylation of aryl iodides using alcohols and dioxygen as the carbonyl source
Pd-catalyzed carbonylation, as an efficient synthetic approach to the installation of carbonyl groups in organic compounds, has been one of the most...
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Oscillatory carbonylation of poly(ethylene glycol)methyl ether acetylene. Improved model of reaction mechanism
The study presents a mathematical model of Bruk Temkin-Gorodsky Novakovic (BT-GN) reaction system employing palladium-catalyzed oscillatory...
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Difluoroalkylative carbonylation of alkenes to access carbonyl difluoro-containing heterocycles: convenient synthesis of gemigliptin
Fluorinated heterocycles play a vital role in pharmaceutical and agrochemical industries. Hence, rapid and efficient construction of fluorinated...
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Contributions of post-synthesized mesopore structures of ferrierite zeolite for gas-phase dimethyl ether carbonylation activity
Mesoporous ferrierite zeolite (FER) synthesized by a post-desilication method was applied for a gas-phase dimethyl ether (DME) carbonylation to...
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Functionalized Au15 nanoclusters as luminescent probes for protein carbonylation detection
Atomically precise, ligand-protected gold nanoclusters (AuNCs) attract considerable attention as contrast agents in the biosensing field. However,...
