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Phosphinidenes
Of the low-valent organophosphorus compounds phosphinidenes occupy a special place. In ‘free’ phosphinidenes the phosphorus atom carries a single...
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Photoinduced Reactions of Metal Carbenes in Organic Synthesis
The photoinduced reactions of metal carbene complexes, particularly Group 6 Fischer carbenes, are comprehensively presented in this chapter with a...
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Crystalline cyclic (alkyl)(amino)stannylene via transient stannyne
We demonstrate that a bulky cyclic amino ligand, specifically 1,1,3,3-tetraphenylisoindolinyl, can facilitate the formation of a transient stannyne,...
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Hierarchical self-assembly of crown ether based metal-carbene cages into multiple stimuli-responsive cross-linked supramolecular metallogel
The hierarchical self-assembly (HSA) strategy widely utilized in biological systems has been applied in artificial systems to orchestrate small...
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Biomacromolecule supported N-heterocyclic carbene-palladium(II) as a novel catalyst for Suzuki–Miyaura and Mizoroki–Heck cross-coupling reactions
The field of catalysis is ever flourishing to meet the challenges faced in our day-to-day needs kee** in mind the environmental concerns. In line...
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Organometallacycles as Intermediates in Oxygen-Transfer Reactions. Reality or Fiction?
Organometallacyclic compounds have been suggested as intermediates in several transition metal mediated oxidation reactions without direct...
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Complex Polycyclic Molecules from Acyclic Precursors via Transition Metal-Catalyzed Cascade Reactions
This review gives an insight into the growing field of transition metal-catalyzed cascades. More particularly, we have focused on the construction...
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Anatomy of Catalytic Centers in Phillips Ethylene Polymerization Catalyst
A relevant fraction of the polyethylene produced in the world (about 30%) is obtained with the Phillips process. Many efforts in the last 30 years...
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Microkinetic modelling in computational homogeneous catalysis and beyond
DFT models have been repeatedly demonstrated to be able to supply fundamental information on chemical processes through molecular insights into their...
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Carbene Complexes of Heme Proteins and Iron Porphyrin Models
The possible formation of carbene complexes of cytochromes P450 enzymes in various metabolisms of xenobiotics is first described. In view of these...
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Isolable dicarbon stabilized by a single phosphine ligand
In contrast to naturally occurring F 2 , O 2 and N 2 , diatomic C 2 is an intriguing species that has only been observed indirectly in the gas phase, and...
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Effects of N-substitution on CO2 trap** by cyclic vinylidenes at DFT levels
Carbenes are anticipated to interact with different greenhouse gases including CH 4 , N 2 O, CO 2 , etc. Here, CO 2 trap** of singlet (s) and triplet (t)...
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Organic Reactions and Their Mechanisms
Unlike inorganic reaction which take place between ions, the organic reactions are basically molecular in nature. An organic reaction takes place by...
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Electronic Structure and Reactivity of Metal Carbenes
Metal carbenes have for a long time been classified as Fischer or Schrock carbenes depending on the oxidation state of the metal. Since the...
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Chromium-Templated Benzannulation and Haptotropic Metal Migration
This review highlights the recent development in intramolecular migration of metal templates along fused arene skeletons. The focus is on the...
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Cycloaddition Reactions of Group 6 Fischer Carbene Complexes
Group 6 heteroatom-stabilised carbene complexes (Fischer carbene complexes) offer many interesting possibilities to build rings (carbocycles and...
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Cyclopropanation with Ruthenium Catalysts
In this decade, a variety of ruthenium complexes have been intensively investigated that exhibit catalytic activity for cyclopropanation of olefins...
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Tetrel-bond interactions involving boron-substituted carbenes
The tetrel-bonded complexes formed between the selected boron-substituted carbenes and TH 3 F (T = C, Si, Ge, Sn, Pb) have been explored by using the...
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Metal Carbene Reactions from Dirhodium(II) Catalysts
The dirhodium(II) core is a template onto which both achiral and chiral ligands are placed so that four exist in a paddle wheel fashion around the...
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Advances in Metal-Catalyzed Denitrogenative Pathways for N-Heterocycle Synthesis
For more than a century, cutting-edge research in organic chemistry has been the discovery of novel, powerful synthetic procedures to create very...
