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Switchable aqueous catalytic systems for organic transformations
In living organisms, enzyme catalysis takes place in aqueous media with extraordinary spatiotemporal control and precision. The mechanistic knowledge...
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Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent
This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain...
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Functional Cellulose Materials Fabricated by Using Ionic Liquids as the Solvent
Cellulose is one of the most abundant natural polymers in the nature, which has many attractive advantages, such as renewability, biodegradability,...
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Role of Ionic Liquids as Solvent & Catalyst for Heck and Suzuki Reactions: A Comprehensive Review
Ionic liquids (ILs) have overcome solutions to problems associated with increased production with sustainable green approaches over the last three...
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Dynamic two-dimensional covalent organic frameworks
Porous covalent organic frameworks (COFs) enable the realization of functional materials with molecular precision. Past research has typically...
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Growing Impact of Ionic Liquids in Heterocyclic Chemistry
In the quest for replacing the conventional toxic organic solvents, a continual effort has been made in fabricating a solvent that is versatile,...
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Surface Rearrangement of Diblock Copolymer Brushes—Stimuli Responsive Films
This article reviews results from our group of the synthesis and characterization of diblock copolymer brushes. Results from the literature are...
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Chromium-Templated Benzannulation and Haptotropic Metal Migration
This review highlights the recent development in intramolecular migration of metal templates along fused arene skeletons. The focus is on the...
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Hydrogen Bond-Assembled Synthetic Molecular Motors and Machines
Nature uses molecular motors and machines in virtually every significant biological process but learning how to design and assemble simpler...
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Development of CO2-Mediated Switchable Hydrophilicity Solvent-Based Microextraction Combined with HPLC-UV for the Determination of Bisphenols in Foods and Drinks
In traditional dispersive liquid-liquid microextraction procedures, both extraction and dispersive solvents are required, and thus, it increases the...
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Templated Synthesis of Interlocked Molecules
Mechanically interlocked molecular compounds can be synthesized in high yields by using template-directed assistance to covalent synthesis. Catenanes...
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Solvent-Mediated 1,ω-Bis(isoquinoline)alkane/Iodobismuthate Hybridized Isomers: Structures and Packing Mode Dependent-Photoluminescence/Thermochromisms
The hybridization of 1,4-bis(isoquinoline)butane (BIQBT 2+ ) cation with iodobismuthate under different solvents produce two isomers α-[(BIQBT)(BiI 4 ) 2 ] n ...
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Lewis Acid−Base Pairs for Polymerization Catalysis: Recent Progress and Perspectives
Lewis pair polymerizationPolymerization (LPP), catalyzed by frustrated Lewis pairs (FLPs), Frustrated Lewis pair (FLP) interacting LPs (ILPs), or...
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Controlling oncogenic KRAS signaling pathways with a Palladium-responsive peptide
RAS oncoproteins are molecular switches associated with critical signaling pathways that regulate cell proliferation and differentiation. Mutations...
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Tunable molecular editing of indoles with fluoroalkyl carbenes
Building molecular complexity from simple feedstocks through precise peripheral and skeletal modifications is central to modern organic synthesis....
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Sequence structure controllable polymerization-induced self-assembly
Polymerization-induced self-assembly (PISA) combines synthesis and self-assembly of artificial polymers in one-pot, which brings us one step closer...
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Recent Advances in Nickel-Catalyzed C-C Cross-Coupling
Transition metal-catalyzed carbon–carbon bonds formation is a fundamental process and has attracted much attention in the synthetic chemistry...
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Functionalization of nanocellulose using atom transfer radical polymerization and applications: a review
AbstractNanocellulose has become a research hotspot in the field of green, sustainable materials owing to its abundant availability and excellent...
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A Mechanistic Analysis of Dehydrogenation Reactions with First-Row Transition Metal Complexes
Over the past decade, the dominance of first-row transition metals in catalytic dehydrogenation reactions has outpaced traditional precious...
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Metal-Dependent Base Pair Switching of N,N-Dicarboxymethyl-5-Aminouracil Nucleosides
The base pair switching of UOH has had limited application because it requires the consecutive introduction of multiple UOH bases into DNA strands....