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Binuclear Co(II), Ni(II), and Cu(II) Hexafluoroacetylacetonates with Spin-Labeled Nitrophenols
AbstractThe interaction of mono- and tetranuclear hexafluoroacetylacetonates [M 4 (hfac) 4 (OMe) 4 (MeOH) 4 ] (where М = Co, Ni) and [Cu 4 (hfac) 4 (OMe) 4 ] with...
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New binuclear Cu (II) complex: synthesis, structural elucidation, cytotoxic and DNA-binding evaluation
A novel copper complex [Cu(μ 2 –OH)(1,10-phenanthroline)(4-aminobenzenesulfonic acid)·3H 2 O] 2 ( 1 ) was synthesized and characterized by X-ray...
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Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines
AbstractThe reactions of Cu(II), Co(II), and Zn(II) terephthalates with hydroxyalkylamines (tris(2-hydroxyethyl)amine, bis(2-hydroxyethyl)amine,...
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New Binuclear Copper(II) Complex Based on 1,2-Bis(2-(4,4,4-trifluoro-1,3-dioxobutyl)phenoxyethane: Synthesis and Structure
AbstractNew binuclear complex 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethanedi(dimethylformamide)dicopper(II) is synthesized,...
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Two binuclear copper(II) complexes incorporated with 3-phenylpentanedioic acid: crystal structure and bioactivity characteristics
Two complexes were synthesized utilizing Cu(II) ions as central building blocks and incorporating 3-phenylpentanedioic acid and a nitrogen-containing...
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Zn (II), Cu (II), Co (II), and Ni (II) complexes bearing aza-heterocyclic ligands: synthesis, characterization, and anticancer activities
Due to their structural arrangements, coordination complexes have shown potential to combat various human diseases. Nitrogen heteroatoms are a...
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Theoretical Studies of Magnetic Properties of Acetic Acid Bridged Binuclear Cu(II) Complex {Cu2(μ2-O2CCH3)4} (N2C4H4)2
AbstractThe magnetic properties of the binuclear Cu(II) complex {Cu 2 (μ 2 -O 2 CCH 3 ) 4 }(N 2 C 4 H 4 ) 2 were studied using density functional theory combined...
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Magnetism in Binuclear Compounds: Theoretical Insights
This chapter is devoted to theoretical calculations aimed at determining the electronic structure of binuclear complexes, including isotropic and...
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Transition Metal (Zn(II), Co(II), Cu(II), Ni(II)) Complexes for the Removal of Acidic Sulfur Impurities from Hydrocarbon Fuel
AbstractThe review addresses the main approaches to desulfurization of hydrocarbon products by adsorption methods. Examples of the use of various...
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Generation of Long-Lived Phenoxyl Radical in the Binuclear Copper(II) Pivalate Complex with 2,6-Di-tert-butyl-4-(3,5-bis(4-pyridyl)pyridyl)phenol
AbstractA new binuclear copper(II) complex Cu 2 (Piv) 4 (L) 2 , where Piv – = pivalate, L = 2,6-di- tert -butyl-4-(3,5-bis(4-pyridyl)pyridyl)phenol, was...
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Binuclear Pd(II) complexes with multidentate Schiff base ligands: synthesis, catalysis, and antibacterial properties
Three new binuclear palladium(II) complexes with multidentate Schiff base ligands were synthesized and characterized by FT-IR, UV–Vis, 1 H-NMR,...
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Synthesis, Structural Characterization, Molecular Docking, Thermal Studies, and Antimicrobial Activity of Ni(II) Binuclear Complexes
AbstractA new hexadentate ligand, 3,3′-{(1 E ,1′ E )-[(4-chloro-1,2-phenylene)bis(azaneylylidene)]bis(methaneylylidene)}bis(2-hydroxybenzoic acid) (H 4 L)...
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Complexes of Cu(II), Ni(II), Co(II), and Ag(I) Metals with 1,4-Bis(3-Phenyl Triazenil) Benzene
AbstractNew complexes of Cu(II), Ni(II), Co(II) and Ag(I) with 1,4-bis(3-phenyl triazenyl) benzene are obtained. Using the methods of IR, EPR,...
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Synthesis and Structure of Cu(II) and Co(II) Complexes with N-{2-[(E)-(4-Cyclohexylphenyl)Iminomethyl]Phenyl}-4-Methylbenzene-1-Sulfonamide
AbstractNew Cu(II) and Co(II) complexes with the N-{2-[(E)-(4-cyclohexylphenyl)iminomethyl]phenyl}-4-methylbenzene-1-sulfonamide Schiff base are...
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Synthesis, Crystal Structure, and Activity of Cu(II) and Zn(II) Complexes of 2-Mercaptoquinoline N-Oxide
AbstractThe mononuclear Cu(II) complex, Zn(II) complex, and homodinuclear Zn(II)-Zn(II) complex of 2-mercaptoquinoline N -oxide, have been...
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Complexation of Zn(II) and Cu(II) by Perfluorinated β-Diketones: Theoretical and Experimental Approaches and Potential Use as Copper-Eliminating Agents
Aqueous chelation of six perfluorinated β-diketones with copper(II) and zinc(II) was studied under various conditions. Complexation with...
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Binuclear Complexes of Cu(II) and Mg(II) with 2-Furancarboxylic Acid: Synthesis, Structure, EPR Spectroscopy, and Results of In Vitro Biological Activity against Mycolicibacterium Smegmatis and SCOV3
AbstractUsing the reactions of copper(II) acetate magnesium(II) oxide with 2-furancarboxylic acid (HFur), compounds with chemical compositions [Cu 2 (Fur)...
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AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX
AbstractA new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II) 2 Ca(II)] complex has been successfully...
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Electrocatalytic Hydrogen Evolution by Binuclear Metal (M=Co, Fe, Mn) Xanthine Bridged Bis-corrole
Three binuclear metal (M=Co, Fe, Mn) xanthine bridged bis-corrole complexes were synthesized and investigated as electrocatalysts for the hydrogen...
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Structures and Magnetic Properties of Binuclear Co(II) and Dy(III) Complexes with Cis-1,3-Dibenzyl-2-Imidazolidone-4,5-Dicarboxylic Acid of Variable Conformations
Two new complexes [Co 2 (bia) 2 (2,2′-bpy) 2 ] ( 1 ) and [Dy 4 (bia) 6 (2,2′-bpy) 2 (H 2 O) 2 ]·8H 2 O ( 2 ) (H 2 bia = cis-1,3-dibenzyl-2-imidazolidone-4,5-dicarboxylic...
