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Facile synthesis of CuO/Cu-MOF/GO for efficient photocatalytic benzene hydroxylation to phenol
Phenols are one of the most important classes of raw materials in the chemical industry, and a variety of compounds are derived from them. The direct...
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2D RGO nanosheets supported anti-spinel NiFe2O4 nanocubes for efficient hydroxylation of phenol
A novel type of nanocomposite containing anti-spinel NiFe 2 O 4 nanocrystals and reduced graphene oxide (RGO) is successfully reported for boosting the...
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Critical enzyme reactions in aromatic catabolism for microbial lignin conversion
The application of microbes to valorize aromatic compounds derived from the abundant plant biopolymer lignin is a rapidly develo** area of research...
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Exploring the role of flavin-dependent monooxygenases in the biosynthesis of aromatic compounds
Hydroxylated aromatic compounds exhibit exceptional biological activities. In the biosynthesis of these compounds, three types of hydroxylases are...
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Preparation, characterization and stability of cross linked nitrilase aggregates (nitrilase–CLEAs) for hydroxylation of 2-chloroisonicotinonitrile to 2-chloroisonicotinic acid
Nitrilases capable of performing hydroxylation of 2-chloroisonicotinonitrile to 2-chloroisonicotinic acid were screened, and ES-NIT-102 was the best...
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Metabolic Engineering of the Shikimic Acid Pathway in Escherichia coli for Production of Derived Aromatic Compounds
The microbial production of aromatic compounds derived from various intermediates of the shikimic acid (SHK) pathway comprise a great diversity of...
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Unified short syntheses of oxygenated tricyclic aromatic diterpenes by radical cyclization with a photoredox catalyst
The biomimetic two-phase strategy employing polyene cyclization and subsequent oxidation/substitution is an effective approach for divergent...
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Modeling the hydroxylation of estragole via human liver cytochrome P450
Natural compounds derived from plants are generally regarded safe and devoid of adverse effects. However, there are individual ingredients that...
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Complex regulation in a Comamonas platform for diverse aromatic carbon metabolism
Critical to a sustainable energy future are microbial platforms that can process aromatic carbons from the largely untapped reservoir of lignin and...
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Catalytic Mechanisms and Active Species of Benzene Hydroxylation Reaction System Based on Fe-Based Enzyme-Mimetic Structure
Subject to the shortcomings of traditional heterogeneous materials (such as the limited controllability of the preparation process, the complex...
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Amorphous Vanadium Oxide Supported on Activated Carbon Prepared by Dielectric Barrier Discharge as an Efficient and Stable Catalyst for Hydroxylation of Benzene to Phenol
Effective and selective catalytic oxidation of benzene under moderate conditions remains a significant challenge. The surface properties of amorphous...
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β-Hydroxylation of α-amino-β-hydroxylbutanoyl-glycyluridine catalyzed by a nonheme hydroxylase ensures the maturation of caprazamycin
Caprazamycin is a nucleoside antibiotic that inhibits phospho- N -acetylmuramyl-pentapeptide translocase (MraY). The biosynthesis of nucleoside...
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QSAR Approach in Study of Mutagenicity of Aromatic and Heteroaromatic Amines
In this chapter we give an overview on QSAR models for treating the mutagenicity of cyclic amines. An extensive discussion is focused on the...
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A 4-hydroxybenzoate 3-hydroxylase mutant enables 4-amino-3-hydroxybenzoic acid production from glucose in Corynebacterium glutamicum
BackgroundMicrobial production of aromatic chemicals is an attractive method for obtaining high-performance materials from biomass resources. A...
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Photocatalytic Degradation of Polycyclic Aromatic Hydrocarbons by Ag3PO4/MoS2 Composite
Polycyclic aromatic hydrocarbons (PAHs) are of increasing concern due to their environmental persistence, toxicity, and potential for...
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Selective aqueous oxidation of aromatic alcohols under solar light in the presence of TiO2 modified with different metal species
A set of metals modified TiO 2 photocatalysts were prepared starting from titanium tetraisopropoxyde and different metal precursors to study the...
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Recent Progress on Peroxidase Modification and Application
Peroxdiase is one of the member of oxireductase super family, which has a broad substrate range and a variety of reaction types, including...
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Rational Designed Polymer as a Metal-Free Catalyst for Hydroxylation of Benzene to Phenol with Dioxygen
AbstractDirect hydroxylation of benzene to phenol with dioxygen is a green route for synthesis of phenol. The higher bonding energies of C–H in...
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Regioselective and enantioselective propargylic hydroxylations catalyzed by P450tol monooxygenases
Regioselective and enantioselective hydroxylation of propargylic C-H bonds are useful reactions but often lack appropriate catalysts. Here a green...
