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Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation
The development of novel strategies to rapidly construct complex chiral molecules from readily available feedstocks is a long-term pursuit in the...
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Catalytic asymmetric synthesis of sulfur-containing atropisomers by C-S bond formations
Chiral organosulfur compounds are not only widely distributed in bioactive natural products and pharmaceuticals, but also play a significant role in...
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Radical approaches to C–S bonds
Organosulfur functionalities are ubiquitous in nature, pharmaceuticals, agrochemicals, materials and flavourants. Historically, these moieties were...
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Stereoselectivity in Pd-catalysed cross-coupling reactions of enantioenriched nucleophiles
Advances in Pd-catalysed cross-coupling reactions have facilitated the development of stereospecific variants enabling the use of configurationally...
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Visible light-promoted alkylation of imines using potassium organotrifluoroborates
A mild, redox-neutral, alkylation of imines with potassium alkyl-trifluoroborates is described. The reaction proceeds under photo-redox conditions at...
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Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling
The traditional transition metal-catalyzed cross-coupling reaction, although well suited for C(sp2)–C(sp2) cross-coupling, has proven less amenable...
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Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes
The first catalytic enantioselective nucleophilic borylation of carbonyl compound has been achieved. A series of aldehydes reacted with a diboron...
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Cesium carbonate as a mediated inorganic base in some organic transformations
Cesium carbonate is a type of alkali carbonate salt having a remarkable number of applications and has been demonstrated to be a mild inorganic base...
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Improving Transformations Through Organotrifluoroborates
Organotrifluoroborates have emerged as choice reagents for a number of diverse transformations, providing reactivity patterns that complement those...
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Bibliographical Backgrounds
The cyanamide moiety consists of a nitrogen atom bearing a nitrile group. When the nitrogen atom is substituted with a carbonyl group, one speaks of...
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Organotrifluoroborate Preparation
A novel route for the preparation of a wide range of organotrifluoroborate salts with different counter cations is described. It is a safe, rapid and...