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Synthesis of Hantzsch poly-substituted pyridines containing adamantyl moiety
A one-step procedure has been developed for the synthesis of new Hantzsch poly-substituted pyridines from a three-component reaction of N -(adamantan-1...
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Synthesis of 2-adamantyl-containing amines as compounds with potential pharmacological activity
The regularities of the reduction of unsaturated nitriles containing the 2-adamantyl fragment with lithium aluminum hydride and nickel—aluminum alloy...
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STRUCTURE OF SOME ADAMANTYL-CONTAINING UREAS AND HYDROGEN BONDS IN THEIR CRYSTALS
AbstractMolecular and crystal structures of five substituted urea derivatives with bulky adamantyl fragments in their substituents are considered. It...
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Synthesis of 1-(1-Adamantyl)-2-[4-(1H-imidazol-1-ylmethyl)phenoxy]ethanone Derivatives
AbstractTwo methods have been developed for the first synthesis of 1-(1-adamantyl)-2-[4-(1 H -imidazol-1-ylmethyl)phenoxy]ethanone derivatives by the...
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Adamantyl-Substituted Triplet Diradical: Synthesis, Structure, Redox and Magnetic Properties
AbstractA stable diradical 2-{ N -[(3s,5s,7s)-adamantyl-1]- N -oxylamino}-4,4,5,5-tetramethyl-4,5-dihydro-1 H -imidazole-3-oxide-1-oxyl—a heteroatomic...
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Chemistry of vinylidene complexes—XXVII—new µ-vinylidene MnPt complexes with platinum-coordinated 1-adamantyl isocyanide ligand: spectroscopic, structural and electrochemical study
New binuclear MnPt µ-vinylidene complexes Cp(CO) 2 Mn(µ-C=CHPh)Pt(CN–Ad)(L) [L=PPh 3 ( 1a ), P(OPr i ) 3 ( 2a )] bearing a terminal platinum-coordinated...
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Thermal Stability Study of 4-(1-Adamantyl)phenol
AbstractThe thermal stability of 4-(1-adamantyl)phenol has been studied in the temperature range of 703–753 K, the components of the thermolysis...
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Synthesis, structure, and antiviral properties of novel 2-adamantyl-5-aryl-2H-tetrazoles
The reaction of 5-aryl- NH -tetrazoles with adamantan-1-ol in concentrated sulfuric acid proceeds regioselectively with the formation of the...
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Synthesis of new efficient and selective carboxylesterase inhibitors based on adamantyl and citronellyl 4,4,4-trifluoro-2-arylhydrazonylidene-3-oxobutanoates
A series of new adamantyl and citronellyl 4,4,4-trifluoro-2-arylhydrazinylidene-3-oxo-butanoates was synthesized. The synthesized compounds in...
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Experimental and DFT investigation of structure and IR spectra of H-bonded associates of p-(3-carboxy-1-adamantyl)thiacalix[4]arene
The IR spectra of p -(3-carboxy-1-adamantyl)thiacalix[4]arene ( 1 - AdCOOHTC4A ) have been studied. IR spectra of crystalline 1 - AdCOOHTC4A obtained at...
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A novel polymethyl methacrylate (PMMA) with excellent optical and thermal properties-bearing hydroxyadamamtyl substituent
Polymethyl methacrylate (PMMA) is an important thermoplastic polymer and a versatile lithographic resist. However, the low heat resistance and low...
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Study of SQ109 analogs binding to mycobacterium MmpL3 transporter using MD simulations and alchemical relative binding free energy calculations
N -geranyl- N ΄-(2-adamantyl)ethane-1,2-diamine (SQ109) is a tuberculosis drug that has high potency against Mycobacterium tuberculosis (Mtb) and may...
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Reactions of 1,3-dehydroadamantane with polyfluorinated alcohols
A one-step synthesis of hard-to-reach adamantyl polyfluoroalkyl ethers in yields up to 95% comprises the reaction of strained 1,3-dehydroadamantane...
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Synthesis of Phosphinic Pseudomethionyl-Glutamyl-Histidine
AbstractThe amidoalkylation of a phosphonous acid containing a structural isostere of diethyl glutamiate, using ethyl carbamate and...
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Study of p-(3-carboxy-1-adamantyl)-calix[4]arene with hydrogen bonds along the upper and lower rim by IR spectroscopy and DFT
The IR spectra of p -(3-carboxy-1-adamantyl)-calix[4]arene ( AdC4A ) were studied. Using IR spectroscopy, it has been shown that in calixarene in dilute...
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Synthesis of 1-(4-Alkoxybenzyl)-1H-(benz)imidazoles
AbstractN -Alkylation of 1 H -imidazole and 1 H -benzimidazole with 4- n -octyloxybenzylchloride, 4- n -hexadecyloxybenzylchloride and...
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1,3-Dehydroadamantane and Its Derivatives: A Versatile Synthetic Platform for the Preparation of Functional Compounds with a Cage Structure. A Review
AbstractA promising strategy in the synthesis of functional compounds with a cage structure is the use of 1,3-dehydroadamantane (tetracyclo[3.3.1.1. 3,7...
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Synthesis and antioxidant activity of 1-R-3-(2-fluorophenyl)selenoureas containing polycyclic fragments
We have developed an improved two-stage approach to the synthesis of 2-fluorophenylisoselenocyanate from 2-fluoroaniline, which at the first stage...
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Bis-adamantylated resorcinol as an antioxidant and precursor material for family of other polymers
Present embodiment is a study of evaluation of antioxidant property of bis-adamantylated resorcinol [4, 6- bis(1-adamantyl) resorcinol] 1b on...
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Thermodynamic Properties of Some Functionally Substituted Azoles in the Condensed State
AbstractResults are presented from measuring the heat capacity in the condensed state via low-temperature adiabatic calorimetry in the range of 5–370...
