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A Two-Dimensional Framework Based on 1,3-bis(2-Methyl-Imidazol-1-yl)-Benzene Exhibiting Luminescent and Photocatalytic Properties
A two-dimensional Cd(II) complex [Cd(1,3-BMIB)(OBA)·H 2 O] n (1) (1,3-BMIB = 1,3-bis(2-methylimidazol-1-yl)benzene, H 2 OBA = 4,4′-oxybis(benzoic acid)) is...
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Synthesis, Characterization and the Effect of the Auxiliary Ligands on the Dimensionality of Two Cobalt(II)-Fumarate Coordination Polymers with Bis(Imidazole) Ligands
AbstractTwo new Co(II) coordination polymers, namely {[Co(μ-fum) 0.5 (μ-obix) 2 (H 2 O)](NO 3 )} n ( 1 ), {[Co(μ-fum) 0.5 (μ-mbix) 2 (H 2 O)](NO 3 )} n ( 2 ), (H 2 fum:...
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Bisbenzimidazole salts and their in silico–in vitro inhibitory abilities on hCA I, hCA II, and AChE enzymes
Eight new bisbenzimidazolium halides were prepared from alkyl halides and 4,4′-bis[(benzimidazol-1-yl)methyl]-1,1′-biphenyl.The structures of the...
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Synthesis of dicationic hetarylmethylimidazolium salts via the reaction of N, N′-diaryl-4-chloromethylimidazolium chlorides with N-heterocycles
The reaction between N, N ′-diaryl-4-chloromethylimidazolium chlorides and N-nucleophiles, viz. various azoles and azines, which proceeds via ...
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RETRACTED ARTICLE: Crystal Structures and Anti-Gastric Cancer Activities of Two Cd(II)-Based Coordination Polymers Constructed from Different Donor Ligands
Two new Cd(II)-containing coordination polymers, namely [Cd(H 2 O) 2 (L 1 ) 2 ](NO 3 ) 2 (1 , L 1 = 1,3-bis-(imidazol-1-yl)-5-methyl-benzene) and [Cd 2 (L 2 )(H 2 O) 6 ](DMF)...
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Transition-Metal-Based Carbon–Carbon and Carbon–Heteroatom Bond Formation for the Synthesis and Decoration of Heterocycles
A literature overview, up to the end of 2004, of the most important microwave-assisted transition-metal-mediated processes used for the decoration...
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Condensed azole-based organophosphorus heterocycles
This review summarizes for the first time the literature data on the methods of constructing with covalent bonds condensed systems based on...
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4-Sulfanylmethyl- and 4-sulfonylmethyl-substituted N,N′-diarylimidazolium salts as new proligands in the synthesis of Pd complexes with N-heterocyclic carbenes
The reaction of readily available N,N′ -diaryl-4-chloromethylimidazolium chlorides with thiols afforded 4-(alkyl)arylsulfanylmethyl- N,N′ -diarylimidazol...
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Metal–Organic Frameworks (MOFs) Catalyzed Photodegradation of Organic Dyes: Syntheses, Designing Strategies, and Mechanism
Metal–organic frameworks (MOFs) or coordination polymers (CPs) are an assorted class of materials finding applications in areas, viz. sensing and...
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Di-, tetra-, and perhydropyrrolo[1,2-a]imidazoles: The Methods of Synthesis and Some Aspects of Application
The review summarizes and systematizes the literature data on the synthesis and some aspects of application of pyrrolo[1,2- a ]imidazoles. Synthetic...
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Click Synthesis, Characterization, Mesomorphic Properties, and Antimicrobial Evaluation of Some Novel Imidazo[1,2-a]pyrazine Derivatives Containing a 1,2,3-Triazole Ring
AbstractIn an attempt to rationalize the search for new potential antimicrobial agents, a novel series of 1,4-disubstituted...
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Methods for the synthesis of imidazo[2,1-b][1,3]thiazines, their annulated and hydrogenated analogs
The review systematizes literature data on methods for constructing imidazo[2,1- b ]thiazines and their hydrogenated analogs. The synthetic approaches...
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Barium manganate: a versatile oxidant in organic synthesis
This review presents the applications of BaMnO 4 as an efficient oxidizing reagent in oxidation of organic compounds. Using BaMnO 4 , benzylic, aromatic...
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Synthesis of axially chiral alkenylboronates through combined copper- and palladium-catalysed atroposelective arylboration of alkynes
The incorporation of alkenylboronates into axially chiral compounds increases their structural diversity and provides a synthetic handle for...
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The Biology and Chemistry of Microsomal Prostaglandin E Synthase (mPGES) - I Inhibitors for Cancer Biomedicine
According to WHO, Cancer is the leading cause of death worldwide, accounting for nearly 10 million deaths in 2020. The predicted global cancer burden...
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Metathesis Polymerization To and From Surfaces
Polymerization to and from surfaces using metathesis-based techniques – ring-opening metathesis polymerization (ROMP) and 1-alkyne polymerization –...
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The Molecular Diversity of 1H-Indole-3-Carbaldehyde Derivatives and Their Role in Multicomponent Reactions
1 H -Indole-3-carbaldehyde and related members of the indole family are ideal precursors for the synthesis of active molecules. 1 H -Indole-3-carbaldehyde...
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The Use of N-Heterocyclic Carbenes as Ligands in Palladium-Mediated Catalysis
Recent developments in the use of N-heterocyclic carbenes (NHC) as ligands in palladium-mediated transformations are described. These versatile...
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Synthetic Approaches to Perfluoroalkyl-Substituted Heterocyclic Phosphonates
AbstractThe review considers methods of synthesis of perfluoroalkyl-substituted, mainly trifluoromethylated, heterocyclic phosphonates.
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Two Cd(II) Complexes Based on Carboxylate and Bis(imidazolyl) Ligands: Syntheses, Crystal Structures and Luminescence Properties
AbstractTwo new metal–organic coordination complexes, {[Cd 8 (tdc) 8 (bbi) 8 (H 2 O) 8 ]·4DMF]} n ( 1 ) and {[Cd(cbba) 2 (m-bix) 2 ]} n ( 2 ) (H 2 tdc = 2,5-thiophenedicar...
