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Synthesis of Acetylenic [Chloro(iodo)methyl]silanes and 2-Sulfanylbenzothiazoles Based Thereon
AbstractBromomagnesium derivatives of ethynylsilanes [Me 4– n Si(C≡CMgBr) n , n = 1–3] reacted with chloro(chloromethyl)dimethylsilane to give the...
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Unusual Transformations of Allylsilanes in the Reaction with N,N-Dichloroarenesulfonamides
AbstractThe reactions of allyl(chloromethyl)dimethylsilane, diallyl(dimethyl)silane, and diallyl(diphenyl)silanes with N , N -dichloroarenesulfonamides...
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Iridium-Catalyzed Silylation
In this chapter, homogeneous iridium-catalyzed silylation reactions are reviewed, focusing primarily on their synthetic utility. Additionally,... -
Silyl Anions
The last 10 years have witnessed tremendous advances in the field of silyl anion research. New methods for the synthesis of alkali metal silanides... -
Synthesis of new trans-1,2-disilylethylene derivatives by hydrosilylation of ethynylsilanes
Eight new trans-1,2-disilylethylenes were synthesized by the hydrosilylation of (CH ≡ C) 2 Si(OCH 3 )CH 3 with HSiCl 3 and HSi(CH 3 )Cl 2 , and also of (CH 3 ) 3 Si...
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Organosilicon Compounds of Group I Elements
The simplest compounds containing a bond between silicon and a Group Ia metal are the silicides. The first representative of this class of compound... -
Organosilicon acetylenic ethers
Silicoacetylenic ethers and bromoethers were synthesized by the reaction of silylethynylmagnesium bromides with α -halo ethers. The bromoethers when...
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Organosilicon Compounds of Group II Elements
Prolonged boiling of a mixture of silicon tetrachloride with magnesium, calcium, zinc, or mercury oxide in a polar solvent (an organic nitrile or...