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Reactions of Carbosilanes
There are some principal objectives in the study of the reactivity of carbosilanes: First, to what extent are the generally known reactions of... -
Preparative Organic Chemistry Using Clays
Application of clays, modified clays or clay-supported reagents to chemistry is receiving increasing interest. This lecture will focus on recent... -
The Formation of Carbosilanes
The synthetic routes known to date to form carbosilanes are based on the gas phase pyrolysis of methylsilanes, on the reaction of CH2Cl2 and CHCl3... -
Fluorine and Oxygen
The following chapters focus on oxygen fluorides OnF2, n=1 to 6, oxygen fluoride radicals OxF, x=1 to 4, and hypofluorous acid, HOF. -
Mechanism of transannular bromination reactions of diolefins of the bicyclo[3.3.1]nonane series
Mechanisms of reactions of brominated diolefins of the bicyclo[3.3.1]nonane series were studied. The reaction of transannular cyclization into...
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Anodic Oxidations
Direct anodic oxidation of alkanes may be performed if they have ionization potentials lower than about 10 eV [l]1. Such oxidations can be classified... -
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Various Examples
The HO-LU interaction came early to the notice of theoreticians. Hückel pointed out the role of LU in the alkaline reduction of naphthalene and... -
Bicyclo[3,3,1]nonanes and Related Compounds
The bicyclo[3,3,l]nonane ring system I, shown here both in plan and in perspective, has been known for about seventy years, and work on this, and... -
The Separation of Polar, Steric, and Resonance Effects by the Use of Linear Free Energy Relationships
Structural modification of a reactant molecule may influence the rate or equilibrium constant of a reaction through polar, steric, or resonance... -
Linear Correlations of Substituent Effects in 1H, 19F, and 13C Nuclear Magnetic Resonance Spectroscopy
Nuclear magnetic resonance (nmr), from its inception, has provided useful and sometimes unique information about molecules. Nuclear shielding and... -
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Recent developments in the chemistry of adamantane and related polycyclic hydrocarbons
The chemistry of adamantane and related “cage-like” hydrocarbons has developed rapidly in recent years. These developments, encompassing a broad...