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Effect of Star-shaped chain architectures on the polylactide stereocomplex crystallization behaviors
Linear and star-shaped polylactides (PLA) with similar molecular weights of each arm are synthesized via ring-opening polymerization of LA with...
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Can classic Avrami theory describe the isothermal crystallization kinetics for stereocomplex poly(lactic acid)?
Classic Avrami model and its modifications have found diverse applications in describing the thermal and phase behaviors of inorganic metals and...
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Pentaerythritol particles covered by layer-by-layer self assembled thin films with stereocomplex of isotactic poly(methyl methacrylate) and syndiotactic poly(methyl methacrylate)
In this paper, we present a different approach of coating a phase change material (PCM) for a possible use in thermal energy storage. We focused on...
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The Terpenes Limonene, Pinene(s), and Related Compounds: Advances in Their Utilization for Sustainable Polymers and Materials
The preparation of sustainable polymers from renewable resources is a main task in modern polymer and materials chemistry. For this, terpenes, that... -
Surface-modified iron oxide nanoparticles for adsorption, photodegradation, and selective removal applications
We explored the factors and mechanisms of the adsorption and photocatalytic activity of iron oxide nanoparticles (Fe 2 O 3 NPs) coated with poly(sodium...
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Chemoselective and Living/Controlled Polymerization of Alkenyl Methacrylates by the Phosphonium Ylide/Organoaluminum Lewis Pairs
Chemoselective, living/controlled polymerizations of allyl methacrylate (AMA) and vinyl methacrylate (VMA) with/without methyl methacrylate (MMA) by...
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Cellulose nanospheres coated polylactic acid nonwoven membranes for recyclable use in oil/water separation
Oily wastewater has always been an environmental issue that we are concerned about and committed to managing. Although the superwetting membranes...
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Poly(β-cyclodextrin)-mediated polylactide-cholesterol stereocomplex micelles for controlled drug delivery
A series of host-guest interaction-adjusted polylactide stereocomplex micelles was prepared via the self-assembly of 4-armed poly(ethylene...
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Highly Thermally Conductive Polydimethylsiloxane Composites with Controllable 3D GO@f-CNTs Networks via Self-sacrificing Template Method
Constructing controllable thermal conduction networks is the key to efficiently improve thermal conductivities of polymer composites. In this work,...
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Mainchain Semifluorinated Polymers with Ultra High Molecular Weight via Reaction-enhanced Reactivity of Intermediate (RERI) Mechanism
Achieving the linear polymers with high molecular weight via step-growth polymerization of A 2 and B 2 monomers is significantly limited by the...
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High-Performance Biodegradable PBAT/PPC Composite Film Through Reactive Compatibilizer
Poly(butylene adipate- co -terephthalate) (PBAT) is currently the largest commercial biodegradable plastics with good toughness and film forming...
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Self-nucleation Effect of Crystallization with Various Nucleating Agents
In this work, the self-nucleation effect on crystallization was studied for polypropylene with various nucleating agents. The talc was employed to...
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Plasticization of biodegradable stereocomplex polylactides with poly(propylene glycol)
The plasticization of stereocomplex polylactide (scPLA) with poly(propylene glycol) (PPG) is described. The poly( L -lactide) (PLLA), poly(D-lactide)...
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The Crystallization Behavior of L-Poly(lactic acid)/Polypropylene Blends: The Acceleration for Both L-Poly(lactic acid) and Polypropylene
For a polymer/polymer dismissible blend with two crystallizable components, the crystallization behavior of different components and the reciprocal...
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Effect of Physical Aging on Heterogeneity of Poly(ε-caprolactone) Toughening Poly(lactic acid) Probed by Nanomechanical Map**
Poly(lactic acid) (PLA) is a promising bio-based environmentally-friendly plastic. Nevertheless, the physical aging-induced brittleness of PLA limits...
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Bilayer Compounded Polytetrafluoroethylene Membrane for Enhanced Oil-Water Emulsion Separation
In order to achieve efficient and durable oil-water emulsion separation, the membranes possessing high separation efficiency and mechanical strength...
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Lightweight, Strong and High Heat-Resistant Poly(lactide acid) Foams via Microcellular Injection Molding with Self-Assembly Nucleating Agent
Poly(lactide acid) (PLA) foams have shown considerable promise as eco-friendly alternatives to nondegradable plastic foams, such as polystyrene (PS)...
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Addition of Thermoplastic Starch (TPS) to Binary Blends of Poly(lactic acid) (PLA) with Poly(butylene adipate-co-terephthalate) (PBAT): Extrusion Compounding, Cast Extrusion and Thermoforming of Home Compostable Materials
Development of home compostable materials based on bioavailable polymers is of high strategic interest as they ensure a significant reduction of the...
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Evolution of polyhydroxyalkanoate synthesizing systems toward a sustainable plastic industry
Designing sustainable biobased and/or biodegradable plastics opens up opportunities to achieve a low-carbon society and overcome plastic pollution....
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d-Lactic acid production from agricultural residues by membrane integrated continuous fermentation coupled with B vitamin supplementation
Backgroundd -Lactic acid played an important role in the establishment of PLA as a substitute for petrochemical plastics. But, so far, the d -lactic...