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Synthesis, Crystal Structure, Photophysical Properties, and Antibacterial Activities of the Copper(II) Complex Derived from 4-Chloro-2-{[(2,6-Dimethylphenyl)Imino]Methyl}Phenol
AbstractA new asymmetrical Schiff base ligand, ( E )-4-chloro-2-{[(2,6-dimethylphenyl)amino] methyl}phenol (HL), and its mononuclear Cu(II) complex...
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Synthesis, spectroscopic, electrochemical, thermal and antimicrobial studies of Ni(II), Zn(II), Cu(II) and Co(II) metal complexes of novel bidentate schiff base ligand
New Schiff base was synthesized from condensation of anthracene-10-carbaldehyde with 4-amino-3-mercapto-1,2,4-triazin-5(4 H )-one. Resulted azomethine...
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Theoretical Modeling of Exo- and Endohedral Hydrogenation Reactions of the Doped Magnesium Cluster Mg17Ni
AbstractBased on DFT and IRC calculations, the potential energy surfaces of the hydrogenation channels of the Mg 17 Ni cluster have been compared. In...
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Co(II), Ni(II), and Cu(II) Complexes Containing Isatin-Based Schiff Base Ligand: Synthesis, Physicochemical Characterization, DFT Calculations, Antibacterial Activity, and Molecular Docking Analysis
AbstractSchiff base ligand [3-(2-hydroxyphenylimino)-1,3-dihydroindol-2-one] was synthesized by the condensation reaction of isatin with...
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Structure and Synthesis of Dihalodicyanoaurate Complexes [Ph3PR][Au(CN)2Hal2] (Hal = Cl, R = Me, СH2Ph; Hal = Br, R = cyclo-C6H11; Hal = I, R = Ph)
AbstractIonic gold(III) complexes [Ph 3 PMe][Au(CN) 2 Cl 2 ] ( I ), [Ph 3 PCH 2 Ph][Au(CN) 2 Cl 2 ] ( II ), [Ph 3 PC 6 H 11 - cyclo ][Au(CN) 2 Br 2 ] ( III ), and [Ph 4 P][Au(CN) 2 I 2 ]...
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Synthesis, Crystal Structure, Hirshfeld Surface Analysis, Molecular Docking, IR Spectroscopy and DFT Calculations of a Novel 2D Layered Hybrid Compound (C6H10N3O)2Cu2Cl6
The 2D hybrid compound bis(2-amino-4-methoxy-6-methylpyrimidinium) bis(μ 2 -chloro)-tetrachloro-di-copper(II), (C 6 H 10 N 3 O) 2 Cu 2 Cl 6 , is successfully...
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1,2-BIS[BIS(PYRIDIN-2-YL-METHYL)PHOSPHINO] ETHANE AND ITS PdCl2-BASED COMPLEX: SYNTHESIS AND CRYSTAL STRUCTURE
Abstract1,2-Bis[bis(pyridin-2-yl-methyl)phosphino]ethane, R 2 PCH 2 CH 2 PR 2 (R = 2-PyCH 2 ), has been synthesized in 92% yield via the reaction of Cl 2 PCH 2 CH
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Synthesis, characterization, in vitro antimicrobial activity, DNA binding assay, antioxidant and anti-inflammatory efficacy of trinuclear heterobimetallic complexes of Ni(II) derived by the reaction of [Ni(C13H12N2O)2]Cl2 with dialkyl/diaryl organometallic dichlorides
The newly designed trinuclear heterobimetallic complexes [Ni(L) 2 (M) 2 R 4 Cl 2 ] were synthesized by using methanolic solution of mononuclear Ni(II)...
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Assembly of a New 2D Heterometallic 3d–4f Coordination Polymer Bearing Planar Tetranuclear Square Building Blocks
A new two-dimensional (2D) 3d–4f heterometallic coordination polymer, which is {[Tb 2 Zn 4 ( µ 3 -TFMIDC) 4 ( µ 4 -HTFMIDC)(H 2 O) 8 ]·2H 2 O} n , has been successfully...
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Classification of the Inclined Plates of Mass-Exchange Columns (Review of Designs)
A classification of planar and volumetric inclined contact plates of mass-exchange column apparatuses is proposed. The most characteristic designs of...
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Design and Analysis of Terahertz Wave Tunable Metamaterial with High Refractive Index
Metamaterials are a class of artificially designed artificial composite materials with periodic arrangement of sub-wavelength structure. Because of...
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Copper (II) complexes based bis(pyrazolyl)borate derivatives as efficient anticancer agents: synthesis, characterization, X-ray structure, cytotoxicity, molecular docking and QSAR studies
Copper-based complexes have various applications in the current era, particularly in the field of pharmaceutical and biochemistry. Four types of the...
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Numerical investigation of electro-thermo-convection in a square enclosure with incorporated hot solid body
The electro-thermo-convection in a square cavity with incorporated hot solid body is numerically investigated. The finite volume method associated...
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Chemometric Extractive Synthesis, Characterization and Antimicrobial Studies of Fe(II) and Fe(III) Complexes of N2O2 Chelating Ligand, Bis(Salicylidene) Ethylenediamine
Bis(salicylidene) ethylenediamine (H 2 BMPDE) was synthesized by the condensation of ethylenediamine and salicylaldehyde in a 1:2 mole ratio and used...
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STRUCTURE OF A BINUCLEAR RHODIUM(I) COMPLEX WITH THE ACENAPHTHENE- 1,2-DIIMINE LIGAND
AbstractBy the interaction of [Rh 2 (COE) 4 (μ-Cl) 2 ] (COE = cyclooctene) with 1,2-bis[(2,6-diisopropyl phenyl)imino]acenaphthene (dpp-bian) new...
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Ground and Excited State Electronic Structures of d8-Squared Planar Platinum(II) and Gold(III) Complexes Bearing Cyclometallated 2,6-Diphenylpyridine and Pyrene-Derived N-Heterocyclic Carbene
AbstractElectronic structures of four pyrene-derived N-heterocyclic carbene complexes of platinum(II) and gold(III) bearing cyclometallated...
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Transition metal complexes of pyridazine-based ligand: synthesis, characterization, biological activities, and molecular docking studies
A new class of pyridazine-based six Iron(II), Nickel(II) and Copper(II) metal complexes of (E) -2-(6-chloropyridazin-3-yl)-1-(1-(pyridin-2-yl)ethyliden...
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Influence of Bridged Group on Coordination Mode and Ethylene Oligomerization Behavior of Diamine Bridged Salicylaldimine Ni(II) Complexes
AbstractSeries of diamine and p-phenylenediamine bridged salicylaldimine ligands ( L1 – L4 ) were synthesized, and the corresponding nickel complexes ( C1 –...
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Electrodeposition of silicon films from organic solvents on nanoporous copper substrates
AbstractSilicon and silicon-based materials are among the important modern materials with application in many fields of technology from electronics...
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Three-Layered Membranes for Planar Solid Oxide Fuel Cells of the Electrolyte-Supported Design: Characteristics and Applications
AbstractThree-layered ceramic membranes based on stabilized zirconia for planar solid-oxide fuel cell (SOFC) are prepared by the tape casting method....
