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EPR spectroscopy of functional nanostructures: new targeted approaches and applications
Electron paramagnetic resonance (EPR) spectroscopy allows one to study the magnetic, structural, and functional properties of nanostructures and...
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A Stable Copper-based Metal-Azolate Framework for Efficient Electroreduction of CO2 to C2+ Products
Driven by renewable or excess electrical energy, electrochemical CO 2 reduction reaction (eCO 2 RR) represents a promising carbon-neutral approach to...
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The Optimization Performance of Fibrous Sodium Alginate Co-Polymer in Direct Methanol/Ethanol Fuel Cells
A novel grafting polymer was synthesied via the grafting of itaconic acid (IA) and co-acrylamide (Am) onto sodium alginate (NaAlg) for direct...
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Efficient Removal and Preconcentration of Pd(II) Ions in Environmental Water Using Co2SiO4 Nanoparticles Modified by Mordant Red 3 as a Novel Adsorbent
In this work, Co 2 SiO 4 nanoparticles were facilely synthesized using the pechini sol gel method then modified by mordant red 3 as a novel composite...
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Adsorbed cobalt porphyrins act like metal surfaces in electrocatalysis
Electrodes chemically modified with molecular active sites are potent catalysts for energy conversion reactions. Such electrodes are typically...
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Rationalizing the Efficiency of HKUST-1 for Capture and Biomimetic Sequestration of CO2
In light of their outstanding properties, metal–organic frameworks appear to be the latest and most assured sorbent in CCUS technology. In this...
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Novel, Robust and Efficient W/Co@g-C3N4 Catalyst Enable Outstanding Performance for the Straightforward Oxidative Amidation of Aldehydes with Amines
A comprehensive vision has been promoted for straightforward oxidative amidation, deploying a majority of amines and aldehydes via a robust and novel...
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Operando reconstruction towards stable CuI nanodots with favorable facets for selective CO2 electroreduction to C2H4
Cu-based electrocatalysts with favorable facets and Cu + can boost CO 2 reduction to valuable multicarbon products. However, the inevitable Cu + ...
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Adsorptive removal of heavy metals from wastewater using Cobalt-diphenylamine (Co-DPA) complex
Heavy metals like Cadmium, Lead, and Chromium are the pollutants emitted into the environment through industrial development. In this work, a new...
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Intermetallic Pd-In catalysts for methanol synthesis by CO2 hydrogenation
The use of supported intermetallic Pd x In y nanoparticles as an efficient catalyst for the synthesis of methanol from carbon dioxide was shown. On...
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Enhanced CO2/N2 separation performance in HP-Cu-BTCs by modifying the open-metal sites and porosity using added templates
HP-Cu-BTCs (CTAB), HP-Cu-BTC(N,N), HP-Cu-BTC(SDBS) series with open metal coordination site Cu(I), cage window sites, tunable porosity, high specific...
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Ga-doped CeO2 nanorods as highly active catalysts for the synthesis of dimethyl carbonate from CO2 and methanol
In this work, the effect of Ga as dopant on CeO 2 was examined in the direct synthesis of DMC from CO 2 and methanol. We prepared a series of Ga-doped...
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Research on properties and catalytic behaviour in CO hydrogenation at atmospheric and high pressure of bimetallic systems (10%Co + 0.5%Pd)/TiO2 (Al2O3)
The properties of prereduced (10%Co + 0.5%Pd)/Al 2 O 3 (TiO 2 ) systems in the CO hydrogenation reaction at atmospheric and high pressure were studied. At...
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Boosting the Catalytic Performance of γ-MnOOH Through Post-Treatment with Potassium Hydroxide on n-Butylamine with CO2
In this study, a simple potassium hydroxide (KOH) post-treatment was applied to increase the catalytic performance of γ-MnOOH in the carbonylation of...
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Recent Trends in Plasma-Assisted CO2 Methanation: A Critical Review of Recent Studies
In recent years, enormous efforts have been devoted to alleviating global energy demand and the climate crisis. This has instigated the search for...
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Bio-base Metal Organic Frameworks as Potential CO2 Adsorbents
Environmental friendliness and high adsorption capacity are important properties of CO 2 adsorbents. Bio-based metal–organic framework (bioMOFs)...
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NMR-based quantification of liquid products in CO2 electroreduction on phosphate-derived nickel catalysts
Recently discovered phosphate-derived Ni catalysts have opened a new pathway towards multicarbon products via CO 2 electroreduction. However,...
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Molecular Basis of Asphaltene Stability
AbstractThe instability of asphaltenes in crude oils, manifested in their precipitation, is a major production issue that may arise both during the...
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State-of-the-art thermocatalytic systems for CH4 and CO production via CO2 hydrogenation: critical comparison, mechanistic considerations and structure-performance insights
The unprecedented increase of atmospheric CO 2 concentration and the associated climate change calls for the urgent implementation of CO 2 mitigation...
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An experimental guide to in operando electrochemical Raman spectroscopy
Electrochemical Raman spectroscopy can provide valuable insights into electrochemical reaction mechanisms. However, it also shows various pitfalls...
