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Electro-oxidation of hydrazine shows marcusian electron transfer kinetics
Although hydrazine (N 2 H 4 ) oxidation in an electrochemical environment has been of great interest for years, its intrinsic electron transfer kinetics...
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Intermolecular charge-transfer complex between solute and ionic liquid: experimental and theoretical studies
Ground-state intermolecular donor–acceptor complex ([MCP][NTf 2 ]-MN; 1:1) is formed between π -electron of 1-methyl-naphthalene (MN) as solute...
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Metal-mediated reactions of bromoform with electron-rich and electron-deficient carbon-carbon and carbon-hetero atom multiple bonds
The addition of bromoform to carbon-carbon and carbon-heteroatom multiple bonds has gathered interest from the synthetic community as it leads to...
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Combinations of electron and proton donors in transition-metal complex mediated nitrogen reduction reactions
Nitrogen fixation is a complex process involving the transfer of six electrons and protons. Diverging from the conventional Haber-Bosch process,...
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Regulating Electron-transfer over ZnIn2S4 by Sn(II)/Sn(IV) Co-Do** for Efficient Photocatalytic Hydrogen Production
The development of photocatalysts with efficient charge separation and transferring is essential for efficient photocatalytic H 2 generation. Here, we...
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Substituent effects of halogens on the excited-state intermolecular proton transfer reactions
Fluorescent aromatic urea compounds undergo excited-state intermolecular proton transfer (ESPT) in the presence of acetate anions to produce an...
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One-Electron Transfer in Reactions of Stable Organic Radicals with Oxygen
AbstractMechanisms of oxidation of stable organic radicals with molecular oxygen are based on a fundamental physical interaction, namely Coulomb...
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Sensitive detection of miRNA based on enzyme-propelled multiple photoinduced electron transfer strategy
A method is presented that uses photoinduced electron transfer (PET) for the determination of microRNAs (miRNAs) in clinical serum samples and...
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Theoretical investigation on regulating photophysical properties and proton transfer behavior by electronegativity for near-infrared emitting styryl dyes
Our main focus is to explore the atomic electronegativity-dependent photoinduced behavior of styryl derivatives (HBO, HBS, and HBSe). The results of...
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Emission and energy transfer investigation of non-conjugated total carbon configuration between BODIPY and naphthalimide
An energy cassette,
N -butyl-6-(3-phenylethynyl-1,3,7,9-tetramethylBODIPY)-naphthalimide ( BON ), was constructed with an energy donor and acceptor...
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Photocatalysts for steering charge transfer and radical reactions in biorefineries
Photocatalysis has emerged as a green protocol for biorefineries thanks to sustainable energy input. The unique radical mechanism of photocatalysis...
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Forty years of theory-inspired experiments on charge-transfer via solutions and electrodes: the Georgian accents
This scholarly review, which also contains some specific historical details, is written by a few of researchers representing two generations...
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Effect of Electron Structure of La-Based Perovskites on the Catalytic Combustion of n-Butylamine
Studying the relationship between electronic structure and activity helps to understand the catalytic mechanism since the catalytic combustion is a...
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Reaction environment impacts charge transfer but not chemical reaction steps in hydrogen evolution catalysis
Interfacial electrocatalysis involves elementary chemical and charge transfer reaction steps. For the hydrogen evolution reaction (HER), the applied...
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Heat Transfer: Steady-State Conduction
Heat transfer involves the flow of thermal energy between objects due to temperature differences. It is an integral part of food processing and...
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Charge Transfer in Natural and Artificial Nucleic Acids
Nucleic acids are known for their impressive range of applications and are thoroughly studied in various ways. One of the most fascinating properties...
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Steering S-scheme charge transfer via interfacial dipoles induced by amine-containing polyelectrolytes
The lack of a robust interfacial driving source over multicomponent photocatalysts is an essential contributor to the sluggish spatial charge...
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The theoretical study of electron-induced trimerization of acrylic acid anion radical in the gas phase
In this work, the electron-induced reaction of acrylic acid was studied using an FT-ICR-mass spectrometer and DFT calculations at M06-2X/aug-cc-pVTZ...
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Gas Mass Transfer and System Pressure in Biohydrogen Production
The process of hydrogen production interacts highly with gas–liquid mass transfer and bubble behaviors as well as the gaseous pressures. In this...