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Trinuclear europium complexes with a tripodal ligand: formation kinetics in acetonitrile
Here we report on the characterizations (mass spectrometry and NMR) and kinetic investigations related to the formation of trinuclear complexes [Eu 3 L ]
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Zinc (II)–Boron (III) Aqueous Complex Formation Between 25 and 70 °C
The zinc boron complex formation was studied as a function of temperature (25, 50 and 70 °C) in boric acid solutions of various concentration (0.25,...
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Kinetic control over the chiral-selectivity in the formation of organometallic polymers on a Ag(110) surface
Methods to control chiral-selectivity in molecular reactions through external inputs are of importance, both from a fundamental and technological...
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Designing a highly efficient type III polyketide whole-cell catalyst with minimized byproduct formation
BackgroundPolyketide synthases (PKSs) are classified into three types based on their enzyme structures. Among them, type III PKSs, catalyzing the...
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Study on the formation process of soot from 2,5-dimethylfuran pyrolysis by ReaxFF molecular dynamics
Furan derivatives (derived from biomass) play a significant role in the biofuel technology. In this paper, the molecular dynamics simulation of the...
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Analytical Determination of Dependence of Full Gel Formation Time on Parameters of Fiber Making by Wet Method
The phenomenon of gel formation for the process of chemical fiber making from polymer solution was studied. An approximate algebraic equation of...
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Ion-Beam-Assisted Formation of the Silver-Containing Surface of Porous Silicon
Abstract—The formation of a silver-containing porous layer on the surface of KEF-4,5 single-crystal silicon by ion-beam do** was studied. The dose...
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Standard Enthalpies of Formation of Glycyl-L-tyrosine and Its Dissociation Products in Aqueous Solutions
AbstractThe enthalpies of dissolution of crystalline glycyl-L-tyrosine in water and in aqueous potassium hydroxide at 298.15 К were determined by the...
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Metal-catalysed C–C bond formation at cyclopropanes
Cyclopropanes are important substructures in natural products and pharmaceuticals. Although traditional methods for their incorporation rely on...
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Evidences for Polaron Formation in Cuprates
It is widely believed that the essential physics of high temperature superconducting copper oxides are governed by the properties of their...
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Simultaneous time-resolved inorganic haloamine measurements enable analysis of disinfectant degradation kinetics and by-product formation
We demonstrate the application of proton transfer time-of-flight mass spectrometry (PTR-TOF-MS) in monitoring the kinetics of disinfectant decay in...
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Gellan gum-gelatin based cardiac models support formation of cellular networks and functional cardiomyocytes
Cardiovascular diseases remain as the most common cause of death worldwide. To reveal the underlying mechanisms in varying cardiovascular diseases,...
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Structural snapshots along K48-linked ubiquitin chain formation by the HECT E3 UBR5
Ubiquitin (Ub) chain formation by homologous to E6AP C-terminus (HECT)-family E3 ligases regulates vast biology, yet the structural mechanisms remain...
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Thermodynamics of complex formation of silver(I) with substituted pyridines and cyclic amines in non-aqueous solvents
The understanding of the thermodynamic stability and speciation of metal complexes in solution requires access to their enthalpy and entropy of...
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An Electrostatic Mechanism for the Formation of Hybrid Nanostructures Based on Gold Nanoparticles and Cationic Porphyrins
AbstractThe interaction of cationic porphyrin with gold nanoparticles (GNPs) coated with polymer shells with positive and negative surface potentials...
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A Study of the Structure Formation of Impregnating Amino-Formaldehyde Resins
AbstractStudies of structure formation of modified impregnating amino-formaldehyde resins are considered. Based on the obtained deformation curves of...
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Enzymatic synthesis of organoselenium compounds via C‒Se bond formation mediated by sulfur carrier proteins
Organoselenium compounds are rare in nature but play important physiological roles by exploiting the distinct features of selenium. However, the...
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Immobilization of oligo DNA strands on TEMPO-oxidized pulp fibers and evaluation of duplex formation
Paper fiber functionalization by modification with DNA molecules expands the applicability and specificity of paper-substrate analytical devices such...
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Adsorption of alpha-synuclein and inhibition of fibril formation by nanocellulose and gold-coated-nanocellulose
Interfering with the aggregation of the protein alpha-synuclein (aSyn) has been a topic of research for > 25 years, as this protein is found in...
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Influence of Acid Reagents on Oil Sediment Formation
AbstractThe formation of oil sediment in highly paraffinic oil in the presence of carboxylic and naphthenic acids was studied. The influence of the...
