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Metal-Catalyzed Aromatic C-O Bond Activation/Transformation
Phenol derivatives have attracted significant attention as a renewable aromatic feedstock for the production of organic compounds that are required...
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Pillararene-Based Supramolecular Polymer
Pillar[n]arenes, as a new generation of macrocyclic molecules, have attracted tremendous attention since its firstly being synthesized. Due to their...
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Chemical Transformations of Tetracyclo[3.3.1.13,7.01,3]decane (1,3-Dehydroadamantane): VII. Reaction of 1,3-Dehydroadamantane with Alkanediols and Amino Alcohols
The reaction of 1,3-dehydroadamantane with C 2 –C 6 α,ω-alkanediols selectively afforded ω-(adamantan- 1-yloxy)alkan-1-ols in 87–94% yield. The reaction...
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Macrocycle-based oligo- and polylactides: synthesis and prospects of application
The review considers methods for modifying oligo- and polymers of lactic acid by macrocyclic moieties (cyclodextrin, tetrapyrrole, and calixarene)...
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Cyclodextrin-Based Supramolecular Hydrogel
Cyclodextrins (CDs), as a kind of cyclic host molecules, have been widely investigated due to their specific complexation with a series of guest...
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Reduction of unsaturated adamantyl-containing nitriles with lithium aluminum hydride in 2-methyltetrahydrofuran
Reduction of unsaturated adamantyl-containing nitriles with lithium aluminum hydride in 2-methyltetrahydrofuran was examined. It was found that under...
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Biological Systems Involving Cucurbituril
Featuring rigid and confined cavity, high binding affinity toward metal and organic cations, the emerging chemistry of cucurbit[n]urils (CB[n]s) has...
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Catalytic Asymmetric C–H Oxidation with H2O2 and O2
This chapter surveys the existing catalyst systems, either organocatalytic or metal-based, for the chemo- and stereoselective oxidation of C–H groups...
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Molecular Simulations of Supramolecular Architectures
In this chapter, two computational methods, namely, molecular dynamics (MD) simulation and free energy calculation based on MD simulations,...
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E- and Z-, di- and tri-substituted alkenyl nitriles through catalytic cross-metathesis
Nitriles are found in many bioactive compounds, and are among the most versatile functional groups in organic chemistry. Despite many notable recent...
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Pillararene-Based Supramolecular Polymer
Pillar[n]arenes, as a new generation of macrocyclic molecules, have attracted tremendous attention since its firstly being synthesized. Due to their...
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Biomimetic asymmetric catalysis
Enzymes are the core for biological transformations in nature. Their structures and functions have drawn enormous attention from biologists as well...
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Polyrotaxane Actuators
With the emergence of supramolecular chemistry and modern nanotechnology, a great deal of research has been conducted on idiosyncratic classes of...
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Advances in Kumada–Tamao–Corriu cross-coupling reaction: an update
AbstractThe formation of the C–C bond is a major and important reaction in synthetic organic chemistry and frequently catalyzed by transition-metal...
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Nickel-Catalyzed Cross-Coupling Reactions of Unreactive Phenolic Electrophiles via C–O Bond Activation
Nickel-catalyzed cross-coupling reactions of aryl esters, carbamates, carbonates, ethers and arenols are reviewed. Carbon–oxygen bonds in these...
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Azo group(s) in selected macrocyclic compounds
Azobenzene derivatives due to their photo- and electroactive properties are an important group of compounds finding applications in diverse fields....
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Functional Supramolecular Materials Formed by Non-covalent Bonds
Molecular recognition is essential for realizing functional supramolecular materials. Non-covalent host-guest interactions are effective tools to...
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Sequence-controlled polymers via reversible-deactivation radical polymerization
The development of reversible-deactivation radical polymerization (RDRP) has made a great contribution not only in controlling the molecular weight...
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Recent Advances on CO2 Utilization as C1 Building Block in C-N and C-O Bond Formation
In the last decade, enormous efforts have been initiated to establish catalytic transformations with carbon dioxide (CO2) as a C1 building block...