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Non-statistical assembly of multicomponent [Pd2ABCD] cages
Self-assembled hosts, inspired by biological receptors and catalysts, show application potential in sustainable synthesis, energy conversion and...
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Metal-polymer framework based on hyperbranched polyester polyphthalate and palladium(ii) ions: synthesis, structure, and physical and catalytic properties
The Pd II complex was synthesized on the platform of hyperbranched polyester polyphthalate. The polymeric ligand and complex were characterized by...
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Double Complex Salts of Copper(II) Amines with the [RuNOCl5]2– Anion: Synthesis, Structure, Properties
AbstractThe reaction of copper(II) chloride with (NH 4 ) 2 RuNOCl 5 in the presence of ammonia or ethylenediamine (en) gives [CuL n ][RuNOCl 5 ] double...
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Using the Internal Standard Method with a Planar Detector in the Determination of Lanthanides in Geological Samples by Neutron Activation Analysis
AbstractThe determination of eleven lanthanides in geological samples by long-living radionuclides using comparator instrumental neutron activation...
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Dechanneling of High-Energy Particles from Planar Channels of Crystal. Elastic and Inelastic Scattering Processes
AbstractOn the basis of the principles of nonequilibrium statistical thermodynamics, the kinetic theory of dechanneling of high-energy particles from...
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Bandwidth Enhancement of Planar Terahertz Metasurfaces via Overlap** of Dipolar Modes
We present enhancement of operational bandwidths of planar terahertz metasurfaces by incorporating a complex unit cell that consists of a pair of...
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Synthesis, Spectroscopic Characterization, DFT Calculations, Antibacterial Activity, and Molecular Docking Analysis of Ni(II), Zn(II), Sb(III), and U(VI) Metal Complexes Derived from a Nitrogen-Sulfur Schiff Base
AbstractA series of metal complexes of Ni(II), Zn(II), Sb(III), and U(VI) were synthesized by reacting the corresponding metal salts with the Schiff...
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Synthesis, Structural, Spectroscopic, Hirshfeld Surface Analysis and Computational Study of Copper Complex Containing Salicylaldimine Ligands
AbstractHerein, a new Schiff base copper complex named as of bis{( E )-5-(diethylamino)-2-(((3-iodo-4-methylphenyl)imino)methyl)phenol}copper(II) ( DIMP-Cu...
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Cluster Variation for Spatially Distributed Heterogeneous Systems
AbstractFundamentals of cluster variation (CV) are developed for locally heterogeneous spatially distributed systems. The theory is based on the...
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Ultrasound irradiation synthesis of novel copper(II) complex with the 2-thiophenimidazoline ligand: SC-XRD, HSA, and DFT study
A novel coordination CuCl 2 (L) 2 complex was synthesized by complexation of the 2-thiophenimidazoline ligand with CuCl 2 .2H 2 O in less than 10 min. The...
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Investigating CO2 storage properties of Pd(II) and Co(II) chelates of a Schiff's base ligand
A new metal complexes are made from the ligands derived from amoxicillin based Schiff's base coordinated with Pd(II) and Co(II) have been synthesized...
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New binuclear Cu (II) complex: synthesis, structural elucidation, cytotoxic and DNA-binding evaluation
A novel copper complex [Cu(μ 2 –OH)(1,10-phenanthroline)(4-aminobenzenesulfonic acid)·3H 2 O] 2 ( 1 ) was synthesized and characterized by X-ray...
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A copper(II) chloride coordination compound with 2-phenyl-4,5-dihydro-1H-imidazole ligand: synthesis, characterization, crystal structure, HSA, and DFT studies
Under ultrasound irradiation in an ethanol solvent, a new coordination complex of Cu(II) was successfully synthesized within a 10-min timeframe...
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Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and DFT Calculations of Ni(II) Complex with 3,3′-(-(pentane-3,3-diylbis(1H-pyrrole-5,2-diyl))bis(diazene-2,1-diyl))Dipyridine
A Ni(II) complex of 3,3′-(-(pentane-3,3-diylbis(1H-pyrrole-5,2-diyl))bis(diazene-2,1-diyl)) dipyridine, NiL , has been synthesized and characterized....
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The Rate of Fast Particles Leaving a Planar Channeled Regime in a Quasiclassical Approach
AbstractThe rate of particles leaving a planar channeling regime is studied in the framework of nonequilibrium statistical theory. In the...
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Rhenium-Linked Multiporphyrin Assemblies:Synthesis and Properties
Re(CO)5Cl readily reacts with pyridine-derivatized porphyrins to give molecular squares or planar dimers featuring fac-Re(CO)3(Cl) corners....
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Synthesis, Crystal Structure and Fluorescent Property of Cis-bis[N,N-diethyl-N'-(p-nitrobenzoyl)thiourea-kS,O] Platinum(II) Complex
The reaction of the N , N -diethyl- N' -( p -nitrobenzoyl)thiourea with K 2 [PtCl 4 ] results in the complex of configurational cis -[Pt(L- kS , O ) 2 ], and...
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Organyltriphenylphosphonium Dichlorodicyanoaurates [Ph3PR][Au(CN)2Cl2] (R = n-Pr, i-Bu, and n-Hp): Synthesis and Structures
AbstractThe reactions of potassium dichlorodicyanoaurate with n- propyl-, iso- butyl-, and n- heptyltriphenylphosphonium bromides in water followed by...
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Solvothermal synthesis of cobalt PCP pincer complexes from [Co2(CO)8]
Treatment of [Co 2 (CO) 8 ] with the ipso -substituted P(C-X)P Y ligands (X = Br, Cl; R = i Pr, t Bu) bearing Y = NH and CH 2 linkers under solvothermal...
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Palladium Complexes [Ph3PCH2C(O)Me][PdCDmso-S)] and [Ph4Sb(Dmso-O)][PdBr3(Dmso-S)]: Synthesis and Structures
AbstractIonic palladium complexes with mononuclear anions [Ph 3 PCH 2 C(O)Me][PdCl 3 (Dmso- S )] ( I ) and [Ph 4 Sb(Dmso- O )][PdBr 3 (Dmso- S )] ( II ) are synthesized...
