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Transition-Metal-Complexed Catenanes and Rotaxanes in Motion: Towards Molecular Machines
In the course of the last decade, many dynamic molecular systems, for which the movements are controlled from the outside, have been elaborated....
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Cobalt-based Metalloporphyrins As Efficient Electro-catalysts for Hydrogen Evolution From Acetic Acid and Water
Four molecular electrocatalysts based on cobalt complexes, CoT(X)PP (X = H ( 1 ), OH ( 2 ), CN ( 3 ), COOH ( 4 )), were prepared from meso -tetra- p -X-phenylpor...
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Neo-Porphyrinoids: New Members of the Porphyrinoid Family
The four pyrrole rings and four meso carbons of tetrapyrrolic porphyrins can be arranged in different ways and the resulting porphyrin isomers...
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Electrochemical Sensors Based on Copper–Cadmium Bimetallic Porphyrin Coordination Polymers with Various Cu/Cd Ratios
AbstractBimetallic porphyrin coordination polymers with various Cu/Cd ratios ( Cu – Cd ) were synthesized and characterized by X-ray diffraction,...
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Synthesis and Design of Metalloporphyrin Oligomers with Temperature-Assisted Spectral-Luminescent Properties
AbstractA number of metal-linked porphyrin oligomers of different structures were synthesized and their luminescent sensitivity to temperature was...
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Porphyrin complexes of transition metals with a large dipole moment as active components of new film electret materials
This paper presents the results of a systematic study aimed at searching for organometallic molecules with a large dipole moment in order to create...
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Metal Crown-Porphyrin Complexes: Preparation, Optical Properties, and Applications (Review)
AbstractThe review addresses methods for the synthesis of metal complexes of crown-substituted porphyrins; structural features of these compounds;...
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Revised structure of 2,13-dinitro-5,10,15,20-tetraphenylporphyrin. Inside high-resolution NMR
5,10,15,20-Tetraphenylporphyrin-copper(II) complex when nitrated with 25% aqueous nitric acid in CHCl 3 led to three β,β-substituted dinitro-isomers....
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The co-crystal of copper(II) phenanthroline chloride complex hydrate with p-aminobenzoic acid: structure, cytotoxicity, thermal analysis, and DFT calculation
Complex [Cu(phen) 2 Cl]Cl∙2PABA∙4H 2 O has been isolated, where phen ligand is 1,10-phenanthroline and PABA is p -aminobenzoic acid. The complex...
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Study of the Metal Exchange Reaction of Cadmium(II) 5,15-Dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with d-Metal Salts in Organic Solvents
AbstractThe kinetics of the metal exchange reactions of cadmium(II) 5,15-dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with copper(II) and...
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Photocatalytic activity of pyrazinoporphyrin in the presence of gold nanoparticles and nanoclusters
The effect of gold nanoparticles and nanoclusters on the catalytic activity of dicarboxy-substituted pyrazinoporphyrin was studied using the...
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Macrocycle Synthesis Through Templation
This review highlights the major advances over the last 5 years in the templated synthesis of carbon-based macrocycles. With selected examples, it...
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Heteroatomic substitution of tetraphenylporphyrin as approach for regulating coordination ability
The work reports first studied kinetics of complexation between copper and heterosubstituted porphyrins, namely...
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Bulky-substituted phthalodinitriles and cobalt and copper phthalocyanines based on them: synthesis, thermal analysis and spectroscopic properties
By the nucleophilic substitution of the nitro group in 4-nitrophthalononitrile for the residues of alkoxy-substituted phenols, the synthesis of...
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Covalent and non-covalent systems based on s-, p-, and d-metal macroheterocyclic complexes and fullerenes
The review summarizes various systems containing macroheterocyclic donor platforms and fullerenes. The specific features of the chemical structure...
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Electronic Communication in Heterometallated Porphyrin Oligomers
This book cuts across the divisions of organic, inorganic, and physical chemistry. It describes new methods for creating π-conjugated porphyrin...
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Cyclopropanation with Ruthenium Catalysts
In this decade, a variety of ruthenium complexes have been intensively investigated that exhibit catalytic activity for cyclopropanation of olefins...
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Two-Dimensional Dye Assemblies on Surfaces Studied by Scanning Tunneling Microscopy
This chapter gives an overview of the ordering of dyes on atomically flat conductive surfaces as revealed by scanning tunneling microscopy....
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Spectroscopic, thermodynamic and molecular docking studies on the interaction of two water-soluble asymmetric cationic porphyrins with calf thymus DNA
The water-soluble cationic porphyrin, 5-(1-dodecyl pyridinium-4-yl)-10,15,20-tris(1-methylpyridinium-4-yl)-21 H ,23 H -porphyrin tetrachloride (MDTMPyP),...
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Design and binding ability of organometallic Zn porphyrin films toward imidazole derivatives
A Zn II tetraarylporphyrin containing bidentate binding sites in para -positions of the meso -phenyl fragments of the macrocycle was synthesized and...