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Hydrosilylation Catalysis for One-Pot Synthesis
One-pot synthesis, including the hydrosilylation of alkenes, alkynes, carbonyl compounds, CO2, and other molecules, enables the facile synthesis of... -
Recent Development of Cobalt-Catalyzed Hydrosilylation Reactions: New Catalysts, Mechanistic Understandings, and Future Trends
This chapter presents a comprehensive summary of cobalt-catalyzed hydrosilylation of alkenes and alkynes from 2016 to 2023 with the objective of... -
Separations by Shape: Molecular Shape Recognition in Liquid Chromatography
Molecular shape can provide a basis for chromatographic separations that is distinct from other interaction mechanisms often considered in liquid...
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Stereoselective synthesis and metathesis polymerization of exo-5-(Pentamethyldisiloxanyl) norbornene
AbstractA one-step selective method based on the hydrosilylation of 2,5-norbornadiene with commercially available silanes in the presence of a...
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Enantioselective Radical Reactions
Over the past two decades, many researchers have been interested in “taming” the reactive free radical intermediate and utilizing it in... -
Modern Approaches to Obtaining Organofunctional Silsesquioxanes
AbstractModern research in the field of synthesis of organofunctional oligosilsesquioxanes is considered. Relationships between the composition and...
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Evolution of Organometallasiloxanes
AbstractThe development of organometallasiloxane chemistry from first polymeric systems to individual organometallasiloxanes and functional...
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Metal-free visible-light-mediated aerobic oxidation of silanes to silanols
Oxidation of silanes into silanols using water/air has attracted considerable attention. The known methods with no exception required a metal...
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Chemically modifying electrodes—a classical tool box
The paper provides a detailed overview of heterogeneous chemical reactions leading to the electrode surface modification and further reactivity of...
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One-Step Selective Method for the Synthesis of Silicon-Containing exo-Norbornenes
AbstractA one-step selective method for the synthesis of exo isomers of silicon-containing norbornenes by hydrosilylation of norbornadiene-2,5 with...
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Preparation and Characterization of Silanized Cardboard via Inverse Gas Chromatography and Complementary Analytical Techniques
Three silanized cardboard samples, MeSi-CB, Me 2 Si-CB, and MePhSi-CB were prepared by reacting bare cardboard with chlorosilanes with different...
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Recent Advances in the Field of Polycarboranesiloxanes Synthesis
AbstractThe reports on the synthesis and study of polycarboranesiloxanes published after 2000 have been reviewed. The data on the C- and...
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Effect of Epoxidized Natural Rubber-Grafted-Modified Microfibrillated Cellulose to Compatibility in Wood Pulp/Polylactic Acid Biocomposite: Mechanical–Thermal and Durability Analysis
The aim of this work was to enhance the performance of a wood pulp/polylactic acid (PLA) biocomposite using epoxidized natural rubber...
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Sequentially Palladium-Catalyzed Processes
Sequentially palladium-catalyzed reactions consist of combinations of identical, related, or significantly different palladium-catalyzed processes... -
Hydrosilylation of ferrocene-containing alkenes and alkynes as a route to siloxane aerogels modified with ferrocene
The reaction of ferrocene-containing alkenes and alkynes with HSi(OEt) 3 and HSiMe(OMe) 2 in the presence of Karstedt catalyst (Pt 2 [(Me 2 SiCH=CH 2 ) 2 O] 3 )...
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Reinforced Polymers: The Emerging Role of Diazonium Modification of Fillers
This chapter summarizes the knowledge of fillerFiller modification with diazonium salts, with a view to designing high-performance reinforced polymer... -
An Overview of N-Heterocycle Syntheses Involving Nitrene Transfer Reactions
The addition of either free or transition metal-supported nitrenes to unsaturated C–C bonds and heteroatom lone pairs, as well as intramolecular... -
Electrochemical characterization of functionalized magnetite nanoparticles with pyrogallol on a Au electrode
One reason for the interest in surface modification of magnetite nanoparticles is to create a physical barrier that inhibits their agglomeration and...
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Palladium-Catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds
For many years, unactivated alkyl electrophiles that contain β hydrogens were generally regarded as unsuitable partners for palladium-catalyzed... -
Metallocene-Catalyzed Selective Reactions
Transition metal cyclopentadienyl complexes constitute a large family of compounds that can be used as catalyst for a number of organic...