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Reductive dimerization of fluoroolefins. 2. Cyclic olefins
Cyclic perfluoroolefins containing a perfluoroalkyl substituent at the double bond are capable of undergoing reductive dimerization upon cathodic...
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Telomerization of isoprene with piperidine on complex palladium catalysts
1. The telomerization of isoprene with piperidine on PdCl 2 +Ph 3 P, (Ph 3 P) 2 PdCl 2 , Pd(OAc) 2 +2Ph 3 P, Pd-(acac) 2 +2Ph 3 P, and Pd(OAc) 2 +2P(OC 6 H 4 CH 3 -o) 3 ...
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Synthesis of higher fluorine-containing dienes and allenes
1. Highly electrophilic olefins containing three perfluoroalkyl groups at the double bond undergo a unique dimerization reaction in the presence of...
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Determination of low levels of fluorine in concentrated phosphoric acid by use of the fluoride electrode
The determination of both high and low fluorine concentrations in concentrated phosphoric acid is complicated by the reaction of hydrofluoric acid...
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The Reactions of Metal Atoms
Metal atoms are the ultimate coordinately and electronically unsaturated neutral species and owe much of their high reactivity to this unsaturation... -
Electroreduction of perfluoropiperidine
1. The ability of perfluoropiperidine to function as a one-electron oxidizing agent was confirmed by electrochemical methods.
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Exploratory investigations on the chemistry and technology of fertilizers and salts
From this review of exploratory work we can 1) decide to some extent which results of the exploratory work deserve further development and...
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New N-fluoroimines
We have obtained the N-fluoroimidofluoride of difluoroaminodifluoric acid, the N-fluoroimine of difluoroaminopentafluoroacetone, and the...
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Reaction of α,ω-diiodo- and α, β- dichloro-ω-iodoperfluoroalkanes with some aromatic compounds
1. The reaction of some α,ω -diiodoperfluoroalkanes, namely 1,2-diiodoperfluoroethane and 1,6-diiodoperfluorohexane, with benzene, naphthalene and...
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Reactions of Organic Fluorine Compounds
The factual material to be discussed in this chapter on the reactions of organic fluorine compounds is so abundant that it is out of the question to...