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Quantum-Chemical Study of Formation of Alkyl- and Alkenyladamantanes by Ionic Alkylation with Olefins
AbstractThe thermodynamic parameters of formation reactions (total energy at 0 K, enthalpy, and Gibbs free energy at a temperature of 298.15 K and a...
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Coumarins as Emerging Anti-Viral Compounds from Natural Origins: Ethnopharmacology, Chemistry, Mechanism of Action, Clinical and Preclinical Studies, and Future Perspectives
From the natural origin, more than 1300 coumarins have already been recognized. Coumarins are natural products and secondary metabolites in plants,... -
Coumarins as Emerging Antiviral Compounds from Natural Origins: Ethnopharmacology, Chemistry, Mechanism of Action, Clinical, Preclinical Studies, and Future Perspectives
From the natural origin, more than 1300 coumarins have already been recognized. Coumarins are natural products and secondary metabolites in plants,... -
Advances in the Chemistry of Unsaturated Adamantane Derivatives (A Review)
AbstractThis review discusses various issues related to the synthesis of unsaturated adamantane derivatives, to the development of novel methods...
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Synthesis of 3,5-Bis(hydroxymethyl)adamantan-1-ols and 3,5-Bis(nitrooxymethyl)adamantan-1-yl Nitrates
AbstractA convenient method has been developed for the synthesis of 3,5-bis(hydroxymethyl)adamantan-1-ols via successive nitroxylation of...
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Catalytic Alkylation of Adamantane with Propylene: Quantum-Chemical Calculations and Experimental Data
AbstractThe mechanism of interaction of adamantane with propylene has been studied by quantum-chemical calculations within the density functional...
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Kinetic Study of the Nitrolysis of Haloadamantanes
AbstractThe kinetics of nitrolysis of haloadamantanes containing halogen atoms in the bridging and bridgehead positions with fuming nitric acid have...
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Exploiting the sp2 character of bicyclo[1.1.1]pentyl radicals in the transition-metal-free multi-component difunctionalization of [1.1.1]propellane
Strained bicyclic substructures are increasingly relevant in medicinal chemistry discovery research because of their role as bioisosteres. Over the...
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Physiologically Active Compounds Based on Membranotropic Cage Carriers–Derivatives of Adamantane and Polyhedral Boron Clusters (Review)
AbstractData on compounds based on cage structures―boron clusters (polyhedral boron hydrides, carboranes, metallacarboranes) and compounds of the...
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Chemoselectivity of Nitroxylation of Cage Hydrocarbons
AbstractThe composition of reaction mixtures obtained by nitroxylation of 13 cage hydrocarbons with 100% nitric acid and its mixtures with acetic...
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Introduction of Heteroatoms to Alkyl Carbocations Generated from Alkylboron Reagents via Electrochemical Activation
Organic molecules consist of hydrocarbon frameworks and their function mainly depends on the presence of polar heteroatoms that are attached to the... -
Merging Boron with Nitrogen–Oxygen Bonds: A Review on BON Heterocycles
AbstractCyclic boronate esters play important roles in organic synthesis, pharmacology, supramolecular chemistry and materials science owing to their...
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Size and charge effects of metal nanoclusters on antibacterial mechanisms
Nanomaterials, specifically metal nanoclusters (NCs), are gaining attention as a promising class of antibacterial agents. Metal NCs exhibit...
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Organic Reactions and Their Mechanisms
Unlike inorganic reaction which take place between ions, the organic reactions are basically molecular in nature. An organic reaction takes place by... -
Theory and Practice of the Preparation of Adamantylarenes
AbstractThe adamantylation of diphenyl oxide and phenol with 1-chloro(bromo)adamantanes in a liquid phase has been studied. The reaction has been...
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Oxidative functionalization of adamantanes (review)
The results of studies in the area of oxidative functionalization of hydrocarbons of the adamantane series over the last two decades have been...
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Quantum chemical, experimental, theoretical spectral (FT-IR and NMR) studies and molecular docking investigation of 4,8,9,10-tetraaryl-1,3-diazaadamantan-6-ones
AbstractThe compounds 4,8,9,10-tetraaryl-1,3-diazaadamantan-6-ones ( a – e) were synthesized and characterized by FT-IR, 1 H and 13 C NMR spectra, and...
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Interplay of thermochemistry and Structural Chemistry, the journal (volume 30, 2019, issues 1–2) and the discipline
The contents of issues 1 and 2 of Structural Chemistry from the calendar year 2019 are summarized in the present review. A brief thermochemical...
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