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New Trends in Hexacoordinated Phosphorus Chemistry
Phosphorus derivatives with six substituents at the immediate periphery of the heteroatom are quite common, more than usually imagined, and this...
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Direct conversion of white phosphorus to versatile phosphorus transfer reagents via oxidative onioation
The main feedstock for the value-added phosphorus chemicals used in industry and research is white phosphorus (P 4 ), from which the key intermediate...
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On the interpretation of Mössbauer isomer shifts of iron-organic compounds
Analysis of the available data for several classes of homo- and heteroleptic iron-organic compounds has shown that coefficient ∇ IS/aID = 0.04 mm s −1 ...
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The Rise of Organophosphorus Derivatives in π-Conjugated Materials Chemistry
This chapter concerns the synthesis and properties of π-conjugated oligomers and polymers containing phosphorus moieties, an area of increasing...
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Structure and Nomenclature
From the beginning of coordination chemistry, the color of coordination compounds had fascinated researchers and the variety of colors has been...
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Aryl Compounds of Pentavalent Antimony: Syntheses, Reactions, and Structures
AbstractThe synthesis methods, some reactions, and specific features of the structures of aryl compounds of pentavalent antimony and examples of...
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“Zwitterionic Phospholide Derivatives—New Ambiphilic Ligands”
Attachment of one or two phosphonio substituents converts a phospholide anion not only into a zwitterion or cation but induces as well a...
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Axial Coordination to Metalloporphyrins Leading to Multinuclear Assemblies
The use of axial coordination to metalloporphyrins is discussed on the basis of constructing multinuclear complexes. Starting with single...
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Comparative DNA binding ability and phosphatase-like activity of mono and dinuclear Ni (II) complexes: a structure-activity correlation
Two Ni(II) complexes [(Ni L1)(CH 3 COO) (H 2 O) 2 ](1) and [{(NiL2) (CH3COO)} 2 (µ-H 2 O)] (2) having different coordination environments around metal centres...
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Azomethine-functionalized organic–inorganic framework: an overview
Imines are organic moieties associated with numerous frameworks and show applications in organic synthesis, medicine, chemical analysis, and new...
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Polyphosphazenes: A Review
In this paper the synthesis, properties and applications of poly(organophosphazenes) have been highlighted. Five different classes of macromolecules...
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Synthesis and Application of Novel Chiral Cp Ligands in Transition Metal Catalysis
Chiral cyclopentadienyl groups and their respective metal complexes have been studied for several decades. However, it is only in the last decade...
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Computational Approach Toward Identification and Catalytic Degradation of Chemical Warfare Agents Using MOFs
Chemical warfare agents (CWAs) are toxic synthetic chemical weapons used for mass destruction in wars. Despite the prohibition on their use by...
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Synthesis Methods, Structure, and Applications of Metal Dicyanoaurate, Tetracyanoaurate, and Dihalodicyanoaurate Complexes
AbstractCyanoaurate complexes represent a broad class of compounds with diverse structures. In particular, coordination polymers based on these...
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Complexation with Transition Metals
The electron-deficiency fullerenes that resemble olefins are facile to react with nucleophilic transition metals to form related complexes with novel...
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Complexation with Transition Metals
The electron-deficiency fullerenes that resemble olefins are facile to react with nucleophilic transition metals to form related complexes with novel...
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Metallosupramolecular Dye Assemblies
Metallosupramolecular assemblies of dyes are of increasing interest as model systems for natural light harvesting and photosynthetic complexes as...
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Coordination Complexes
In this chapter, we focus on coordination complexes. In a typical coordination complex (or simply complex), a central metal atom or ion is chemically...
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Material design modelling for optimisation of lithium battery fast charging
The increasing demand for high-performance energy storage solutions has brought lithium batteries to the focus of modern technology. The need for...
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A comprehensive review on synthesis, characterization, and applications of polydimethylsiloxane and copolymers
AbstractPolydimethylsiloxane belongs to a polymeric organosilicon compounds that is widely used as silicon-based organic polymer....
