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Article
Support and dispersion effects on activity of platinum catalysts during wet oxidation of organic wastes
Catalytic activity of platinum catalysts such as Pt/graphite, Pt/TiO2, Pt/Al2O3, and Pt/active carbon was studied using a slurry phase CSTR. Three model reactions, namely, phenol, maleic acid, and malonic acid ox...
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Article
Separation and purification ofBacillus thuringiensis(Bt) toxic protein CrylAb from transgenic rice by ion-exchange chromatography
A separation method for Bt toxic protein CrylAb from Bt transgenic rice (Ke Ming Dao) by ion-exchange chromatography has been developed and validated. Bt transgenic rice-extract containing CrylAb toxic protein is...
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Article
HPLC determination of copper(II), cobalt(II) and iron(II) in pharmaceutical preparations using 2-acetylpyridine-4-phenyl-3-thiosemicarbazone derivatizing agent
Cu(II) Co(II) and Fe(II) in pharmaceutical preparations were determined using precolumn derivatization and solvent extraction with 2-acetylpyridine-4-phenyl-3-thiosemicarbazone (APPT) as complexing reagent. Li...
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Article
HPLC determination of copper(II), cobalt(II) and iron(II) in pharmaceutical preparations using 2-acetylpyridine-4-phenyl-3-thiosemicarbazone derivatizing agent
Cu(II) Co(II) and Fe(II) in pharmaceutical preparations were determined using precolumn derivatization and solvent extraction with 2-acetylpyridine-4-phenyl-3-thiosemicarbazone (APPT) as complexing reagent. Li...
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Article
Heteroorganic derivatives of furan. 65. Effect of substituents on shielding of 1H, 13C, and 29Si and 29Si-13C spin-spin coupling constants in NMR spectra of 2-substituted furans and 5-trimethylsilylfurans
The results of an investigation of 2-substituted furans and 5-trimethylsilylfurans by NMR spectroscopy and the CNDO/2 method showed that the chemical shifts of the different nuclei do not correlate sufficientl...
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Article
The use of p-n-butyl oxybenzoic acid as liquid-crystalline sorbent in gas chromatography
The retention mechanisms of polymethylbenzenes and n-alkylbenzenes on the inert solid support Chromaton (spec-surface area: 1m2/g) and the adsorbent-support Silochrom (C-80 (80 m2/g) coated with p-n-butyl oxybenz...
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Article
Tetrazoles. 15. Electrical conductivity of 5-phenyltetrazole and its salts in water and organic solvents
The electrical conductivity of 5-phenyltetrazole and its potassium, cesium, and ammonium salts in water, acetone, acetonitrile, nitromethane, and dimethyl sul-foxide has been studied. 5-Phenyltetrazole and its...
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Article
Radical meso-alkylation of vanadyletioporphyrin
The possibility of the meso-alkylation of vanadyletioporphyrin (25–30% yields) by its reaction with alkyl bromides [C(6)-C(12)] in the presence of finely dispersed silver metal at 150–180 °C in an argon atmospher...
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Article
13C NMR spectra of 5-substituted 8-mercaptoquinolines
The increments of the substituents were determined from the 13C NMR spectra of 5-substituted quinolines. It is shown that the increments correlate with those in benzenes, as well as with the Swain-Lupton constant...
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Article
Calculation of the electronic spectrum within the CNDO/S (complete neglect of differential overlap/S) approximation and character of the long-wave absorption band of 2-N-pyridinia-1,3-indandione betaine
The electronic spectrum of 2-N-pyridinia-1,3-indandione betaine was calculated by the MO LCAO method within the CNDO/S approximation with the Del Bene-Jaffe parametrization in order to refine the concepts rega...
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Article
Mo self-consistent-field (scf) calculations of quinoline and its derivatives. 4. Theoretical examination of the formation of the mesoionic form of 8-mercaptoquinoline and its derivatives
The formation of the mesoionic form of 8-mercaptoquinoline and its derivatives in a polar medium was examined within the CNDO/2 approximation. The change in the tautomerization constants of these compounds is ...
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Article
13C NMR spectra of 7-substituted 8-mercaptoquinolines
The13C NMR spectra of 7-substituted [7-CH3, 2,7-(CH3)2, 7-Cl, 7-Br, and 7-SCH3] 8-mercaptoquinolines and 8-methylmercaptoquinolines were examined. It is shown that the changes in the13C chemical shifts of the qui...
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Article
13C NMR spectra of 7-substituted 8-mercaptoquinolines
The13C NMR spectra of 7-substituted [7-CH3, 2,7-(CH3)2, 7-Cl, 7-Br, and 7-SCH3] 8-mercaptoquinolines and 8-methylmercaptoquinolines were examined. It is shown that the changes in the13C chemical shifts of the qui...
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Article
13C NMR spectra of protonated S-methylquinolines
The signals in the13C NMR spectra of protonated 2-, 3-, 4-, 5-, 6-, and 8-S-methylquinolines in solution in 6 N DCl were assigned. The changes in the13C chemical shifts relative to the neutral molecules were comp...
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Article
13C NMR spectra of 8-mercaptoquinoline and 8-hydroxyquinoline
The signals in the13C NMR spectra of quinoline and its 8-substituted derivatives (SH, SCH3, OH, OCH3, NH2, I, and CH3), 8,8′-diquinolyl disulfide, the 8-hydroxy-N-methylquinolinium ion, and the protonated and ani...
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Article
Mo self-consistent-field (scf) calculations of quinoline and its derivatives. 3. Protonation energies and basic properties
The basic properties (pKNH+) of quinoline and its amino-, methoxy-, and S-methyl-substituted derivatives (substitution in the 2–8 positions of the quinoline ring) are compared with the bond energy [E(NhetH)], the...
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Article
Mo self-consistent-field (scf) calculations of quinoline and its derivatives. 3. Protonation energies and basic properties
The basic properties (pKNH+) of quinoline and its amino-, methoxy-, and S-methyl-substituted derivatives (substitution in the 2–8 positions of the quinoline ring) are compared with the bond energy [E(NhetH)], the...
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Article
13C NMR spectra of S-methylquinolines
The 13C chemical shifts and the increments (Δδ) of the SCH3 group in the NMR spectra of S-methylquinolines were measured. It is shown that the chemical shifts of S-methylquinolines correlate satisfactorily with t...
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Article
Molecular-orbital self-consistent field calculations of quinoline and its derivatives
The electronic spectra of the thiol, anionic, protonated, and mesoionic forms of 8-mercaptoquinoline and the mesoionic form of 5-mercaptoquinoline and the 5-mercapto-N-methylquinolinium ion were calculated wit...
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Article
Research on polymerocyanines
A number of dimethylidynenullomethylidynedimerocyanines that are derivatives of 1-methyl-2-thioketo-3-ethylimidazolidin-4-one, 2-thioketo-3-n-butyloxazolidin-4-one, and 1-phenyl-3-methylpyrazol-5-one were synt...