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655 Result(s)
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Article
Birch reduction of the dichlorocarbene adduct of poly(1,1-dimethyl-1-sila-cis-pent-3-ene)(Cl2C-I): synthesis and characterization of poly(1,1-dimethyl-3,4-methylene-1-sila-cis-pent-3-ene) CH2-I)
Birch reduction of the dichlorocarbene adduct of poly(1,1-dimethyl-1-sila-cis-pent-3-ene) (Cl2C-I) yields poly(1,1-dimethyl-3,4-methylene-1-sila-cis-pent-3-ene) (CH2-I) which has been characterized by 1H, 13C and...
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Article
Siloxanes with aliphatic isocyanate groups
Tetramethylcylcotetrasiloxane (D4H) was hydrosilylated with α,α′-dimethyl meta-isopropenyl benzyl isocyanate (m-TMI). The reaction with this commercially available and inexpensive isocyanate produces in 100% y...
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Article
Anionic ring opening polymerization of 3,4-benzo-1,1-dimethyl-1-silacyclopentene
Treatment of 3,4-benzo-1,1-dimethyl-1-silacyclopentene with a catalytic amount of n-butyllithium and HMPA in THF yields poly(3,4-benzo-1,1-dimethyl-1-silapentene). This polymer has the highest melting temperature...
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Article
Anionic ring opening polymerization of 1-silacyclopent-3-ene
1-Silacyclopent-3-ene (I) undergoes anionic ring opening polymerization catalyzed by methyllithium/HMPA to yield poly(1-sila-cis-pent-3-ene) (II). II was characterized by 1H, 13C, and 29Si NMR, GPC, TGA and eleme...
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Article
Synthesis and anionic ring opening polymerization of 1-germa-1,1-dimethyl[3,4,c]thienocyclopentane
1-Germa-1,1-dimethyl[3,4,c]thienocyclopentane (I) has been prepared from 3-germa-3,3-dimethyl-7-thiabicyclo[3,3,0]oct-1-ene (II)1 by oxidation with dichorodicyanoquinone (DDQ). Treatment of I with a catalytic amo...
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Article
Laser photocatalytic polymerization of phenylacetylene
The polymerization of phenylacetylene induced by ultraviolet laser (266 and 355 nm) irradiation of W(CO)6 and W(CO)6-TiCl4 in CCl4 solvent was investigated. The weight-average molecular weights of the polymers re...
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Photolithographic Plating of Platinum and Copper on Insulating Substrates
Several micrometer thick layers of platinum or copper can be photolithographically deposited on Mylar or silica substrates by taking advantage of the photochemistry of [PtCl6]2− in alcohols. This reaction gives r...
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Article
UV absorption spectra of polystyrene
Polystyrene (PSt) exhibits a new UV absorption band at around 290nm in comparison with ethylbenzene, which is attributed to associative interaction between pendant phenyl groups. Similar absorption bands are a...
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Article
Liquid crystalline polyesters with two-dimensional mesogenic units
A series of thermotropic, liquid crystalline (LC) polyesters was prepared in which the mesogenic group contained an unusually large, polarizable pendant group in an attempt to increase intermolecular interacti...
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Article
Compatibilization in ionomer blends
Two kinds of copolymers, i.e. poly(styrene-co-methacrylic acid) (SMaa) and poly(butyl methacrylate-co-methacrylic acid) (BmaMaa) containing a common but minor (10–20%) component of methacrylic acid, were synth...
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Article
Compatibilization in ionomer blends
Copolymers of poly(styrene-co-4-vinylpyridine) (SVp) and poly(butyl methacrylate-co-4-vinylpyridine) (BmaVp) containing common minor units of pyridine were prepared. The blends of BmaVp/SVp were reacted with a...
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Article
Synthesis and characterization of polyacrylates containing charge transfer groups
Polyacrylates containing para-nitro azobenzene have been synthesized by free radical polymerization. The influence of the length of the spacer of the homopolyacrylates (HPn, n=3,4,6), content of methyl acrylat...
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Chapter
Relations of High-Field Non-Linear Dielectric Properties and Electrorheological Effects
The non-linear dielectric property of the electrorheological (ER) fluids under high AC electric field still lacks detailed investigation compared with other studies on ER fluids. In its physical principle, ER ...
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Article
A novel free radical interfacial copolymerization
Free radical interfacial copolymerization which is carried out by means of an amphiphilic bifunctional initiator as a novel polymerization method was proposed for the first time. For utilizing the new polymeri...
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Chapter
Studies on Foamed Hydrogen Absorbing Electrodes
In the paper, some factors affecting electrode’s hydrogen absorption performances were studied making use of the techniques of galvanostatic cycling, XRD and SEM. Conditions of hydrogen storage alloy manufactu...
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Article
Synthesis and characterization of surface-cyanofunctionalized poly (N-isopropylacrylamide) latexes
A series of P[N-isopropylacrylamide (NIPAM)] latexes with different contents of cyano groups were successfully prepared by either seeded or shot-growth polymerizations of an aqueous solution containing acrylonit...
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Article
Corona poling of liquid crystalline polymers with nitroazobenzene side chains
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Article
Enzyme-catalyzed degradation of aliphatic polycarbonates prepared from epoxides and carbon dioxide
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Article
Preparation and oil-absorptivity of crosslinked polymers containing stearylmethacrylate, 4-t-butylstyrene, and divinylbenzene
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Article
Morphological investigation of styrene and acrylamide polymer microspheres prepared by dispersion copolymerization
The morphology of the styrene and acrylamide copolymer microspheres prepared by dispersion copolymerization in an ethanol/water medium was investigated. The effects of the styrene/acrylamide ratio, ethanol/wa...