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    A three-shell supramolecular complex enables the symmetry-mismatched chemo- and regioselective bis-functionalization of C60

    Molecular Russian dolls (matryoshkas) have proven useful for testing the limits of preparative supramolecular chemistry but applications of these architectures to problems in other fields are elusive. Here we ...

    Ernest Ubasart, Oleg Borodin, Carles Fuertes-Espinosa, Youzhi Xu in Nature Chemistry (2021)

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    Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

    Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as synthetically very important for the catalytic oxidation of C–H and C=C moieties that are hard to activate c...

    Irene Prat, Jennifer S. Mathieson, Mireia Güell, Xavi Ribas in Nature Chemistry (2011)