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    Chapter

    Oxidation—Reduction; Electron and Proton Transfer

    It was shown in Chap. 1 that a free energy change ΔG p,T can be associated with a change of electrical potential. In the present case, we consider the application to oxidation-...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Metalloproteins

    Cytochromes ad were classified on the basis of characteristic absorbance maxima (Keilin and Keilin, 1966). The heme can be attached to the protein noncovalently (cytochromes a, b, and d) or covalently (cytochrom...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Photosynthesis: Photons to Protons

    Most of the chlorophyll or bacteriochlorophyll molecules in the photosynthetic organelle serve as an antenna for light gathering. Approximately one chlorophyll molecule out of 500, and one bacteriochlorophyll ...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Transduction of Electrochemical Ion Gradients to ATP Synthesis

    Proton pum** ATPases can be divided into three classes (Pedersen and Carafoli, 1987a,b; Nelson, 1988): (1) The eubacterial “F-type” that is present in bacteria such as E. coli, mitochondria, and chloroplasts, d...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Thermodynamic Background

    Thermodynamics describes physical and chemical phenomena in terms of macroscopic properties of matter that are obvious to our senses such as pressure, temperature, and volume. These phenomena are divided into ...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Membrane Structure and Storage of Free Energy

    Chloroplasts, mitochondria, and Gram-negative bacteria all share the property of being bounded by a pair of membranes (Keegstra et al, 1984). The two membranes differ in passive permeability properties, the ou...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    The Quinone Connection

    The concept that the long-chain quinones in energy-transducing membranes (Fig. 5.1 A and B) act as mobile carriers of electrons and protons is partly based on the high concentration of quinone in all energy-tr...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Light and Redox-Linked H+ Translocation: Pumps, Cycles, and Stoichiometry

    Two mechanisms of H+ translocation have been discussed thus far, the uptake and release of H+ by ubi- and plastoquinone (Chap. 5), and the release of H+ in the photosynthetic water splitting reaction (Chap. 6.8)....

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)

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    Chapter

    Active Transport

    All living organisms must exchange material with the surrounding environment across their cell membranes, exporting waste materials and importing useful metabolites. The transport of such materials is catalyze...

    William A. Cramer, David B. Knaff in Energy Transduction in Biological Membranes (1990)