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  1. No Access

    Article

    A US perspective on closing the carbon cycle to defossilize difficult-to-electrify segments of our economy

    Electrification to reduce or eliminate greenhouse gas emissions is essential to mitigate climate change. However, a substantial portion of our manufacturing and transportation infrastructure will be difficult ...

    Wendy J. Shaw, Michelle K. Kidder, Simon R. Bare… in Nature Reviews Chemistry (2024)

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    Article

    Atomic control of active-site ensembles in ordered alloys to enhance hydrogenation selectivity

    Intermetallic compounds offer unique opportunities for atom-by-atom manipulation of catalytic ensembles through precise stoichiometric control. The (Pd, M, Zn) γ-brass phase enables the controlled synthesis of...

    Anish Dasgupta, Haoran He, Rushi Gong, Shun-Li Shang, Eric K. Zimmerer… in Nature Chemistry (2022)

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    Article

    Evaluating differences in the active-site electronics of supported Au nanoparticle catalysts using Hammett and DFT studies

    Supported metal catalysts, which are composed of metal nanoparticles dispersed on metal oxides or other high-surface-area materials, are ubiquitous in industrially catalysed reactions. Identifying and characte...

    Gaurav Kumar, Luke Tibbitts, Jaclyn Newell, Basu Panthi… in Nature Chemistry (2018)

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    Article

    Controlling activity and selectivity using water in the Au-catalysed preferential oxidation of CO in H2

    Industrial hydrogen production through methane steam reforming exceeds 50 million tons annually and accounts for 2–5% of global energy consumption. The hydrogen product, even after processing by the water–gas ...

    Johnny Saavedra, Todd Whittaker, Zhifeng Chen, Christopher J. Pursell… in Nature Chemistry (2016)