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Article
Enhanced photothermal dehydration of methanol over W18O49/Au/SAPO-34 catalysts with broadened light absorption
Methanol-to-olefins (MTO) process is one of the most critical pathways to produce low carbon olefins. Typically, the reaction is driven by thermal catalysis, which inevitably needs to consume large amounts of ...
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Article
Fabrication of Ag2S electrode for CO2 reduction in organic media
Electro-reduction of carbon dioxide (CO2) to carbon monoxide (CO) has been extensively studied on metal and alloy electrodes for many decades. However, owing to their disadvantages of low current density and high...
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Chapter and Conference Paper
Experimental Study on the Reversion Reaction Between Magnesium and CO Vapor in the Carbothermic Reduction of Magnesia Under Vacuum
The mechanism of magnesia production was investigated experimentally in reversion reaction process in vacuum. Condensation temperature and temperature gradient which effected on the condensation of the magnesi...
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Article
Open AccessAntisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide
The intercalation compounds with various electrochemically active or inactive elements in the layered structure have been the subject of increasing interest due to their high capacities, good reversibility, si...
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Chapter
Mechanism of Carbothermic Reduction of Magnesia and Reversion Reaction
In this study, the mechanism of the carbothermic reduction process to extract magnesium from magnesia and the reversion reaction in vacuum were investigated. The carbon monoxide (CO) content of the gas, phases...
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Chapter
Study on Mechanism of Magnesia Production by Reversion Reaction Process in Vacuum
The mechanism of magnesia production was investigated experimentally in reversion reaction process in vacuum. The results showed that the reversion reactions were exothermic reaction, the gas-phase reversion w...
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Chapter
Study on the Thermodynamic and Experimental Carbothermic Reduction of Garnierite
The overall utilization of magnesium and other metals should be systematically considered during the exploration of deficient garnierite .In this paper the thermodynamic analysis of the carbothermic reduction ...
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Chapter
Industrial Production of Dimethyl Carbonate from CO2 in China
This chapter contains a detailed introduction to dimethyl carbonate (DMC) followed by a presentation to the manufacturing process for DMC synthesis. Particularly, we mainly introduce the recent advances on tec...
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Article
Analysis of Magnesia Carbothermic Reduction Process in Vacuum
The mechanism of magnesia carbothermic reduction was investigated experimentally in a reduction reaction process in vacuum. The thermodynamic calculation results showed that the initial reduction temperature b...
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Article
Behavior Analysis of CaF2 in Magnesia Carbothermic Reduction Process in Vacuum
Magnesium production by carbothermic reduction of magnesia with CaF2 in vacuum was investigated experimentally by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy ...
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Article
Thermochemical study of mixed ligand complexes of rare earths with glycine andL-alanine
In order to obtain the standard molar enthalpies of formation of Rare-Earth amino acid coordination compounds, precise isothermal solution-reaction calorimetric method was used. The value of ΔrH ...
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Article
Synthesis, DNA-binding and cleavage studies of macrocyclic copper(II) complexes
Two macrocyclic copper(II) complexes, [CuL1](ClO4)2 (L1 = 2,6,9,13-tetraparacyclophane, a Schiff base) and [CuL2]Cl2 [L2 = 3,10-bis(2-benzyl)-1,3,5,8,10,13-hexaazacyclotetradecane] have been prepared and characte...
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Article
DNA-binding and cleavage studies of a dinuclear copper(II) complex with a 26-membered hexaazamacrocycle
The complex, [Cu2LCl2]Cl2 · 3H2O, where L = the macrocyclic ligand bis-p-xylylBISDIEN Schiff base, has been prepared and characterized by elemental analysis, i.r. and mass spectra. The binding of the complex with...