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Article
Partialsynthese des Aldosterons
The preparation of the (18 → 11β)-lactone ofΔ 5-3-ethylenedioxy-11β-hydroxy-21-acetoxy-20-oxo-pregnen-18-oic acid (XV) is reported. Since this compound has previously been transformed into aldosterone, the reacti...
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Article
Neue Substitutionsreaktionen bei Steroiden
The intramolecular substitution of the angular methyl groups in steroids by attack of O-radicals derived from 6β-, 11β, and 20-alcohols is discussed. Irrespective of their genesis, these radicals abstract a hydro...
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Article
Ein neues Verfahren zur Herstellung von 19-Norsteroiden
The new methods for the production of 19-norsteroids described involve the conversion of 5α-halogen-6β-hydroxy-steroids into the corresponding 5α-halogen-6β:19-ethers either with lead tetraacetate or by the hypoi...