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Article
Chain orientation in natural rubber, Part II: 2H-NMR study
Stress-induced crystallisation (SIC) and stress-induced melting (SIM) in natural rubbers (NR), unfilled and filled with carbon black (CB) have been studied by 2H-NMR measurements. Various materials have been swol...
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Article
Chain orientation in natural rubber, Part I: The inverse yielding effect
Inhomogeneous deformations are observed in stretched natural rubber of different crosslink density; the conditions of observation, nucleation and propagation are given in the first part of the paper. In sample...
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Article
Dramatic anion size effect on structural and magnetic properties within a series of novel antiferromagnetic organometallic radical cation salts: [Cp Mo(dmit) ][X ](X = PF , AsF ,SbF )
Electrocrystallization of CH2Cl2 solutions of Cp2Mo(dmit), dmit2- = 2-thioxo-1,3-dithiole-4,5-dithiolate, in the presence of n-Bu4NX (X- = PF 6 - ...
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Article
Experimental determination and modelization of a unique phase diagram: solid solutions of antiferromagnetic organometallic radical cation salts
The physical properties of paramagnetic Mo(V) organometallic radical cation salts, , are investigated through the study of two series of solid solutions ...