![Loading...](https://link.springer.com/static/c4a417b97a76cc2980e3c25e2271af3129e08bbe/images/pdf-preview/spacer.gif)
-
Article
Competition of (3+2) annulation and (3+2) cycloaddition in the reaction of alkenes with donor-acceptor cyclopropanes
Lewis acid-initiated reaction of (het)aryl-substituted donor-acceptor cyclopropanes with styrenes was studied. The initiation of the process by tin(IV) chloride caused the reaction to proceed in two alternative d...
-
Article
Ring expansion of donor—acceptor cyclopropanes bearing arylcarbamoyl group into 1,5-diarylpyrrolidin-2-ones
The rearrangement of 2,N-diaryl-1-carbamoylcyclopropanecarboxylates upon their treatment with titanium(iv) chloride was found to proceed as ring expansion affording 1,5-diaryl-2-oxopyrrolidine-3-carboxylates. In ...
-
Article
Reaction of donor-acceptor cyclopropanes with 1,3-diphenylisobenzofuran. Lewis acid effect on the reaction pathway
Reaction of donor-acceptor cyclopropanes with 1,3-diphenylisobenzofuran in the presence of lanthanide triflates, as well as CuOTf, Sn(OTf)2, SnCl2, ZnCl2, GaCl3, and MgI2, proceeds as a formal [3+4]-cycloaddition...
-
Article
Unusual reactions of vinyl ketones with tetranitromethane. The synthesis of 5-acyl-3-nitroisoxazoles
-
Article
Synthesis of nitrosubstituted triangulanes
The [1+2] cycloaddition of ethyl nitrodiazoacetate to various methylenecyclopropanes afforded 1-ethoxycarbonyl-1-nitropolyspirocyclopropanes. These compounds were used in the synthesis of first representatives...