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Article
Discussion of an open problem
Quantum mechanics rears its head in many places and one of them is inorganic chemistry, where the electronic spin associated with unpaired electrons has a profound influence. This was the topic of the 2012 CEC...
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Article
Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions
Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as synthetically very important for the catalytic oxidation of C–H and C=C moieties that are hard to activate c...
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Article
Efficient water oxidation catalysts based on readily available iron coordination complexes
Water oxidation catalysis constitutes the bottleneck for the development of energy-conversion schemes based on sunlight. To date, state-of-the-art homogeneous water oxidation catalysis is performed efficiently...